Results 301 to 310 of about 736,654 (353)

Mitochondria‐Catalyzed Activation of Anticancer Prodrugs

open access: yesChemCatChem, Accepted Article.
Mitochondria mediate electron transport chain (ETC) to power ATP synthase. In cancer cells, the ETC is disturbed leading to leakage of electron that ultimately results in generation of H2O2. This difference between cancer and healthy cells can be used for the design of cancer‐specific prodrugs as confirmed in several proof‐of‐concept studies ...
Michael Raucheisen   +7 more
wiley   +1 more source

Rhodium‐Catalyzed Oxidative Alkenylation of Naphthalene: Factors That Influence Reaction at the β‐ versus α‐Position

open access: yesChemCatChem, EarlyView.
This study reports the direct oxidative alkenylation of naphthalene with olefins (ethylene and propylene) in the presence of a Rh(I) catalyst precursor and Cu(OPiv)2 as an oxidant. The regioselectivity of alkenylation (i.e., β‐ versus α‐functionalization) is highly variable based on reaction conditions.
Christopher W. Reid   +2 more
wiley   +1 more source

Effect of the Aromatic Content of Organosilica Supports on Aqueous Phase Phenol Hydrogenation

open access: yesChemCatChem, Accepted Article.
In this work, bridged polysilsesquioxanes with varying aromatic content were used as catalyst supports with active metal palladium (Pd) for aqueous phase phenol hydrogenation. Alkoxysilane precursors, bis (trimethoxy silyl ethyl) benzene (BTEB) and bis (tri methoxy silyl) ethane (BTE) were co‐condensed by sol‐gel synthesis to vary the aromatic content ...
Anagha Hunoor   +9 more
wiley   +1 more source

Phosphino(silyl) Nickel Complexes for Alkene Hydroboration Catalysis: Steric Tuning of Pre‐Catalyst Provides High Regioselectivity

open access: yesChemCatChem, Accepted Article.
Bis(phosphino)silyl nickel complexes featuring diethylphosphino donors on the tridentate PSiP ligand are effective pre‐catalysts for room temperature alkene hydroboration with HBPin. Terminal and geminal alkenes, including a wide scope of vinyl arenes, reacted to afford exclusively the linear, anti‐Markovnikov boronate ester product in all cases ...
Laura Turculet   +4 more
wiley   +1 more source

Integration of FTIR Spectroscopy, Volatile Compound Profiling, and Chemometric Techniques for Advanced Geographical and Varietal Analysis of Moroccan Eucalyptus Essential Oils. [PDF]

open access: yesSensors (Basel)
El Orche A   +9 more
europepmc   +1 more source

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