Results 51 to 60 of about 19,659 (164)

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

Adsorption of Nitrobenzene from Water onto High Silica Zeolites and Regeneration by Ozone [PDF]

open access: yes, 2007
This work investigates the removal of nitrobenzene (NB), a model pollutant from water, by combining adsorption onto zeolites and regeneration with ozone.
Debellefontaine, Hubert   +3 more
core   +2 more sources

Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†

open access: yesChinese Journal of Chemistry, EarlyView.
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley   +1 more source

Extraction and DFT Study on the Complexation of Zn2+ with Beauvericin

open access: yesActa Chimica Slovenica, 2014
From extraction experiments and γ-activity measurements, the exchange extraction constant corresponding to the equilibrium Zn2+(aq) + 1 . Sr2+(nb) ⇔1 .
Emanuel Makrlík   +2 more
doaj  

Probing the mechanism of electron capture and electron transfer dissociation using tags with variable electron affinity [PDF]

open access: yes, 2009
Electron capture dissociation (ECD) and electron transfer dissociation (ETD) of doubly protonated electron affinity (EA)-tuned peptides were studied to further illuminate the mechanism of these processes. The model peptide FQpSEEQQQTEDELQDK, containing a
Beauchamp, J. L.   +5 more
core   +2 more sources

Engineered Metal–Organic Frameworks‐Based Materials for Environmental Detection

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Engineered metal–organic frameworks (MOFs) regulated by various material modification strategies are discussed for environmental contaminant detection under different sensing mechanisms, providing future improvements of MOFs in environmental detection. Sensitive and selective detection of contaminants is crucial for environmental protection.
Pan Gao   +3 more
wiley   +1 more source

Correlation Between the Molecular Structure of Metal‐Supporting Ligands and Catalysis in the Oxygenase‐Mimicking Immobilized Metal Complex Catalysts

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa   +8 more
wiley   +1 more source

Complexation of the Ammonium Cation with Dibenzo-18-crown-6: Extraction and DFT Study

open access: yesActa Chimica Slovenica, 2013
From extraction experiments and gamma-activity measurements, the extraction constan corresponding to the equilibrium NH4(+)(aq) + 1*Na(+)(nb) 1*NH4(+)(nb) + Na(+)(aq) taking place in the two-phase water - nitrobenzene system (1 = dibenzo-18-crown-6, aq
Emanuel Makrlík   +2 more
doaj  

Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley   +1 more source

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