Beneficial influence of nanocarbon on the aryliminopyridylnickel chloride catalyzed ethylene polymerization [PDF]
, 2013 A series of 1-aryliminoethylpyridine ligands (L1―L3) was synthesized by condensation of 2-acetylpyridine with 1-aminonaphthalene, 2-aminoanthracene or 1-aminopyrene, respectively.
Durand, Jérôme +6 more
core +4 more sources
Immobilizing metallocene by solid polymethylaluminoxane “sMAO” for slurry-phase ethylene-1-hexene copolymerization [PDF]
MATEC Web of Conferences, 2022 In the field of olefin catalytic polymerization, metallocene catalysts show higher activity than traditional Ziegler-Natta catalysts. In this study, benzoic acid catalyzed the controlled hydrolysis of trimethylaluminum (TMA) to methylaluminoxane (MAO ...
Wu Chaofan +5 more
doaj +1 more source
Synthesizing polypropylene with percolation network catalyzed by inorganic nanoparticles-functionalized Ziegler-Natta catalyst [PDF]
Polyolefins JournalPolypropylene is one of the most widely used synthetic resins, which is mainly synthesized with Ziegler-Natta catalysts. In this paper, the functionalized Ziegler-Natta catalyst is applied to prepare high-performance polypropylene.
Tingting Yang +3 more
doaj +1 more source
Comparative simulation study of gas-phase propylene polymerization in fluidized bed reactors using aspen polymers and two phase models [PDF]
, 2012 A comparative study describing gas-phase propylene polymerization in fluidized-bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as
Hussaina M.A. +3 more
core +1 more source
イソニトリルの重合と金属錯体との反応に関する研究 [PDF]
, 2009 Trace amounts of Pt- and Ru-doped Ni/Mg(Al)O catalysts were prepared by a citrate method and tested in the oxidative reforming of C3H8 under daily start-up and shut-down (DSS) operation.
Li, Dalin +6 more
core +3 more sources
Preactive Site in Ziegler–Natta Catalysts [PDF]
The Journal of Physical Chemistry C, 2019 Ziegler–Natta catalysts are one of the most important industrial catalysts for the production of isotactic polypropylene, yet they are still not properly understood at the molecular level.
E. S. (Merijn) Blaakmeer +4 more
openaire +2 more sources
Química Nova, 1997 The Ziegler-Natta catalyst and the polymerization thereof are systems which require careful handling and special treatment of chemicals. In spite of the use of inert atmosphere and dry chemicals, some Ziegler-Natta systems may present low activities or ...
Thaís H. S. Costa +4 more
doaj +1 more source
What do We Know about Reaction Mechanism? The Electrospray Ionization Mass Spectrometry Approach [PDF]
, 2011 Santos, LS (reprint author), Univ Talca, Lab Asymmetr Synth, POB 747, Talca, Chile.Man's fascination with chemical reactions goes back to ancient times.
Santos, L.S.
core +2 more sources
Characterization of phthalate internal donor in MgCl2 supported Ziegler-Natta catalyst by solid state 13C NMR [PDF]
Polyolefins Journal, 2022 Ziegler-Natta catalyst for propylene polymerization, which TiCl4 and di-alkyl phthalate were supported on MgCl2, was analyzed by solid state 13C NMR. It was confirmed that the spin-lattice relaxation time (“relaxation time” hereafter) of carbonyl group ...
Masayoshi Saito +4 more
doaj +1 more source
Crystal structures and polymorphism of polymers: Influence of defects and disorder [PDF]
, 2018 The crystal structures and the polymorphism of polymers are described on the basis of the main principles that define the conformation of polymer chains in the crystalline state and the modes of packing of macromolecules.
Auriemma, Finizia +3 more
core +1 more source