Results 71 to 80 of about 2,440 (209)

Helical Photonic Metamaterials for Encrypted Chiral Holograms

open access: yesAdvanced Science, Volume 12, Issue 38, October 13, 2025.
This article explores the untapped potential of 3D‐printed helical structures as chiral metamaterials and metaholograms by uncovering how specific geometric parameters govern their chiroptical behavior. Combining terahertz experiments and simulations, it reveals how tunable, stretchable helices enable broadband ellipticity and encrypted QR codes ...
Wonjin Choi   +6 more
wiley   +1 more source

Probing Chiral Nanoparticles and Surfaces by Infrared Spectroscopy

open access: yesCHIMIA, 2006
Chiral metal surfaces and nanoparticles have the potential to be used for the selective production, the resolution and the detection of enantiomers of a chiral compound, which renders them highly attractive in view of the tremendous consequences
Cyrille Gautier   +5 more
doaj   +1 more source

Asymmetric Epoxidation: A Twinned Laboratory and Molecular Modeling Experiment for Upper-Level Organic Chemistry Students [PDF]

open access: yes, 2015
The coupling of a student experiment involving the preparation and use of a catalyst for the asymmetric epoxidation of an alkene with computational simulations of various properties of the resulting epoxide is set out in the form of a software toolbox ...
Hii, KKM, Rzepa, HS, Smith, EH
core   +3 more sources

Identification of Pyrrolizilactone Biosynthetic Gene Cluster with Unique Short‐Chain Dehydrogenase Gene for 3‐Methylproline Formation

open access: yesChemistryEurope, Volume 3, Issue 5, September 18, 2025.
A standalone enzyme, derived from the reductase domain of a polyketide synthase‐nonribosomal peptide synthetase hybrid enzyme, is identified as a pyrroline carboxylate reductase. This enzyme is involved in the biosynthesis of 3‐methylproline, an amino acid building block of a unique tricyclic pyrrolizidinone structure of a fungal metabolite ...
Naoki Kato   +6 more
wiley   +1 more source

Sesquiterpene Lactones from Calea pinnatifida: Absolute Configuration and Structural Requirements for Antitumor Activity

open access: yesMolecules, 2020
This work describes the chromatographic fractionation of the aerial parts of Calea pinnatifida and the structural characterization and determination of the absolute configuration of the isolated compounds as well as their antitumor potential.
Lhaís Araújo Caldas   +7 more
doaj   +1 more source

Circular dichroism of designed peptide helices and β-hairpins: analysis of trp- and tyr-rich peptides [PDF]

open access: yes, 2005
VCD versus ECD spectroscopy. Peptides rich in aromatic residues yield anomalous far-UV electronic circular dichroism (ECD) spectra that preclude secondary structure assignment.
Anderson   +72 more
core   +1 more source

Single‐Step Insertion of Organic Sulfur Into a Fe6C Carbide Carbonyl Cluster, Including the Natural Amino Acid L‐Cysteine: Vibrational Circular Dichroism and Chirality Transfer

open access: yesAngewandte Chemie, Volume 137, Issue 38, September 15, 2025.
We describe a one‐pot synthetic procedure for the functionalization with organosulfur ligands of hexa‐iron carbide carbonyl clusters. This synthetic procedure is highly versatile and may be applied to alkyl, aryl, and functionalized organic sulfur reagents, including the chiral amino acids L‐ and D‐cysteine.
Francesca Forti   +6 more
wiley   +1 more source

Bioactive 3-Decalinoyltetramic Acids Derivatives From a Marine-Derived Strain of the Fungus Fusarium equiseti D39

open access: yesFrontiers in Microbiology, 2019
Two novel 3-decalinoyltetramic acid (3DTA) derivatives, namely fusarisetins C and D (1 and 2), and four known derivatives (3–6) were isolated from the marine-derived fungus Fusarium equiseti D39.
Donglin Zhao   +9 more
doaj   +1 more source

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