Results 161 to 170 of about 6,133,717 (325)

A Cu‐Based Near‐IR Active MOF with an Ion‐Pair Guest Exhibiting Versatile and Selective Gas‐Solid Reactivity

open access: yesAdvanced Materials, EarlyView.
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha   +10 more
wiley   +1 more source

Structural Exploration of Zirconium Metal–Organic Frameworks Through Linker Desymmetrization and Modulator Compensation

open access: yesAdvanced Materials, EarlyView.
A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang   +8 more
wiley   +1 more source

COFs on MOFs: Layer‐by‐Layer Synthesis of MOF@COF Nanoparticles with Synergistic Adsorption

open access: yesAdvanced Materials, EarlyView.
A layer‐by‐layer strategy enables the growth of crystalline covalent organic framework (COF) shells on metal–organic framework nanoparticles, creating core–shell structures with tunable porosity. Ordered interstitial mesopores are formed during shell growth, which are connected with the COF's intrinsic micropores, thereby enhancing water sorption. This
Ana Guillem‐Navajas   +11 more
wiley   +1 more source

Hydrogel Thermostat Inspired by Photoprotective Foliage Using Latent and Radiative Heat Control

open access: yesAdvanced Materials, EarlyView.
Guided by Populus alba foliage, this hydrogel latent‐radiative thermostat (LRT) actively balances latent and radiative heat fluxes. An LRT switches solar reflectance, maintains high mid‐IR emissivity, and reversibly evaporates/regenerates water, while titanium oxide (TiO2) nanoparticles toughen the film.
Se‐Yeon Heo   +15 more
wiley   +1 more source

Prussian Blue Analog as a Functional Additive for Restoring Sulfide Solid Electrolytes: Enhancing Moisture Stability in All‐Solid‐State Batteries

open access: yesAdvanced Materials, EarlyView.
This work unveils the multifunctional roles of Prussian blue analogs (PBAs) within the LPSCl matrix, where they act as effective moisture scavengers and enable partial recovery of electrochemical performance. In addition, owing to their relatively soft nature, PBAs help mitigate interfacial stress and thereby enhance electrochemical stability and ...
Sumin Ko   +3 more
wiley   +1 more source

Modeling Water Sorption Capacity of Silica Gel

open access: yesEngineering Proceedings
Silica gel is a widely used desiccant with a high water sorption capacity, influenced by factors such as specific surface area, pore volume, and pore size.
Dragana Kešelj   +4 more
doaj   +1 more source

Anticaking methods for pharmaceutical grade salt : a thesis presented in partial fulfilment of the requirements for the degree of Master of Technology in BioProcess Engineering at Massey University [PDF]

open access: yes, 2005
This is an investigation into the causes of caking in the pharmaceutical grade salt produced by Dominion Salt Limited. It was found that the caking mechanism that occurs in sodium chloride is humidity caking.
Anthony, Kellie J
core  

A Biochar‐Based Composite Hydrogel Microenvironment for Enhanced Biocatalysis

open access: yesAdvanced Materials, EarlyView.
This work presents the synthesis of a polyacrylamide hydrogel wherein biomass‐derived biochar is co‐encapsulated with the enzyme horseradish peroxidase (HRP). The resulting composite hydrogel possesses balanced electron‐rich and electron‐deficient domains, creating an optimal microenvironment that concentrates both hydrogen peroxide and phenol ...
Shengzhe Wang   +9 more
wiley   +1 more source

Roadmap to Precision 3D Printing of Cellulose: Rheology‐Guided Formulation, Fidelity Assessment, and Application Horizons

open access: yesAdvanced Materials Technologies, EarlyView.
This critical review presents a comprehensive roadmap for the precision 3D printing of cellulose. Quantitative correlations link ink formulation and rheological properties to print fidelity and final material performance. This framework guides the development of advanced functional materials, from biomedical scaffolds to electromagnetic shielding ...
Majed Amini   +3 more
wiley   +1 more source

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