Preactive Site in Ziegler–Natta Catalysts [PDF]
Ziegler–Natta catalysts are one of the most important industrial catalysts for the production of isotactic polypropylene, yet they are still not properly understood at the molecular level.
E. S. Blaakmeer +4 more
semanticscholar +3 more sources
The Effects of Internal Electron Donors on MgCl2-Supported Ziegler-Natta Catalysts for Isotactic PP. [PDF]
Li B, Li H, Hu H, Zhou Y, Mao G, Xin S.
europepmc +2 more sources
Correction: In-chain functionalized syndiotactic 1,2-polybutadiene by a Ziegler-Natta iron(iii) catalytic system. [PDF]
Liang S +6 more
europepmc +3 more sources
Computational Study of Catalytic Poisoning Mechanisms in Polypropylene Polymerization: The Impact of Dimethylamine and Diethylamine on the Deactivation of Ziegler-Natta Catalysts and Co-Catalysts. [PDF]
Fernández JAH +2 more
europepmc +3 more sources
DFT and ONIOM Simulation of 1,3-Butadiene Polymerization Catalyzed by Neodymium-Based Ziegler-Natta System. [PDF]
Masliy AN +3 more
europepmc +3 more sources
Assessing 1,9-Decadiene/Ethylene Copolymerization with Ziegler–Natta Catalyst to Access Long Chain-Branched Polyethylene [PDF]
Yang Liu, Yawei Qin, Jin-Yong Dong
doaj +2 more sources
The influence of support in Ziegler-Natta catalysts for olefin polymerization
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A. Parada +3 more
doaj +1 more source
Despite decades of extensive studies, the atomic-scale structure of the active sites in heterogeneous Ziegler-Natta (ZN) catalysts, one of the most important processes of the chemical industry, remains elusive and a matter of debate. In the present work,
A. Ashuiev +12 more
semanticscholar +1 more source
The Use of Electron Donors to Increase Stereospecificity in Ziegler-Natta Propylene Polymerization [PDF]
Different chemical components in traditional Ziegler–Natta catalytic system include: (1) titanium and vanadium containing compounds, mostly TiCl4, as an active centre, (2) trialkylaluminium-based Lewis acid compounds, especially triethylaluminium, as ...
Farshid Nouri-Ahangarani +2 more
doaj +1 more source
Imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalysts for ethylene polymerization and ethylene/1-hexene copolymerization [PDF]
A novel imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalyst for ethylene and ethylene/1-hexene polymerization is investigated. The catalyst is prepared by modification of (SiO2/MgO/MgCl2)TiClx Ziegler-Natta catalysts via supporting vanadium ...
Ting Fu +5 more
doaj +1 more source

