Results 111 to 120 of about 21,237 (271)

Is U3Ni3Sn4 best described as near a quantum critical point?

, 2003
Although most known non-Fermi liquid (NFL) materials are structurally or chemically disordered, the role of this disorder remains unclear. In particular, very few systems have been discovered that may be stoichiometric and well ordered.
Booth, C. H, De Long, L. E., Huber, J. G., Nenkov, K., Shlyk, L.   +4 more
core  

W‐N‐C Tandem Catalytic Centers Mediating Efficient Charge Transfer for the Enhanced Radical‐Path U(VI) Photoreduction

Advanced Science, EarlyView.
This work constructed a tandem W−N−C center to simultaneously achieve the regulation of reaction pathways and optimization of charge separation efficiency. The Lewis‐acidic W6+ sites activated O2 to generate O2−$O_2^ - $, with enhanced charge separation via electronic modulation, steering U(VI) reduction down an efficient radical pathway.
Zhiyao Wu, Jinhao Xu, Hao Fu, Yuxiang Deng, Nannan Wang, Wenhua Zhang, Peng Zhang, Zhiwei Huang, Zhenpeng Cui, Shu‐Xian Hu, Wangsuo Wu, Duoqiang Pan   +11 more
wiley   +1 more source

Selective Hydrogenation of Formamide to Methanol Over Supported Platinum Catalysts

Angewandte Chemie, EarlyView.
Amine–CO2 adducts can be hydrogenated to formamides and subsequently to methanol under mild conditions (<150°C), establishing an integrated CO2 capture‐and‐conversion route in a heterogeneous system that directly links amine sorbent cycling with methanol synthesis.
Xuetao Qin, XinXin Tian, Shou Qiu, Han Yan, Haijun Jiao, Henrik Junge, Matthias Beller   +6 more
wiley   +2 more sources

Mn‐Induced Support Stabilization and Ir Electronic Activation Enable Acid‐Stable, Low‐Loading IrO2 Water Oxidation

Advanced Science, EarlyView.
This study introduces a dual‐regulation strategy utilizing a Mn‐doped Co3O4 support to enhance the activity and stability of low‐loading IrO2 catalysts for acidic water oxidation. Mn induces strong Mn─O covalency to reinforce the spinel lattice and activates Ir sites via interfacial electron transfer.
Zhe Liu, Guoxin Ma, Shixiang Yu, Rui Jin, Fei Wang, Xinxin Wen, Mengxin Chen, Yani Ding, Jia Liu, Xinkai Guo, Diab Khalafallah, Hassan Fouad, Xiao Ren, Siwei Li   +13 more
wiley   +1 more source

Orbital and Electrical Dual Function of Polymer Intercalant for Promoting NH4+ Storage in Vanadium Oxide Anode

Advanced Energy Materials, Volume 15, Issue 11, March 18, 2025.
The impact of polyaniline insertion on the atomic orbitals and electronic structure of vanadium oxide anode is systematically investigated for the first time. The electrode exhibits an outstanding capacity and unprecedent long‐term cycling life, owing to the electron transition to the V 3dxy state and the enhanced diffusion kinetics.
Yue Zhang, Zihang Huang, Lei Lei, Hua Fan, Xu Han, Hui Li, Tianyi Ma   +6 more
wiley   +1 more source

Solar‐Driven Ammonia Synthesis From Nitrate Reduction Paired With CO2 Capture for Sustainable Agriculture via a Robust CuPd Heterojunction

Angewandte Chemie, EarlyView.
Laser‐assisted synthesis of CuPd amorphous/crystalline heterojunction demonstrates >80% Faradaic efficiency for nitrate‐to‐ammonia electroreduction across wide potential windows. The integrated solar‐powered electrolyzer achieves 6% solar‐to‐ammonia energy efficiency at 0.4 sun, 6–20 mg h−1 CO2 capture rate, and stability exceeding 100 h.
Weihua Guo, Xiaofeng Huang, Yangbo Ma, Yun Song, Zihao Li, Qiang Zhang, Yinger Xin, Jianjun Su, Mingming He, Ruixuan Wang, Rui Xue, Xing Li, Shibo Xi, Jian Wang, Shenlong Zhao, Siwei Zhang, Ben Zhong Tang, Alex K. Y. Jen, Ruquan Ye   +18 more
wiley   +2 more sources

Decoupling Chemical and Mechanical Contributions to Capacity Fading in Ni‐Rich Cathodes for Sulfide‐Based All‐Solid‐State Batteries

Advanced Energy Materials, EarlyView.
Ni‐rich cathodes in sulfide‐based ASSBs undergo intertwined (electro)chemical and mechanical degradation. Here, a new diagnostic framework is presented to decouple each contribution by partitioning capacity fading into charge and discharge fading.
Jangwhan Seok, Chanyou Chung, Hyunbeom Lee, Subin Ahn, Seongeun Lee, Sangbin Park, Sunhyun Hwang, Jaeyoung Kim, Jeonghyun Seo, Sungwoo Noh, Juyeong Seong, Sangheon Lee, Won‐Sub Yoon   +12 more
wiley   +1 more source

Self‐Activating Electrocatalysts for Water Splitting: Advancing Structure–Performance Understanding and Beyond

Advanced Energy Materials, EarlyView.
Self‐activating electrocatalysts offer strong potential for advanced water splitting, enabled by their dynamic compositional and structural evolution during operation. This review highlights recent advances in self‐activating OER and HER catalysts, emphasizing the driving forces and mechanisms underlying their adaptive behavior. A conceptual network of
Christean Nickel, Bahareh Feizi Mohazzab, Kiarash Torabi, David Leander Troglauer, Guillermo Corea, Shikang Han, Dandan Gao   +6 more
wiley   +1 more source

Spectroscopic and first-principles calculation studies of the chemical forms of palladium ion in nitric acid solution for development of disposal of high-level radioactive nuclear wastes

AIP Advances, 2018
We have investigated the chemical forms of palladium (Pd) ion in nitric acid solution, using XAFS/UV-vis spectroscopic and first-principles methods in order to develop the disposal of high-level radioactive nuclear liquid wastes (HLLW: radioactive metal ...
Shinta Watanabe, Toshikazu Sato, Tomoko Yoshida, Masato Nakaya, Masahito Yoshino, Takanori Nagasaki, Yusuke Inaba, Kenji Takeshita, Jun Onoe   +8 more
doaj   +1 more source

Operando X‐Ray Diffraction and Total Scattering Characterization of Battery Materials: Not Just a Pretty Picture

Advanced Energy Materials, EarlyView.
This review focuses on operando studies of battery materials by X‐ray diffraction (XRD) and total X‐ray scattering (TXS). This work highlights potential pitfalls and identify best‐practices for operando studies and reviews some unusual experiments to illustrate how these methods can be applied beyond the evaluation of the early‐stage cycling mechanisms
Amalie Skurtveit, Eira Tiberg North, Izar Capel Berdiell, Wouter Van Beek, David S. Wragg, Alexey Y. Koposov   +5 more
wiley   +1 more source