Results 41 to 50 of about 600,113 (211)

Silanolytic Chain Transfer in Olefin Polymerization with Supported Single-Site Ziegler−Natta Catalysts

open access: yes, 2016
Silanolytic Chain Transfer in Olefin Polymerization with Supported Single-Site Ziegler−Natta ...
Haruyuki Makio (1952404)   +2 more
core   +1 more source

Generation of Homogeneous (sp3-C1)-Bridged Cp/Amido and Cp/Phosphido Group 4 Metal Ziegler−Natta Catalyst Systems

open access: yes, 2016
Generation of Homogeneous (sp3-C1)-Bridged Cp/Amido and Cp/Phosphido Group 4 Metal Ziegler−Natta Catalyst ...
Klaus Kunz (2720305)   +4 more
core   +1 more source

Acetylene Semi‐Hydrogenation by Photocatalysis

open access: yesAngewandte Chemie, Volume 138, Issue 40, 28 September 2026.
Photocatalytic acetylene semi‐hydrogenation is an emerging light‐driven route to polymer‐grade ethylene, offering a mild alternative to energy‐intensive thermocatalysis. By replacing H2 co‐feed with water or other proton sources, these systems can achieve high selectivity under ambient conditions.
Anna Fortunato   +6 more
wiley   +2 more sources

Electrified Acetylene Removal From Ethylene Streams Enabled by Facet‐Engineered Cu–TiO2 Interfaces

open access: yesAngewandte Chemie International Edition, EarlyView.
Facet‐engineered interfaces enable selective electrochemical acetylene removal from ethylene streams. Dispersed Cu nanoclusters on the titania {001} facet suppress hydrogen and coupling byproducts, while stabilizing key hydrogenation intermediates.
Aocheng Hu   +6 more
wiley   +1 more source

Synthesis of polyethylene/exfoliated MoS2 nanocomposites by in situ exfoliation polymerization using Ziegler–Natta catalyst intercalated MoS2

open access: yes, 2017
A new synthetic route for polyethylene (PE)/exfoliated MoS2 (EMoS2) nanocomposites using novel Ziegler–Natta catalyst intercalated MoS2 was designed.
He-Xin Zhang   +2 more
core   +1 more source

Caracterização de polietilenos lineares de baixa densidade I.: determinação do teor de ramificação por métodos espectroscópicos Linear low density polyethylene characterization - I.: spectroscopic methods for comonomer content determination

open access: yesPolímeros, 2005
Os polietilenos lineares de baixa densidade (LLDPE) apresentam propriedades variando amplamente em função da concentração e do tipo de comonômero utilizado na copolimerização, além do tipo de catalisador.
Antonio C. Quental   +2 more
doaj   +1 more source

Ziegler-Natta Catalyst Preparation Process: Influential Parameters on Particles Morphology and Activity of Catalyst in Propylene Polymerization [PDF]

open access: yesعلوم و تکنولوژی پلیمر, 2013
Different parameters including temperature and amount of titanium tetrachloride (TiCl4) were examined with respect to Ziegler-Natta catalyst morphology and the catalyst performance during its preparation process.
Hassan Arabi   +3 more
doaj   +1 more source

One century of teaching, research, and innovation in chemical engineering in Mexico: The role of chemical engineering in the background and future of polymer science and industrial production in Mexico

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Timeline of key academic milestones and individuals that shaped chemical engineering at FQ‐UNAM and in Mexico. Abstract One hundred years after the beginning of the teaching of Chemical Engineering in Mexico, which started in 1925 in the former National School of Chemical Sciences, currently Faculty of Chemistry (FQ) at National Autonomous University ...
Patricia Pérez‐Salinas   +2 more
wiley   +1 more source

Influence of THF as Internal‐Donor on Ziegler‐Natta Polyethylene Catalysts

open access: yesMacromolecular Reaction Engineering, EarlyView.
Ziegler–Natta catalysts remain widely applied due to robustness, handling ease, and cost‐effectiveness. To support further optimization, we examine how internal donors such as tetrahydrofuran influence catalyst performance and polymer characteristics.
Alexander Mottl   +7 more
wiley   +1 more source

Extensional Rheology and Extrusion Blow Molding of Idealized High‐Density Polyethylene/Polypropylene Blends as Model Post‐Consumer Resins

open access: yesJournal of Polymer Science, EarlyView.
Compatibilization markedly improves the top‐load compression performance and structural integrity of HDPE/PP blow‐molded bottles. Neat HDPE, PP, and HDPE/PP bottles exhibit premature neck cracking at relatively low strains, whereas the compatibilized HDPE/PP/C blend sustains substantially higher loads and greater deformation without cracking ...
Gabe Cihlar   +4 more
wiley   +1 more source

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