Homogeneous vanadium-based catalysts for the Ziegler–Natta Polymerization of α-Olefins [PDF]
Chemical Society Reviews, 2002 Boersma, J., Hagen, H., van Koten, G.
core +3 more sources
The Effects of Internal Electron Donors on MgCl2-Supported Ziegler-Natta Catalysts for Isotactic PP. [PDF]
Polymers (Basel)Li B, Li H, Hu H, Zhou Y, Mao G, Xin S.
europepmc +2 more sources
Immobilizing metallocene by solid polymethylaluminoxane “sMAO” for slurry-phase ethylene-1-hexene copolymerization [PDF]
MATEC Web of Conferences, 2022 In the field of olefin catalytic polymerization, metallocene catalysts show higher activity than traditional Ziegler-Natta catalysts. In this study, benzoic acid catalyzed the controlled hydrolysis of trimethylaluminum (TMA) to methylaluminoxane (MAO ...
Wu Chaofan +5 more
doaj +1 more source
Synthesis of Isotactic Polybutene-1 with Ziegler-Natta Catalyst [PDF]
علوم و تکنولوژی پلیمر, 2022 Hypothesis: Butene-1 is in excess in the polyolefin plants of Iran. Considering the properties of isotactic polybutene-1, including high creep and environmental stress cracking resistances, excellent elastic reversibility and good chemical abrasion ...
shokoufeh Hakim +2 more
doaj +1 more source
Imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalysts for ethylene polymerization and ethylene/1-hexene copolymerization [PDF]
Polyolefins Journal, 2016 A novel imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalyst for ethylene and ethylene/1-hexene polymerization is investigated. The catalyst is prepared by modification of (SiO2/MgO/MgCl2)TiClx Ziegler-Natta catalysts via supporting vanadium ...
Ting Fu +5 more
doaj +1 more source
Dataset of energetically accessible structures of MgCl2/TiCl4 clusters for Ziegler-Natta catalysts
Data in Brief, 2021 This data article provides a dataset of the energetically accessible structures including the most stable structures of xMgCl2/yTiCl4 nanoplates (x = 6–19, y = 0–4).
Gentoku Takasao +5 more
doaj +1 more source
The Use of Electron Donors to Increase Stereospecificity in Ziegler-Natta Propylene Polymerization [PDF]
علوم و تکنولوژی پلیمر, 2016 Different chemical components in traditional Ziegler–Natta catalytic system include: (1) titanium and vanadium containing compounds, mostly TiCl4, as an active centre, (2) trialkylaluminium-based Lewis acid compounds, especially triethylaluminium, as ...
Farshid Nouri-Ahangarani +2 more
doaj +1 more source
A Study on the Effect of Catalyst Types on Microstructure of Ethylene/1-Hexene Copolymer by Thermal Fractionation [PDF]
علوم و تکنولوژی پلیمر, 2015 Olefinic copolymers of ethylene/1-hexene were synthesized by three main types of supported catalysts, including Philips, Ziegler-Natta and metallocene catalysts, and the specific microstructural features delivered by each class of the catalysts were ...
Seyed Mohammad Mehdi Mortazavi
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A Mathematical Model for Investigating the Effect of Reaction Temperature and Hydrogen Amount on the Catalyst Yield during Propylene Polymerization [PDF]
Kemija u Industriji, 2019 In this study, the effect of reaction temperature and hydrogen amount, as the most effective process variables on the Ziegler-Natta catalysts yield during propylene polymerization, was investigated with the aid of a validated mathematical model.
Gholam Hossain Varshouee +3 more
doaj +1 more source
Preactive Site in Ziegler–Natta Catalysts [PDF]
The Journal of Physical Chemistry C, 2019 Ziegler–Natta catalysts are one of the most important industrial catalysts for the production of isotactic polypropylene, yet they are still not properly understood at the molecular level.
E. S. (Merijn) Blaakmeer +4 more
openaire +2 more sources