Results 51 to 60 of about 81,401 (281)

In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst [PDF]

open access: yesPolyolefins Journal, 2014
A fourth-generation Ziegler-Natta catalyst was prepared to synthesize polypropylene (PP), which was stabilized by in situpolymerization employing lignin as antioxidant.
Maria Marques   +3 more
doaj   +1 more source

Electron Microscopy Transfer System to Protect Atmosphere‐Sensitive Materials for Scanning Electron Microscopy Characterization

open access: yesMicroscopy Research and Technique, EarlyView.
SEM–EDX and XRD characterization confirm that pouches made from readily available aluminum foil, used in combination with a commercial cryo‐EM transfer system, effectively protect highly atmosphere‐sensitive and/or hygroscopic materials from contamination during transfer from inert environments to the SEM vacuum chamber.
Louis G. Corcoran   +8 more
wiley   +1 more source

POLYMERIZATION OF STYRENE USING ZIEGLER – NATTA CATALYST TYPE TICL4/MGCL2 – EB /ALET3 [PDF]

open access: yesمجلة جامعة الانبار للعلوم الصرفة, 2013
In this study Ziegler – Natta catalyst was prepared which is a multi component catalytic system composed of, titaniumtetrachloride (TiCl4) as a active material, anhydrous magnesium chloride MgCl2 as support (carrier) which distribute the active material,
AYAD A. UTTAR, ALI S. ABED
doaj   +1 more source

Olefin Polymerizations Oriented by Rational Designs of Group‐13 Compounds

open access: yesThe Chemical Record, EarlyView.
In coordination olefin polymerization chemistry, boron and aluminum compounds play important roles in both catalyst components and monomers. This personal account introduces our recent progress on the development of catalyst systems featured by the design of group‐13 counteranions, as well as the application of boronic acid‐crosslinked polyolefins to ...
Ryo Tanaka, Yu Zou
wiley   +1 more source

Gas fluidized bed polymerization. [PDF]

open access: yes, 2017
Edição dos ...
GAMBETTA, R.   +2 more
core  

Developing Calibration Reference Materials and Standardized Protocols for Reliable DSC of Polyolefins

open access: yesJournal of Applied Polymer Science, Volume 143, Issue 3, January 15, 2026.
Standardized protocol for reducing T m standard deviation. ABSTRACT Differential scanning calorimetry (DSC) serves as a critical analytical tool in the polyolefin industry for quality control and product differentiation. Between 2000 and 2025, 7574 global patent applications referenced DSC data, highlighting its ubiquitous role in the industry.
Xingxing Zhang   +7 more
wiley   +1 more source

Molecular Weight Distributions in Ideal Polymerization Reactors. An Introductory Review [PDF]

open access: yes, 2011
The ultimate aim of polymerization reaction engineering is the production of polymers with tailor-made properties. An introductory review into this field is presented, with emphasis on the effects on the molar mass distribution (MMD), of the sought ...
Meira, Gregorio Raul, Oliva, H.
core  

Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes [PDF]

open access: yes, 2014
The reaction of the dialkyliron complex [Fe(CH2SiMe 3)2(MesBIP)] (MesBIP = 2,6-bis((N-mesityl)acetimidoyl)pyridine) with protic acids (HY) of different strengths (Y = C6F5O, CF3CO2, Cl, CF3SO3) invariably leads to the cleavage of both Fe-C bonds ...
Cartes Domínguez, María Ángeles   +4 more
core   +1 more source

Styrene Polymerization with Group III Metallocenes: A Generative and Interpretable Catalyst Design Strategy Combining Density Functional Theory and Machine Learning

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
Machine‐learning methods are used to predict styrene binding energies and insertion barriers in a series of group III cationic catalysts. A generative algorithm based on these predicted data is provided to propose new catalysts. The rational design of group III metallocene catalysts for styrene polymerization remains a complex challenge due to ...
Stella Christodoulou   +3 more
wiley   +1 more source

Rapid Methylation of Aryl Bromides Using Air‐Stable DABCO‐Bis(Trimethylaluminum) via Nickel Metallaphotoredox Catalysis

open access: yesAngewandte Chemie, Volume 137, Issue 33, August 11, 2025.
Herein, we report the use of bis(trimethylaluminum)‐1,4‐diazabicyclo[2.2.2]octane (DABAl‐Me3) as practical source of radicals for the introduction of valuable methyl groups to aryl bromides via a Nickel/metallaphotocatalytic cross coupling strategy.
Jonas Djossou   +8 more
wiley   +2 more sources

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