Results 91 to 100 of about 81,401 (281)

Advantages of an Emulsion‐Produced Ziegler‐Natta Catalyst Over a Conventional Ziegler‐Natta Catalyst

open access: yesMacromolecular Materials and Engineering, 2005
AbstractSummary: Self‐supported and MgCl2‐supported Ziegler‐Natta catalysts, produced by two catalyst synthesis methods are compared. Borealis Polymers OY (Finland), who supplied the catalysts, developed the catalyst synthesis methods. The first method (Method One) is based on an emulsion system and consists of an in situ single step preparation.
Mohammed Abboud   +2 more
openaire   +1 more source

Threshold effect of residual catalyst on volume resistivity of polypropylene polymers

open access: yesHigh Voltage, Volume 10, Issue 4, Page 939-952, August 2025.
Abstract Polypropylene (PP) has become the focus of research and development of recyclable polymer dielectric materials because of its excellent electrical and thermal properties. The residual catalyst after PP polymerisation is the main part of ash. It was found that ash particles are uniformly dispersed in the PP matrix.
Xinhua Dong   +11 more
wiley   +1 more source

Effects of SUpport preparation on the perfonnance of the catalysts Ziegler-Natta based in TiCI4/MgCI2

open access: yesRevista Técnica de la Facultad de Ingeniería, 2011
The properties of supported Ziegler-Natta catalysts depend mostly on the preparation of the support. Four kinds of Ziegler-Natta catalysts consisting of TIC4 supported on MgCh were prepared, differting mainly by the method used to prepare the support ...
F. Medina   +4 more
doaj  

Tailoring polypropylene properties by package of internal/external donor in Ziegler Natta catalysts [PDF]

open access: yesPolyolefins Journal
Insights have been developed into the influence of different structures, including bismethoxymethylfluorene (B) and 2,2-diisopropyl succinate (I), on both internal donor (ID) and external donor (ED) roles on the performance of MgCl2/ID/TiCl4.
Nona Ghasemi Hamedani   +3 more
doaj   +1 more source

Heterogeneous Distribution of Entanglements in a Nonequilibrium Polymer Melt of UHMWPE: Influence on Crystallization without and with Graphene Oxide [PDF]

open access: yes, 2016
In the past, studies have been performed to follow chain dynamics in an equilibrium polymer melt using low molar mass polymers. Here we show that in linear ultrahigh molecular weight polyethylene entanglements formed during or after polymerization are ...
Dario Romano   +6 more
core   +4 more sources

Avaliação das condições de envelhecimento do sistema catalítico versatato de neodímio/hidreto de di-isobutilalumínio/cloreto de t-butila na polimerização de 1,3-butadieno

open access: yesPolímeros, 2014
O objetivo deste trabalho foi estudar sistemas catalíticos ternários constituídos por versatato de neodímio, cloreto de t-butila e hidreto de di-isobutil-alumínio para a polimerização de 1,4-cis de butadieno em hexano.
Neusa Maria Tocchetto Pires   +4 more
doaj   +1 more source

Bond Length - Bond Valence Relationships for Carbon - Carbon and Carbon - Oxygen Bonds [PDF]

open access: yes, 2015
In the present study, relationships are developed for determining bond orders (also referred to as bond valences or bond numbers) from published bond lengths for carbon-carbon (C-C) and carbon-oxygen (C-O) bonds.
Hardcastle, F. D., Harris, C.
core   +3 more sources

Electronic Properties of Ti Sites in Ziegler–Natta Catalysts

open access: yesACS Catalysis, 2021
A. Piovano   +8 more
semanticscholar   +1 more source

Principais aspectos da polimerização do 1,3-butadieno Principles aspects of butadiene 1,3 polymerization

open access: yesPolímeros, 2005
Atualmente, há uma grande demanda pelo polibutadieno com alto teor de unidades 1,4-cis, devido às suas excelentes propriedades físicas, tais como alta resistência à abrasão, baixo desenvolvimento de calor, baixa resistência ao rolamento, maior ...
Denise S. S. Nunes   +2 more
doaj   +1 more source

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