Results 51 to 60 of about 2,075 (218)

Study of Ziegler-Natta /Metallocene Hybrid Catalyst on Pilot Device

open access: yes, 2011
In this work, Ziegler-Natta/Metallocene hybrid catalyst (Z-M) was prepared magnifying. The activity and copolymerization behavior of the catalyst were evaluated through 10L model device.
Jun Ji Jia   +4 more
core   +1 more source

Ziegler-Natta Catalyst Preparation Process: Influential Parameters on Particles Morphology and Activity of Catalyst in Propylene Polymerization [PDF]

open access: yesعلوم و تکنولوژی پلیمر, 2013
Different parameters including temperature and amount of titanium tetrachloride (TiCl4) were examined with respect to Ziegler-Natta catalyst morphology and the catalyst performance during its preparation process.
Hassan Arabi   +3 more
doaj   +1 more source

Visible‐Light Driven Acetylene Semi‐Hydrogenation to Ethylene With a Copper Photosensitizer and a Cobaloxime Catalyst

open access: yesChemistry – A European Journal, EarlyView.
A fully noble‐metal‐free photocatalytic system that couples cobaloxime catalysis with Cu photosensitizer for HAT‐driven acetylene‐to‐ethylene conversion is reported. ABSTRACT The purification of ethylene streams from acetylene impurities remains a key industrial challenge, for which light‐powered strategies are emerging as sustainable alternatives to ...
Anna Fortunato   +5 more
wiley   +1 more source

Impact of Commercial Polyolefin Architecture and Composition on Its Ability to Compatibilize High‐Density Polyethylene/Isotactic Polypropylene Blends

open access: yesJournal of Polymer Science, EarlyView.
This research elucidates the relationship between the molecular structure of commercially available ethylene–propylene copolymers and an ethylene/1‐olefin copolymer and its ability to compatibilize high‐density polyethylene/isotactic polypropylene blends. These findings indicate that the compatibilization of these blends with random copolymers benefits
Bailey Eberle   +3 more
wiley   +1 more source

Caracterização de polietilenos lineares de baixa densidade I.: determinação do teor de ramificação por métodos espectroscópicos Linear low density polyethylene characterization - I.: spectroscopic methods for comonomer content determination

open access: yesPolímeros, 2005
Os polietilenos lineares de baixa densidade (LLDPE) apresentam propriedades variando amplamente em função da concentração e do tipo de comonômero utilizado na copolimerização, além do tipo de catalisador.
Antonio C. Quental   +2 more
doaj   +1 more source

Cyclic Olefin Copolymers as Versatile Materials for Advanced Engineering Applications

open access: yesAdvanced Functional Materials, Volume 36, Issue 47, 11 June 2026.
Cyclic olefin copolymers (COCs) are presented as highly versatile materials combining tunable synthesis, excellent optical properties, and mechanical robustness. Their potential spans microfluidics, bioengineering, and advanced electronics, while emerging self‐healing and sustainable solutions highlight future opportunities.
Giulia Fredi   +3 more
wiley   +1 more source

“Naked” Divalent Metal Cations Stabilized by Weakly Coordinating Anions: Syntheses, Properties, and Emerging Applications

open access: yesEuropean Journal of Inorganic Chemistry, Volume 29, Issue 14, 14 May 2026.
The preparation of soluble and stable metal M2+ dications only stabilized by weakly coordinating anions, that is, M[WCA]2 salts, is an emerging field that, beyond its fundamental interest, holds promise in reactivity due to the high electrophilicity of the central M2+ center.
Samuel Dagorne   +3 more
wiley   +1 more source

Process Modeling for Propylene Polymerization to Transfer Reaction Kinetics From Lab to Plant

open access: yesChemie Ingenieur Technik, Volume 98, Issue 5, Page 254-261, May 2026.
The modeling approach combines an industrial model for a fourth‐generation Ziegler–Natta catalyst with lab‐scale derived kinetics of a novel fifth‐generation catalyst. By transferring intrinsic kinetics across scales, polypropylene production can be predicted. Accurate melt flow rate prediction is only obtained with an additional adjustment.
Anna Konopka   +5 more
wiley   +1 more source

Electron Microscopy Transfer System to Protect Atmosphere‐Sensitive Materials for Scanning Electron Microscopy Characterization

open access: yesMicroscopy Research and Technique, Volume 89, Issue 5, Page 759-768, May 2026.
SEM–EDX and XRD characterization confirm that pouches made from readily available aluminum foil, used in combination with a commercial cryo‐EM transfer system, effectively protect highly atmosphere‐sensitive and/or hygroscopic materials from contamination during transfer from inert environments to the SEM vacuum chamber.
Louis G. Corcoran   +8 more
wiley   +1 more source

"Supported Ziegler-Natta catalysts from MgCl2·nROH precursors and its catalytic behaviors for diene copolymerization"

open access: yesHecheng xiangjiao gongye
The precursor MgCl2 · nROH of supported Ziegler Natta catalyst was prepared by chemical activation method, and different pre catalysts TiCl4/MgCl2 (C-Cat) were prepared by loading TiCl4.
FAN Xun-zhang, ZHAO Yuan-jin, LUO Shu-fang, HE Ai-hua?
doaj   +1 more source

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