Results 241 to 250 of about 21,282 (312)

Decoupling H‑Release and OH<sup>-</sup> Management at Pd@TiO<sub>2</sub> Interfaces for Efficient Alkaline Hydrogen Oxidation Reaction. [PDF]

open access: yesACS Catal
Jin B   +13 more
europepmc   +1 more source

Kooperative Redox‐Katalyse der N2O‐Zersetzung mittels auf Co3O4 geträgerten RhOx‐ und CeOx‐Spezies mit kurzreichweitiger Wechselwirkung

open access: yesAngewandte Chemie, EarlyView.
A short‐range Rh‐O‐Co‐O‐Ce interfacial moiety drives low‐temperature N2O decomposition via a cooperative redox cycle. Operando modulated‐excitation XAS with phase‐sensitive detection (ME‐XAS+PSD) tracks rapid, reversible Rh oxidation coupled to Co reduction. Combined kinetics and DFT rationalize the activity trends and identify the Rh‐O‐Co interface as
Daniel C. Cano‐Blanco   +7 more
wiley   +1 more source

A Decoupled Cycling Architecture of Asymmetric Zinc‐Air Battery Unlocks Stable Catalyst Strategy and pH‐Dynamic Influence

open access: yesAngewandte Chemie, EarlyView.
A decoupled cycling architecture along with cost‐effective membrane and efficient catalyst is developed for asymmetric zinc‐air battery. The decoupled design ensures stable operation of catalyst and the pH‐dynamic influence on battery performance is explored, which provides paths for efficient utilization of pH‐decoupling electrolytes.
Yeshu Tan   +6 more
wiley   +1 more source

Structural and chemical insights on the incorporation of americium into zircaloy-derived monoclinic zirconia. [PDF]

open access: yesCommun Chem
Murphy GL   +13 more
europepmc   +1 more source

Data‐ and Theory‐Guided Design of Dual‐Role V‐Doped RuO2 for High‐Performance Acidic Oxygen Evolution

open access: yesAngewandte Chemie, EarlyView.
A data‐ and theory‐guided paradigm, leveraging large‐scale data mining of 718 catalysts and microkinetic modeling, identifies V‐doped RuO2 as optimal for acidic OER. Vanadium doping drives electron withdrawal from Ru centers, generating Lewis acidic sites that polarize O–H bonds and accelerate deprotonation kinetics. Experimental validation achieves an
Zhongliang Liu   +10 more
wiley   +1 more source

Relevant Metal Oxidation States of MAO-Activated Chromium Catalysts for Ethylene Oligomerization. [PDF]

open access: yesInorg Chem
Allgaier A   +6 more
europepmc   +1 more source

Quantitative Photo‐Reforming of Biomass to CO Spurred by In Situ Protonation of Carbon Dioxide Radical Anions

open access: yesAngewandte Chemie, EarlyView.
A “two‐in‐one” photoreduction strategy enabled by electron‐rich yolk Cd species both remote from and adjacent to sulfur vacancies is delivered to be ultraselective for the reduction of O2 and •CO2− in situ formed on the shell Bi2S3 composition (hole) by water oxidation and oxidative C–C cleavage of various biomass organic acids, furnishing CO with > 99%
Tengyu Liu   +5 more
wiley   +1 more source

Shapeshifting exsolved FeNi bimetallic nanostructures as catalytic switchers during the CO<sub>2</sub>-mediated ethane conversion. [PDF]

open access: yesNat Commun
Colombo F   +10 more
europepmc   +1 more source

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