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《2019年诺贝尔化学奖的电化学解读》专辑导读 [PDF]

open access: yes, 2019
《2019年诺贝尔化学奖的电化学解读》专辑导读 2019年诺贝尔化学奖颁给了美国德克萨斯大学奥斯汀分校的约翰·古迪纳夫(John B. Goodenough)、美国纽约州立大学宾汉姆顿分校的斯坦利·惠廷厄姆(M. Stanley Whittingham)和日本旭化成公司的吉野彰(Akira Yoshino)三位科学家以表彰他们对锂电池研发的卓越贡献.
《电化学》编辑部
core  

强化混凝法去除腈纶废水中COD的机理研究

open access: yesGongye shui chuli, 2018
进行了强化混凝法去除腈纶废水中COD的研究。结果表明,铁碳微电解预氧化可提高混凝处理效果。通过对分子质量分布、Zeta电位及核磁共振波谱的测定发现,铁碳微电解的氧化作用可导致大分子有机物降解为小分子有机物,小分子有机物矿化,因此提高了分子质量>50 ku和<3 ku的有机物去除率;微电解产生的Fe2+有电性中和作用,使Zeta电位降低,强化混凝效果;微电解的氧化作用主要破坏酯类和醚类结构。
程爱华, 李杰, 王亚娥
doaj   +2 more sources

Dimensional Assembly Engineering of Ce‐MOF Interfaces for Selective Recognition of Phytic Acid

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT Selective molecular recognition is central to chemical sensing yet discriminating structurally similar molecules at complex interfaces remains challenging. Traditional strategies based on tuning size, charge, or binding‐site chemistry often suffer from limited flexibility.
Qiang Miao   +7 more
wiley   +1 more source

Guanidinium‐Based Covalent Organic Frameworks via Pore Wall Regulation: Efficient Selective Palladium Recovery From Metallurgical Wastewater

open access: yesRare Metals, Volume 45, Issue 5, May 2026.
ABSTRACT Recovering palladium (Pd) from low‐concentration metallurgical wastewater still poses significant challenges. In this study, triaminoguanidine hydrochloride was used as the key functional site, and three guanidine‐functionalized covalent organic frameworks (GCOFs) were successfully constructed by adjusting the substituents (–H, –OH, and –OCH3)
Jiaxing Xiong   +9 more
wiley   +1 more source

A Molten Salt Strategy to Convert Bulk Nb2O5 Into 2D Nonlayered Niobium Nitride Nanosheets for Superior Pseudocapacitive Storage

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT Two‐dimensional (2D) nonlayered niobium nitrides have attracted considerable interest for electrochemical energy storage. However, the synthesis of these materials is hampered by their nonlayered crystal structures, which are characterized by strong three‐dimensional chemical bonding.
Rui Huo   +7 more
wiley   +1 more source

Engineering a Tumor‐Targeted MgH2@Lip/PD‐L1 Nanoplatform for Synergistic Hydrogen Therapy and Immune Activation

open access: yesRare Metals, Volume 45, Issue 3, March 2026.
ABSTRACT Lung cancer remains the leading cause of cancer‐related deaths worldwide, yet immune checkpoint blockade (ICB) is often compromised by an immunosuppressive tumor microenvironment (TME) with acidosis, hypoxia, and poor T cell infiltration. Here, we develop a TME‐responsive nanoplatform (MgH2@Lip/PD‐L1) that couples hydrogen gas therapy with PD ...
Xuyu Gu   +5 more
wiley   +1 more source

带电更换悬垂绝缘子串等电位机器人

open access: yes, 2020
本实用新型涉及输电线路运行维护机器人,具体地说是一种带电更换悬垂绝缘子串等电位机器人。包括爬行机构及设置于爬行机构上的作业手臂Ⅰ、作业手臂Ⅱ及环形抱夹装置,其中环形抱夹装置位于作业手臂Ⅰ和作业手臂Ⅱ的上方,爬行机构可带动作业手臂Ⅰ、作业手臂Ⅱ及环形抱夹装置沿绝缘子串的高度方向运动;环形抱夹装置用于夹持绝缘子串进行定位;作业手臂I和作业手臂II配合完成输电线路绝缘子串的辅助更换作业任务。本实用新型代替等电位电工带电作业,保证了人员安全,同时装置本体在封闭的绝缘杆框架内工作,保证装置不会从高空脱落,安全性好,
王岩   +8 more
core  

基于流动电位法表征膜Zeta电位测试技术的研究进展

open access: yesGongye shui chuli
荷电膜因其具有特殊的分离性能受到广泛关注,随着人们对表征膜荷电性能的Zeta电位的认知加深,对Zeta电位的准确性提出了更高的要求。但是膜荷电性弱,且测量过程中易受操作方法、流道几何尺寸、溶液种类、溶液浓度等多种因素影响,导致Zeta电位测量误差大,准确性低。基于流动电位法,对Zeta电位及其测试技术进行了详细介绍,并对流道压差、流道几何尺寸、电解质溶液等测试工艺进行了总结,同时展望了进一步提高测试膜Zeta电位准确性、减少测试过程中不确定因素影响 ...
史志利
doaj   +2 more sources

MXene‐Assisted Bi2MoO6 Heterogeneous Structures: Constructing Oxygen Vacancy for Accelerated Energy Storage Devices

open access: yesRare Metals, Volume 45, Issue 1, January 2026.
ABSTRACT Two‐dimensional MXene‐based materials have recently attracted attention in supercapacitors and lithium ion batteries due to their excellent electrochemical performance. However, the capacity and agglomerate limits the development of MXene‐based materials.
Han Zhang   +4 more
wiley   +1 more source

Lewis Acid–Base Interactions Enable Sustained Catalytic Activity for Polysulfide Conversion in Lithium‐Sulfur Batteries

open access: yesRare Metals, Volume 45, Issue 1, January 2026.
ABSTRACT Lithium‐sulfur batteries (LSBs) face sluggish sulfur reduction reaction kinetics and severe polysulfide shuttling issues, which significantly limit their performance. In this work, a multifunctional separator with a 3D porous framework featuring confined pore structures and selective adsorption capability is constructed to address these ...
Mengchen Zhang   +12 more
wiley   +1 more source

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