Determination of kinetic parameters for ethylene polymerization (with and without hydrogen) by Ziegler-Natta catalyst. [PDF]
In this study, slurry polymerization kinetics of ethylene with TiCl4/Mg(OEt)2/AlR3 Ziegler-Natta catalysts in various conditions using the model of sum square error (SSE) (method I) and model of least square error (LSE) (Method II) was investigated.
Seyed Mehdi Ghafelebashi Zaranda +1 more
doaj +2 more sources
Síntese de catalisadores Ziegler-Natta: algumas rotas e suas dificuldades Synthesis of Ziegler-Natta catalysts: some routes and their difficulties [PDF]
The Ziegler-Natta catalyst and the polymerization thereof are systems which require careful handling and special treatment of chemicals. In spite of the use of inert atmosphere and dry chemicals, some Ziegler-Natta systems may present low activities or ...
Thaís H. S. Costa +4 more
doaj +2 more sources
Influence of the Ethanol Content of Adduct on the Comonomer Incorporation of Related Ziegler-Natta Catalysts in Propylene (Co)polymerizations. [PDF]
Mehdizadeh M +10 more
europepmc +3 more sources
The Effects of Internal Electron Donors on MgCl2-Supported Ziegler-Natta Catalysts for Isotactic PP. [PDF]
Li B, Li H, Hu H, Zhou Y, Mao G, Xin S.
europepmc +2 more sources
Correction: In-chain functionalized syndiotactic 1,2-polybutadiene by a Ziegler-Natta iron(iii) catalytic system. [PDF]
Liang S +6 more
europepmc +3 more sources
Computational Study of Catalytic Poisoning Mechanisms in Polypropylene Polymerization: The Impact of Dimethylamine and Diethylamine on the Deactivation of Ziegler-Natta Catalysts and Co-Catalysts. [PDF]
Fernández JAH +2 more
europepmc +3 more sources
DFT and ONIOM Simulation of 1,3-Butadiene Polymerization Catalyzed by Neodymium-Based Ziegler-Natta System. [PDF]
Masliy AN +3 more
europepmc +3 more sources
The Use of Electron Donors to Increase Stereospecificity in Ziegler-Natta Propylene Polymerization [PDF]
Different chemical components in traditional Ziegler–Natta catalytic system include: (1) titanium and vanadium containing compounds, mostly TiCl4, as an active centre, (2) trialkylaluminium-based Lewis acid compounds, especially triethylaluminium, as ...
Farshid Nouri-Ahangarani +2 more
doaj +1 more source
Imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalysts for ethylene polymerization and ethylene/1-hexene copolymerization [PDF]
A novel imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalyst for ethylene and ethylene/1-hexene polymerization is investigated. The catalyst is prepared by modification of (SiO2/MgO/MgCl2)TiClx Ziegler-Natta catalysts via supporting vanadium ...
Ting Fu +5 more
doaj +1 more source
The influence of support in Ziegler-Natta catalysts for olefin polymerization
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A. Parada +3 more
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