Results 251 to 260 of about 21,282 (312)

Synergistic Regulation of Interfacial Potential and Anionic Covalency for High‐Voltage Cobalt‐Free All‐Solid‐State Batteries

open access: yesAngewandte Chemie, EarlyView.
A synergistic interface regulation strategy using high‐dielectric BaTiO3 and sulfate‐derived S─O bonds is developed to unlock high‐voltage LiNi0.5Mn1.5O4 all‐solid‐state batteries. By mitigating space‐charge layer effects and stabilizing lattice oxygen, the system achieves high‐rate (3 C) and durable operation in 5 V‐class cobalt‐free solid‐state ...
Yue Wang   +5 more
wiley   +1 more source

A Mononuclear Ruthenium(V)‐Imido Complex With Hydrogen Bonding in the Second Coordination Sphere Forming Aziridines Without N‐Substituents From Alkenes in Water

open access: yesAngewandte Chemie, EarlyView.
This study employs a RuV═NH complex with hydrogen‐bonding (HB) sites in the SCS to afford non‐N‐substituted aziridines selectively. Nitrogen‐atom transfer occurs from the RuV═NH complex to alkenes in water to produce aziridine derivatives in high yields.
Tomoya Ishizuka   +7 more
wiley   +1 more source

Controlling Exsolution Dynamics in High‐Entropy Oxides for Highly Active and Selective Acetylene Semi‐Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
Li+‐induced lattice distortion, valence variation, and local charge redistribution in a rock salt‐structured high‐entropy oxide enable controlled metal exsolution, altering the Cu–Ni–Co exsolution sequence and delivering a surface Cu0‐enriched catalyst with exceptional activity and ethylene selectivity for acetylene semi‐hydrogenation.
Hailing Yu   +17 more
wiley   +1 more source

X-ray absorption spectroscopy of scandium oxide polymorphs. [PDF]

open access: yesRSC Adv
Duarte-Ruiz D   +5 more
europepmc   +1 more source

Gold(III) Semiquinone Complexes: Synthesis, Structure, and Application in Photocatalysis

open access: yesAngewandte Chemie, EarlyView.
Au(III) catecholate complexes engage into electron donor acceptor (EDA) interactions with aryldiazonium salts, enabling single‐electron transfer under green light irradiation. Ligand‐centered one‐electron oxidation to stable semi‐quinone complexes provides a new platform for standalone Au(III) photoredox catalysis, as substantiated by the C–H arylation
Miguel A. Gonzálvez   +8 more
wiley   +1 more source

Single-Determinant Ground State in Ce<sup>4+</sup> Imidophosphorane Complexes. [PDF]

open access: yesInorg Chem
Tateyama H   +12 more
europepmc   +1 more source

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