Results 231 to 240 of about 21,282 (312)

Ketal Protection of Glycerol for Selective Electrosynthesis of Glyceric Acid in Highly Alkaline Media

Angewandte Chemie, EarlyView.
Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang, Baokun Zhang, Kanglei Pang, Egon Campos dos Santos, Hong Liu, Mats Johnsson, Xiaowen Yu   +6 more
wiley   +1 more source

Dissolution of Fe(III)-rich basaltic glass in microbial cultures of iron-reducing microorganisms. [PDF]

Front Microbiol
Yunda E, Gorlas A, Guyot F, Testemale D, Daval D.   +4 more
europepmc   +1 more source

Single‐Atom Iron‐Catalyzed Oxidative Esterification: From Methylarenes to the Upcycling of Polystyrene and Lignin‐Derived Feedstocks

Angewandte Chemie, EarlyView.
Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma, Binyu Zhang, Hui Yang, Yue Hu, Junzheng Yu, Yanbin Cui, Jun Zhao, Matthias Beller, Rajenahally V. Jagadeesh   +8 more
wiley   +1 more source

Abiotic polycyclic aromatic hydrocarbons originating from the sub-oceanic mantle. [PDF]

Sci Rep
Mitsukawa I, Miyake A, Igami Y, Kogiso T, Akizawa N, Matsuno J, Matsumoto M, Tsuchiyama A, Uesugi K, Yasutake M, Taguchi T, Takahashi Y, Yamashita S, Okumura S.   +13 more
europepmc   +1 more source

Polarity‐Directed Synthesis of an Exfoliable 2D Polyoxometalate‐Based Metal‐Organic Framework for Noble Metal‐Free Alkyne Transfer Semi‐Hydrogenation

Angewandte Chemie, EarlyView.
Exfoliation of 2D nanosheets based on polyoxometalate metal‐organic frameworks (POMOFs) gives access to nanostructures with selective catalytic reactivity for the alkyne transfer semi‐hydrogenation which outperform the bulk references and rival some classical noble metal‐based catalysts.
Xusheng Dai, Yalei Zhang, Yue Zhao, Shujun Li, Nana Ma, Qingchun Xia, Yiwei Liu, Rongji Liu, Shuxia Liu, Xuenian Chen, Carsten Streb   +10 more
wiley   +1 more source

Tuning Defects in Ni-Doped Maghemite for Enhanced Solar Driven Oxygen Evolution: Insights From Operando X-Ray Spectroscopies. [PDF]

Adv Sci (Weinh)
Paparoni F, Magnan H, Barbier A, Zitolo A, Cicco A, Rezvani J, Fonda E.   +6 more
europepmc   +1 more source

Matching the Coupling of Valence Electrons in the Oxide Interface to Perturb the Magnetic Order Enhancing Oxygen Reduction in Zinc–Air Batteries

Angewandte Chemie, EarlyView.
Sub‐5 nm Fe2O3/Sm2O3 heterojunction nanoparticles are anchored on nitrogen‐doped carbon nanofibers, featuring coupled Fe(3d)‐O(2p)‐Sm(4f) orbitals at the interface. The resulting super‐exchange induces antiparallel magnetic ordering at heterointerfaces, suppressing spin‐dependent interaction between surface OH* species and Fe sites to facilitate OH ...
Jing Li, Ningkang Peng, Jianhua Ma, Tingyu Lu, Haibin Zhu, Guangyao Zhou, Yizhou Zhang, Yanhui Gu, Yawen Tang, Hao Li   +9 more
wiley   +1 more source

Probing Terra Incognita of Ni-P Catalysts: <i>Operando</i> Explorations during Hydrogen Evolution Reaction. [PDF]

J Am Chem Soc
Kong S, Soto E, Hong J, Davis R, Nelson E, Roddatis V, Lebedev OI, Zheng W, Odhiambo HW, Oh N, Upadhyay V, Spera NCM, Raturi D, Singh P, Ouyang G, Vila FD, Bare SR, Kolen'ko YV, Johnson DD, Kovnir K.   +19 more
europepmc   +1 more source

Strain Engineering via W–O–Ru Interfacial Coupling to Suppress Lattice Oxygen Activation for Stable Acidic Water Electrolysis

Angewandte Chemie, EarlyView.
Constructing atomically coupled W–O–Ru interfacial units on RuO2 triggers a dynamic strain evolution during the oxygen evolution reaction. An initial tensile strain secures structural stability, while a self‐adjusting transition to interfacial compression optimizes catalytic activity.
Yi Guan, Xiaozhang Yao, Ruiwen Qi, Xiangzhong Ren, Gaowa Liu, Zhongxin Song, Lei Zhang, Xueliang Sun   +7 more
wiley   +1 more source