Results 61 to 70 of about 700 (179)

Synthesis of High Isotactic and High Melt Flow Polypropylene in Liquid Propylene [PDF]

open access: yesعلوم و تکنولوژی پلیمر, 2007
This is a report on the study of high melt flow, highly isotactic polypropylene homopolymer synthesized in liquid monomer using a fifth generation Ziegler-Natta catalytic system.
M. Emami   +3 more
doaj   +1 more source

On the Bona Fide Sampling of Reaction Candidates in Red Moon Method by Replica‐Exchange Molecular Dynamics Method: REMD‐RM Method and Its Efficacy in Polymerization and Cross‐Linking Reactions of Polypropylene

open access: yesJournal of Computational Chemistry, Volume 47, Issue 7, March 15, 2026.
Schematic representation of the REMD‐RM method, which integrates the Red Moon (RM) method and the replica‐exchange molecular dynamics (REMD) method. By enhancing molecular reconfiguration and diffusion in the reactant system, the REMD‐RM method can efficiently explore a wide phase space and effectively accelerate the search for reaction candidates ...
Kentaro Matsumoto   +4 more
wiley   +1 more source

Paramagnetic species in Ziegler Natta catalysts

open access: yes, 2023
Abstract: This doctoral thesis investigates the nature and behavior of paramagnetic Ti(III) species in industrial Ziegler-Natta catalysts (ZNCs) used for the polymerization of polyethylene and polypropylene and is the result of a collaborative effort between the EPR laboratories of the University of Torino, the University of Antwerp and the Giulio ...
openaire   +2 more sources

Olefin Polymerizations Oriented by Rational Designs of Group‐13 Compounds

open access: yesThe Chemical Record, Volume 26, Issue 3, March 2026.
In coordination olefin polymerization chemistry, boron and aluminum compounds play important roles in both catalyst components and monomers. This personal account introduces our recent progress on the development of catalyst systems featured by the design of group‐13 counteranions, as well as the application of boronic acid‐crosslinked polyolefins to ...
Ryo Tanaka, Yu Zou
wiley   +1 more source

Influência do envelhecimento de catalisadores Ziegler-Natta à base de neodímio sobre a polimerização de 1,3-butadieno Influence of ageing of neodymium based Ziegler-Natta catalyst on butadiene polymerization

open access: yesPolímeros, 2007
Catalisadores envelhecidos em diferentes tempos (0, 5, 15, 40, 80 e 160 dias) e diferentes temperaturas (10, 25 e 40 °C) foram testados na polimerização 1,4-cis do 1,3-butadieno.
Ivana L. Mello   +3 more
doaj   +1 more source

PEDOT:PSS—A Key Material for Bioelectronics

open access: yesAdvanced Science, Volume 13, Issue 11, 23 February 2026.
PEDOT:PSS ‐ Poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate ‐ is typically processed from water dispersions to form multifunctional and multidimensional constructs with tunable electronic and ionic conductivity. Throught processing engineering, PEDOT:PSS is intergrated in bioelectronic devices that operate efficiently in physiological conditions
Alan Eduardo Ávila Ramírez   +5 more
wiley   +1 more source

Preparation of Ultrahigh Molecular Weight Polyethylene/Graphene Nanocomposite In situ Polymerization via Spherical and Sandwich Structure Graphene/Sio2 Support

open access: yesNanoscale Research Letters, 2018
Reduced graphene oxide/SiO2 (RGO/SiO2) serving as a novel spherical support for Ziegler-Natta (Z-N) catalyst is reported. The surface and interior of the support has a porous architecture formed by RGO/SiO2 sandwich structure.
Enqi Su   +7 more
doaj   +1 more source

Functionalized Polyolefin With Photoresponsive Surface

open access: yesChemistryEurope, Volume 4, Issue 2, February 2026.
The introduction of stimulus‐responsive groups can give polymers some material properties that cannot be realized simply by design and synthesis. Polyolefins, due to their nonpolar nature, suffer from poor compatibility with polar materials; however, directly grafting polar groups like hydroxyls onto their surface via traditional synthesis risks ...
Qiuhui Tian   +7 more
wiley   +1 more source

Principais aspectos da polimerização do 1,3-butadieno Principles aspects of butadiene 1,3 polymerization

open access: yesPolímeros, 2005
Atualmente, há uma grande demanda pelo polibutadieno com alto teor de unidades 1,4-cis, devido às suas excelentes propriedades físicas, tais como alta resistência à abrasão, baixo desenvolvimento de calor, baixa resistência ao rolamento, maior ...
Denise S. S. Nunes   +2 more
doaj   +1 more source

Polimerização 1,4 - cis de butadieno com o sistema catalítico tetracloreto de titânio/triisobutilalumínio/iodo 1,4 cis-Polymerization of butadiene by the catalyst system titanium tetrachloride/triisobutylaluminium/iodine

open access: yesPolímeros, 2000
Foi utilizado o sistema catalítico tipo Ziegler-Natta modificado, constituído por TiCl4/I2/Al(i-Bu)3 para a síntese de polibutadieno com alto teor de unidades 1,4-cis.
Neusa M. T. Pires   +2 more
doaj   +1 more source

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