Results 61 to 70 of about 700 (179)
Synthesis of High Isotactic and High Melt Flow Polypropylene in Liquid Propylene [PDF]
This is a report on the study of high melt flow, highly isotactic polypropylene homopolymer synthesized in liquid monomer using a fifth generation Ziegler-Natta catalytic system.
M. Emami +3 more
doaj +1 more source
Schematic representation of the REMD‐RM method, which integrates the Red Moon (RM) method and the replica‐exchange molecular dynamics (REMD) method. By enhancing molecular reconfiguration and diffusion in the reactant system, the REMD‐RM method can efficiently explore a wide phase space and effectively accelerate the search for reaction candidates ...
Kentaro Matsumoto +4 more
wiley +1 more source
Paramagnetic species in Ziegler Natta catalysts
Abstract: This doctoral thesis investigates the nature and behavior of paramagnetic Ti(III) species in industrial Ziegler-Natta catalysts (ZNCs) used for the polymerization of polyethylene and polypropylene and is the result of a collaborative effort between the EPR laboratories of the University of Torino, the University of Antwerp and the Giulio ...
openaire +2 more sources
Olefin Polymerizations Oriented by Rational Designs of Group‐13 Compounds
In coordination olefin polymerization chemistry, boron and aluminum compounds play important roles in both catalyst components and monomers. This personal account introduces our recent progress on the development of catalyst systems featured by the design of group‐13 counteranions, as well as the application of boronic acid‐crosslinked polyolefins to ...
Ryo Tanaka, Yu Zou
wiley +1 more source
Catalisadores envelhecidos em diferentes tempos (0, 5, 15, 40, 80 e 160 dias) e diferentes temperaturas (10, 25 e 40 °C) foram testados na polimerização 1,4-cis do 1,3-butadieno.
Ivana L. Mello +3 more
doaj +1 more source
PEDOT:PSS—A Key Material for Bioelectronics
PEDOT:PSS ‐ Poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate ‐ is typically processed from water dispersions to form multifunctional and multidimensional constructs with tunable electronic and ionic conductivity. Throught processing engineering, PEDOT:PSS is intergrated in bioelectronic devices that operate efficiently in physiological conditions
Alan Eduardo Ávila Ramírez +5 more
wiley +1 more source
Reduced graphene oxide/SiO2 (RGO/SiO2) serving as a novel spherical support for Ziegler-Natta (Z-N) catalyst is reported. The surface and interior of the support has a porous architecture formed by RGO/SiO2 sandwich structure.
Enqi Su +7 more
doaj +1 more source
Functionalized Polyolefin With Photoresponsive Surface
The introduction of stimulus‐responsive groups can give polymers some material properties that cannot be realized simply by design and synthesis. Polyolefins, due to their nonpolar nature, suffer from poor compatibility with polar materials; however, directly grafting polar groups like hydroxyls onto their surface via traditional synthesis risks ...
Qiuhui Tian +7 more
wiley +1 more source
Atualmente, há uma grande demanda pelo polibutadieno com alto teor de unidades 1,4-cis, devido às suas excelentes propriedades físicas, tais como alta resistência à abrasão, baixo desenvolvimento de calor, baixa resistência ao rolamento, maior ...
Denise S. S. Nunes +2 more
doaj +1 more source
Foi utilizado o sistema catalítico tipo Ziegler-Natta modificado, constituído por TiCl4/I2/Al(i-Bu)3 para a síntese de polibutadieno com alto teor de unidades 1,4-cis.
Neusa M. T. Pires +2 more
doaj +1 more source

