Results 51 to 60 of about 1,864 (182)

Closed‐Loop Recycling of Vinylogous Urethane Vitrimers

open access: yes, 2023
Devising energy-efficient strategies for the depolymerization of plastics and the recovery of their structural components in high yield and purity is key to a circular plastics economy. Here, we report a case study in which we demonstrate that vinylogous
Christoph Weder   +9 more
core   +1 more source

Assessment of Epoxy Functionalized Poly(dimethylsiloxane) Vitrimers Catalyzed with Covalently Attached Amines as Reversible Adhesives

open access: yesMacromolecular Materials and Engineering, 2022
In this work, vitrimeric elastomers based on functionalized poly(dimethylsiloxane) are realized. By exploiting reactions of epoxide functional groups with carboxylic acids in the presence of a covalently bonded amine catalyst, dynamic networks are formed
Florian Wanghofer   +3 more
doaj   +1 more source

Polylactide Vitrimers

open access: yes, 2015
While much research has been aimed at new approaches to the healing of cross-linked polymers, there is a dearth of effort in the healing of renewable cross-linked polymers.
Paula A. Delgado (1326468)   +2 more
core   +1 more source

A Review on Recent Trends of Bioinspired Soft Robotics: Actuators, Control Methods, Materials Selection, Sensors, Challenges, and Future Prospects

open access: yesAdvanced Intelligent Systems, Volume 7, Issue 3, March 2025.
This article reviews the current state of bioinspired soft robotics. The article discusses soft actuators, soft sensors, materials selection, and control methods used in bioinspired soft robotics. It also highlights the challenges and future prospects of this field.
Abhirup Sarker   +2 more
wiley   +1 more source

Catalyst-Free Vitrimers from Vinyl Polymers

open access: yes, 2019
Cross-linked networks feature exceptional chemical and mechanical resilience but consequently lack recyclability. Vitrimers have emerged as a class of materials that feature the robustness of thermosets and the recyclability of thermoplastics without ...
Charles P. Easterling (5806529)   +7 more
core   +1 more source

Fast Upcycling of Poly(ethylene terephthalate) into Catalyst-Free Vitrimers

open access: yes, 2023
We reported a catalyst-free technique to fabricate transesterification-based poly(ethylene terephthalate) (PET) vitrimers via melt reacting PET with N,N′-tetraglycidyldiaminodiphenyl methane (TGDDM) in several minutes. We investigated the effect of TGDDM
Shan-Song Wu   +7 more
core   +1 more source

On‐Demand Deconstructable Thermosets Through Cleavable Comonomer and Thermolatent Base Synergy

open access: yesAngewandte Chemie, Volume 138, Issue 41, 5 October 2026.
Thermosets, valued for their chemical and mechanical properties, resist recycling due to their cross‐linked structure. Weak bonds via comonomers enable degradability, but diffusion limits effectiveness. We incorporate thermolatent bases before polymerization (thermal or 3D‐VAT printing).
Sophia Kouider   +15 more
wiley   +2 more sources

High‐Performance Vitrimeric Benzoxazines for Sustainable Advanced Materials: Design, Synthesis, and Applications

open access: yesMacromolecular Materials and Engineering, 2023
Polybenzoxazines are high‐performance materials capable of replacing conventional thermosets such as phenolics, epoxies, and bismaleimides in composites manufacturing due to their excellent thermomechanical and chemical behavior.
Festus Ifeanyi Anagwu   +2 more
doaj   +1 more source

A Comprehensive Review on Additive Manufacturing of Smart Components: Technologies, Applications, and Future Scope

open access: yesAdvanced Intelligent Systems, EarlyView.
How can additive manufacturing enable components that sense, adapt, heal, and power themselves? This review synthesizes recent advances in smart functionalities, manufacturing technologies, and intelligent design strategies, revealing a pathway toward fully integrated, autonomous, and multifunctional systems across diverse engineering sectors. Additive
Aiswarya Rony   +3 more
wiley   +1 more source

Recyclable and Degradable Covalent Adaptable Polymer Networks (CANs) Based on Dynamic Thiol–Yne Reactions

open access: yesJournal of Applied Polymer Science, EarlyView.
Covalent adaptable networks based on activated alkynes, that is, alkynones, and multifunctional thiols (three and tetrafunctional) are tested in two different recycling strategies: (i) mechanical recycling based on their vitrimeric properties and (ii) chemical recycling based on the reversible thiol addition on the vinylene compound.
Farhad Shohraty   +6 more
wiley   +1 more source

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