Results 41 to 50 of about 1,864 (182)

Interfacial Failure and Self‐Healing in Solid‐State Batteries

open access: yesAdvanced Materials, EarlyView.
Dynamic interfacial self‐healing offers an adaptive route to mitigate coupled mechanical, chemical, and electrochemical degradation in solid‐state batteries. This review connects evolving interfacial failure mechanisms with physical‐flow, chemical‐restoration, stimuli‐responsive, and electric‐field‐assisted repair strategies, highlighting targeted self‐
Xinxin Zhu   +8 more
wiley   +1 more source

Bio-based vitrimers and covalent adaptable networks – a short review

open access: yesNext Sustainability
Biobased vitrimers represent a new class of innovative materials that combine the recyclability of thermoplastics with the durability and mechanical strength of traditional thermosets, offering a promising solution for sustainable applications.
Deniz Bulutcu, Steven Eschig
doaj   +1 more source

Inductively Expandable Supraparticles as Microscopic Force Generators for Remote Mechanical Actuation

open access: yesAdvanced Materials, EarlyView.
This study demonstrates the combination of magnetic nanoparticles and functional blowing agents into supraparticles. Upon induction heating, they actuate via rapid gas generation or extensive volume expansion. These supraparticles lift up to 25 000 times their own mass and rapidly open cured epoxy resins, providing a versatile strategy for fast micron ...
Leoni Luthardt   +3 more
wiley   +1 more source

3D Printing of Self‐Healing Polymers by Material Extrusion: A Process‐Centric Review of Setups, Parameters, and Applications

open access: yesAdvanced Robotics Research, EarlyView.
This review highlights recent advances in material extrusion 3D printing of self‐healing polymers, focusing on the interplay between material chemistry, rheology, hardware customization, and process optimization. Filament‐ and ink‐based extrusion strategies, multimaterial architectures, and postprocessing approaches are discussed for applications in ...
Antonio Pavone   +2 more
wiley   +1 more source

Microscopic evidence for the topological transition in model vitrimers [PDF]

open access: yes, 2023
In addition to the glass transition, vitrimers undergo a topological transition from viscoelastic liquid to viscoelastic solid behavior when the network rearrangements facilitated by dynamic bond exchange reactions freeze.
Arbe, Arantxa   +8 more
core   +1 more source

Bidirectional Disulfide Metathesis Enables Recycling of High‐Performance Thermoset Networks

open access: yesAdvanced Science, EarlyView.
A cyclic aromatic disulfide comonomer enables dual‐mode recyclable pDCPD thermosets through bidirectional disulfide metathesis. The resulting networks combine enhanced mechanical performance with thermal reprocessability and chemical depolymerization into reusable oligomeric fragments, allowing regeneration of high‐performance thermosets with minimal ...
Bohan Li   +8 more
wiley   +1 more source

Rice husk cellulose fiber-derived vitrimers: dynamic covalent network design via transesterification exchange with hierarchical structure preservation

open access: yesMaterials & Design
Bio-based vitrimers have gained considerable attention for their potential to replace fossil derived plastics, address end-of-life recycling issues through dynamic covalent chemistry, and ultimately align materials science with sustainable development ...
Yu Huang   +6 more
doaj   +1 more source

Bioinspired design of elastomeric vitrimers with sacrificial metal-ligand interactions leading to supramechanical robustness and retentive malleability

open access: yesMaterials & Design, 2020
Most elastomeric vitrimers suffer from mechanical weakness in practical applications. Inspired by the development of strong and tough biomaterials relying on sacrificial bond-detachment mechanisms, herein we describe the biomimetic design of elastomeric ...
Siwu Wu   +4 more
doaj   +1 more source

Beyond Traditional Phenolics: Disulfide Bonds for Performance Enhancement of Aerospace Ablation‐Resistant Materials from Processing to Recycling

open access: yesAdvanced Science, EarlyView.
The dynamic disulfide bonds facilitated the development of high‐performance aerospace ablation‐resistant materials. At moderate temperature, the dissociation and recombination of disulfide bonds ensured excellent processability, mechanical properties, and recycling ability of phenolic resin; at high temperature, cleavage of disulfide bonds produced ...
Yu Li   +9 more
wiley   +1 more source

Gel–Sol Transition of Vanillin-Based Polyimine Vitrimers: Imparting Vitrimers with Extra Welding and Self-Healing Abilities

open access: yes, 2019
Vitrimers are cross-linked networks through reversible dynamic covalent bonds. Usually, self-healing of vitrimers are realized by rearrangement of the networks under high temperature (>150 °C) and high pressure.
Jing Sun (141206)   +11 more
core   +1 more source

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