Results 51 to 60 of about 7,913 (200)

CHAIN REGULARITY OF ISOTACTIC POLYPROPYLENE DETERMINED BY DIFFERENT THERMAL FRACTIONATION METHODS [PDF]

, 2014
The chain regularity of isotactic polypropylene (iPP) homo- and random copolymers was characterized by different thermal fractionation methods in this study. Different stepwise temperature programs were applied in a calorimeter (DSC), in order to develop
Doshev, Petar, Gahleitner, Marcus, Horváth, Zsuzsanna, Menyhárd, Alfréd, Pukánszky, Béla, Tranninger, Cornelia, Varga, József   +6 more
core   +1 more source

Olefin Polymerizations Oriented by Rational Designs of Group‐13 Compounds

The Chemical Record, Volume 26, Issue 3, March 2026.
In coordination olefin polymerization chemistry, boron and aluminum compounds play important roles in both catalyst components and monomers. This personal account introduces our recent progress on the development of catalyst systems featured by the design of group‐13 counteranions, as well as the application of boronic acid‐crosslinked polyolefins to ...
Ryo Tanaka, Yu Zou
wiley   +1 more source

Theoretical Study of the Halogen Concentration Effect on the 1,3-Butadiene Polymerization Catalyzed by the Neodymium-Based Ziegler–Natta System

Reactions
In this work, an attempt is made to theoretically substantiate the experimentally known facts of the influence of halogen concentration on the catalytic properties of the neodymium-based Ziegler–Natta system.
Alexey N. Masliy, Ildar G. Akhmetov, Andrey M. Kuznetsov, Ilsiya M. Davletbaeva   +3 more
doaj   +1 more source

Gas phase polymerization of ethylene with a silica-supported metallocene catalyst: influence of temperature on deactivation [PDF]

, 1997
Ethylene was polymerized at 5 bar in a stirred powder bed reactor with silica supported rac-Me2Si[Ind]2ZrCl2/methylaluminoxane (MAO) at temperatures between 40°C and 80°C using NaCl as support bed and triethylaluminium (TEA) as a scavenger for impurities.
Meier, G.B., Roos, P., Samson, J.J.C., Samson, Job Jan C., Weickert, G., Westerterp, K.R.   +5 more
core   +2 more sources

PEDOT:PSS—A Key Material for Bioelectronics

Advanced Science, Volume 13, Issue 11, 23 February 2026.
PEDOT:PSS ‐ Poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate ‐ is typically processed from water dispersions to form multifunctional and multidimensional constructs with tunable electronic and ionic conductivity. Throught processing engineering, PEDOT:PSS is intergrated in bioelectronic devices that operate efficiently in physiological conditions
Alan Eduardo Ávila Ramírez, David Pieter van der Laan, Mustafeez Bashir Shah, Liwen Wang, Erica Zeglio, Achilleas Savva   +5 more
wiley   +1 more source

Functionalized Polyolefin With Photoresponsive Surface

ChemistryEurope, Volume 4, Issue 2, February 2026.
The introduction of stimulus‐responsive groups can give polymers some material properties that cannot be realized simply by design and synthesis. Polyolefins, due to their nonpolar nature, suffer from poor compatibility with polar materials; however, directly grafting polar groups like hydroxyls onto their surface via traditional synthesis risks ...
Qiuhui Tian, Zhiwei Xia, Yanyan Wang, Zhiyi Liu, Qiuping Chen, Yu Wang, Fuzhou Wang, Chen Tan   +7 more
wiley   +1 more source

Ti+4 determination in Ziegler–Natta polymerization catalysts via UV‒vis spectroscopy method [PDF]

Polyolefins Journal
The determination of Ti+4 in Ziegler–Natta catalysts is highly relevant for industrial plants that use Ziegler–Natta (ZN) catalysts based on TiCl4 as a source of titanium.
Jonas Biagini, Joao Henrique dos Santos
doaj   +1 more source

How can pH value during catalyst preparation affect the performance of vanadium-modified (SiO2/MgO/ MgCl2)•TiClx Ziegler-Natta polyethylene catalysts [PDF]

Polyolefins Journal, 2018
Vanadium-modified (SiO2/MgO/MgCl2)•TiClx Ziegler-Natta catalysts were prepared through co-impregnation of water-soluble magnesium and vanadium salts under different pH values.
Ting Fu, Ruihua Cheng, Xuelian He, Zhen Liu, Zhou Tian, Boping Liu   +5 more
doaj   +1 more source

Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes [PDF]

, 2014
The reaction of the dialkyliron complex [Fe(CH2SiMe 3)2(MesBIP)] (MesBIP = 2,6-bis((N-mesityl)acetimidoyl)pyridine) with protic acids (HY) of different strengths (Y = C6F5O, CF3CO2, Cl, CF3SO3) invariably leads to the cleavage of both Fe-C bonds ...
Cartes Domínguez, María Ángeles, Cámpora Pérez, Juan, Palma Ramírez, María del Pilar, Sandoval Valencia, John Jairo, Álvarez González, Eleuterio   +4 more
core   +1 more source

Developing Calibration Reference Materials and Standardized Protocols for Reliable DSC of Polyolefins

Journal of Applied Polymer Science, Volume 143, Issue 3, January 15, 2026.
Standardized protocol for reducing T m standard deviation. ABSTRACT Differential scanning calorimetry (DSC) serves as a critical analytical tool in the polyolefin industry for quality control and product differentiation. Between 2000 and 2025, 7574 global patent applications referenced DSC data, highlighting its ubiquitous role in the industry.
Xingxing Zhang, Lin Liu, Xuelei Duan, Zhe Zhou, Peiqian Yu, Yue Yu, Linfeng Chen, Rongjuan Cong   +7 more
wiley   +1 more source