Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
wiley +2 more sources
Yield of Low Serum Vitamin B12 Results in General Pediatric Outpatient Practice: Age-Specific Patterns and Associations with Testing Indications and Recorded Clinical Features. [PDF]
Imdadoglu T +5 more
europepmc +1 more source
ABSTRACT Arthrogryposis Multiplex Congenita (AMC) encompasses several hundred conditions with diverse genetic, pathophysiological, and clinical origins. The overarching EXPLAIN study explores underlying causes and implications of AMC and represents the largest clinical cohort of adults with AMC reported to date.
My Vuong Hermansen +5 more
wiley +1 more source
Electro‐Organic Synthesis at a Stable Oil/Water/Solid Three‐Phase Interface Reactor
A porous membrane electrode (PME) reactor is developed to promote oil/water/solid three‐phase interfacial contact for electro‐organic synthesis. By promoting the formation of an oil/water interfacial region within or near an amphiphilic catalytic layer, the reactor enables efficient conversion of water‐insoluble organic reactants in aqueous ...
Deyin Chen +7 more
wiley +2 more sources
Exploring Dietary Supplements for Psoriasis Management: A Narrative Review. [PDF]
Pagh P, Hertz S, Hjuler KF.
europepmc +1 more source
Gold‐Einzelatomkatalysatoren ermöglichen die selektive Shuttle‐Hydrochlorierung von Alkinen
Gold‐Einzelatomkatalysatoren auf Aktivkohle ermöglichen dank des Zusammenwirkens zwischen Au(I)‐Zentren und dem Träger die heterogene Shuttle‐Hydrochlorierung von terminalen Alkinen zu Vinylchloriden mit hoher Chemo‐ und Stereoselektivität. Das katalytische System vereint breite Substratverträglichkeit, vereinfachte Abtrennung und Wiederverwertbarkeit ...
Marc‐Eduard Usteri +8 more
wiley +1 more source
This review highlights an emerging anticancer approach integrating platinum agents into photodynamic therapy (PDT) and photoactivated chemotherapy (PACT) systems, further augmented by cancer cell membrane‐ and organelle‐targeting. By directing photoactivated platinum complexes from nontargeted distribution to cancer cells or defined subcellular sites ...
Shu Chen +3 more
wiley +2 more sources
Independent Risk Factors and Combined Predictive Model for Severe <i>Mycoplasma pneumoniae</i> Pneumonia in Children: The Role of Vitamin D Deficiency. [PDF]
Zhang M +5 more
europepmc +1 more source
Pt1, an organometallic platinum‐based complex, act as a modulator of redox homeostasis in cnidarians, regulating cellular functions and life‐cycle dynamics. In Nematostella vectensis, it mitigates oxidative stress, strengthens detox systems and accelerates development.
Giuseppina Tommasini +13 more
wiley +2 more sources
Cobalt‐Catalyzed [2σ+2π] Cycloaddition via Site‐Selective Capture of Bicyclobutane Diradical
We report a Co(II)‐catalyzed strategy that combines thermal activation of bicyclo[1.1.0]butane (BCBs) with site‐selective radical capture to furnish head‐to‐head fused bicyclo[2.1.1]hexanes via [2σ+2π] cycloaddition with indoles. Detailed mechanistic studies (31P NMR, EPR, CV, and DFT) support the catalytic pathway, while phosphine‐oxide trapping and X‐
Tanmayee Nanda +8 more
wiley +2 more sources

