The monopotassium salt of the ligand of a Ziegler–Natta catalyst [PDF]
, 1993 The anion of dipotassium (tert-butylamino)-dimethyl(tetramethylcyclopentadienyl)silanediide can coordinate to transition metals to form precursors for single-component Ziegler-Natta polymerization catalysts.
Bercaw, John E. +2 more
core +1 more source
Angewandte Chemie, Volume 138, Issue 15, 6 April 2026.Titanium silicalite‐1 (TS‐1), used in industrial selective oxidation processes, depends on specific, yet still unresolved Ti sites, dispersed within the framework of an MFI‐zeolite. Applying high field (28.2 T) 47/49Ti NMR and 17O NMR spectroscopy for an array of TS‐1 catalysts enables the development of an NMR crystallography protocol and the ...
Christoph J. Kaul +14 more
wiley +2 more sources
CHAIN REGULARITY OF ISOTACTIC POLYPROPYLENE DETERMINED BY DIFFERENT THERMAL FRACTIONATION METHODS [PDF]
, 2014 The chain regularity of isotactic polypropylene (iPP) homo- and random copolymers was characterized by different thermal fractionation methods in this study. Different stepwise temperature programs were applied in a calorimeter (DSC), in order to develop
Doshev, Petar +6 more
core +1 more source
اثر اصلاح کنند ه ها روی فعالیت کاتالیزورهای زیگلر-ناتا و خواص نهایی پلیمر در پلیمرشدن اولفین ها [PDF]
Baspārish, 2015 فعالیت کاتالیزور از مهم ترین پارامترها در فرایندهای پلیمرشدن است. برای یک سامانه کاتالیزوریفعالیت ممکن است به شرایط پلیمرشدن از قبیل دما و فشار وابسته باشد.
رضا بازوند +3 more
doaj +1 more source
Fragmentable Heterogeneous Cocatalysts for the Metallocene-Catalyzed Polymerization of Olefins, II [1]. Preparation, Characterization and Testing of the Cocatalysts and Microscopic Evaluation of the Polyethylene [PDF]
, 2005 Surface modified silica were reacted with different aluminiumalkyls AlR2R’ (R = Me, Et, i-Bu, R’ = H, Me, Et, i-Bu), oligomeric methylaluminoxane (MAO) and combinations of both, to yield heterogeneous cocatalysts.
Lange, Katharina C. H. +3 more
core +1 more source
Improving the efficiency of high-temperature processes for producing lower olefins via deep-processing of by-products [PDF]
, 2016 Processes for producing lower olefins are critically examined. It is noted that pyrolysis of various types of hydrocarbon is still the main process of obtaining ethylene and propylene, and is accompanied by the formation of considerable amounts of by ...
Bondaletov, Vladimir Grigoryevich +1 more
core +2 more sources
Employing Moment Equations Model to Study the Effect of Different Active Centers on Homopolymerization Kinetics of Ethylene [PDF]
علوم و تکنولوژی پلیمر, 2008 Ethylene was homopolymerized over Ziegler-Natta catalyst and the homopolymerization was modeled using moment equations. Mechanism was modeled according to five different reaction centers of catalyst.
M. Salami-Kalajahi +3 more
doaj +1 more source
Modeling intraparticle transports during propylene polymerizations using supported metallocene and dual function metallocene as catalysts: Single particle model [PDF]
, 2014 Two improved multigrain models (MGMs) for preparing homopolypropylene and long chain branched polypropylene via propylene polymerization using silica-supported metallocene or dual function metallocene as catalysts are presented in this paper ...
Che, Liming +4 more
core +1 more source
Copolymerization of Ethylene and Propylene Using 4th Generation Ziegler- Natta Catalyst: Influence of Cocatalyst, External Electron Donor and Hydrogen [PDF]
علوم و تکنولوژی پلیمر, 2007 Copolymerization of ethylene and propylene was investigated using a 4th generation phthalate Ziegler-Natta catalyst in normal hexane in a Buchi reactor.
R. Mehtarani +4 more
doaj +1 more source
Ultrasound- and microwave-assisted preparation of lead-free palladium catalysts: effects on the kinetics of diphenylacetylene semi-hydrogenation [PDF]
, 2015 The effect of environmentally benign enabling technologies such as ultrasound and microwaves on the preparation of the lead-free Pd catalyst has been studied.
Bonrath, Werner +6 more
core +1 more source