Results 41 to 50 of about 19,659 (164)

Ultrafast Dynamics of Excited Electronic States in Nitrobenzene Measured by Ultrafast Transient Polarization Spectroscopy. [PDF]

, 2019
We investigate ultrafast dynamics of the lowest singlet excited electronic state in liquid nitrobenzene using ultrafast transient polarization spectroscopy, extending the well-known technique of optical Kerr effect spectroscopy to excited electronic ...
Bakhti, Said, Belkacem, Ali, Brister, Matthew M, Champenois, Elio G, Muddukrishna, Pavan, Shivaram, Niranjan, Slaughter, Daniel S, Tan, Liang Z, Thurston, Richard, Weber, Thorsten   +9 more
core   +2 more sources

Surface‐Bound Superoxide Radical‐Mediated Photo‐Fenton Mineralization of Ciprofloxacin on Fe‐Sillenite Nanosheets

Advanced Science, EarlyView.
This study systematically compares the degradation efficiency of CIP in a H2O2‐alone system and a novel Bi12FeO20‐H2O2 photo‐Fenton system. It reveals for the first time the presence of a quinone‐imine intermediate in the H2O2‐alone system, which exhibits toxicity comparable to CIP.
Wenting Qiu, Ji Liu, Hengjun Shang, Yaning Zhang, Shuai Dou, Jing Xu, Ying Zhang, Yang Lou, Yongfa Zhu, Chengsi Pan   +9 more
wiley   +1 more source

The chemistry of ultrasonic degradation of organic compounds [PDF]

, 2011
The destruction of toxic organic molecules using advanced oxidation processes (AOPs) is a potent tool for pollution control and environmental protection.
Bremner, David H., Burgess, Arthur E., Chand, Rashmi   +2 more
core   +3 more sources

N,N,N’,N’-Tetrabutyl-1,10-phenanthroline-2,9-dicarboxamide as Very Effective Extraction Agent for Trivalent Europium and Americium

Acta Chimica Slovenica, 2017
Solvent extraction of microamounts of Eu3+ and Am3+ from water into nitrobenzene by means of a mixture of hydrogen dicarbollylcobaltate (H+B-) and N,N,N’,N’-tetrabutyl-1,10-phenanthroline-2,9-dicarboxamide (L) was studied.
Emanuel Makrlík, Petr Vaňura, Pavel Selucký, Vasily Babain, Dmitriy Dar'in, Mikhail Alyapyshev   +5 more
doaj   +1 more source

Eco‐Friendly Synthesis of Cobalt Phthalocyanine for High‐Efficiency CO2${\rm CO}_{2}$ Electroreduction

Chemistry – A European Journal, EarlyView.
A sustainable synthesis of cobalt phthalocyanine (CoPc) using low‐impact solvents yields high‐performance electrocatalysts with reduced waste (E‐factor 18.6). When integrated into gas diffusion electrodes, CoPc achieves up to 12% Faradays efficiency for CO2‐to‐methanol and 65% CO2‐to‐CO conversion, aligning with state‐of‐the‐art materials and enabling ...
Gloria Zanotti, Federica Palmeri, Venanzio Raglione, Abdolhamid Khodadadi, Camille Tabaries, Jerome Capitolis, Mathieu Prevot, Laurent Piccolo, Mahmoud Zendehdel, Roberto Flammini, Giorgio Contini   +10 more
wiley   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

Chemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve, Mariana Gomes Manso, Tibo Van Eeckhoorn, Mark E. Light, Bruno Linclau   +4 more
wiley   +1 more source

Selective solvation in aqueous mixtures: Interface deformations and instability

, 2012
We briefly review the effects of selective solvation of ions in aqueous mixtures, where the ion densities and the composition fluctuations are strongly coupled.
Araki, Takeaki, Onuki, Akira
core   +1 more source

Determination of Standard Gibbs Energies of Transfer of Organic Anions across the Water/Nitrobenzene Interface [PDF]

, 2002
The oxidation of decamethylferrocene dissolved in a nitrobenzene droplet and attached to a graphite electrode that is immersed in an aqueous electrolyte solution provides the basis to determine the standard Gibbs energies of transfer of simple organic ...
Komorsky-Lovrić, Šebojka, Riedl, Kai, Gulaboski, Rubin, Mirceski, Valentin, Scholz, Fritz   +4 more
core   +1 more source

Photocatalytic Vanadium‐Mediated Amination of Benzene With Hydroxylamine

Chemistry – A European Journal, EarlyView.
Photochemical activation of N‐phenylphenothiazine (PPT) enables a selective direct benzene amination with hydroxylamine in the presence of various vanadium catalysts under mild reaction conditions. Spectroscopic and kinetic analyses identify a key vanadium(IV)‐hydroxylamine intermediate, elucidate the crucial roles of the acidic medium, the ...
Dana Králová, Maximilian Philipp, Matthias Schmalzbauer, Thilo Reiter, Bernd Schäfer, Ruth M. Gschwind, Burkhard König   +6 more
wiley   +1 more source

Solvent extraction of some univalent cations into nitrobenzene solution of dicarbollylcobaltate and extractants containing two or three oxyamide groups

Results in Chemistry
Stability constants of the complexes of some commercially available ligands, containing two or three oxyamide groups in nitrobenzene have been determined from the extraction data.
Petr Vaňura, Pavel Selucký
doaj   +1 more source