Results 71 to 80 of about 6,795 (264)

Propylene–Ethylene Copolymer Covalent Adaptable Networks Synthesized by Resonance‐Stabilized, Radical‐Based Reactive Processing with Excellent Elevated‐Temperature Creep Resistance

ChemSusChem, Volume 18, Issue 20, October 23, 2025.
Propylene‐ethylene copolymer covalent adaptable networks (PEC CANs) are synthesized via one‐step, radical‐based reactive processing with the use of initiator, dynamic cross‐linkers, and vinyl aromatic additives. The best CAN suppresses over 98% of creep at 100 °C (semicrystalline state) for 10,000 s compared to neat PEC.
Yen‐Wen Huang, Mathew J. Suazo, Stephanie M. Barbon, Hayley A. Brown, Evelyn Auyeung, Colin Li Pi Shan, John M. Torkelson   +6 more
wiley   +1 more source

An Investigation on Polymerization of Ethylene by Ziegler-Natta Catalyst in the Presence of a Promoter: Polymerization Behavior and Polymer Microstructure

Bulletin of Chemical Reaction Engineering & Catalysis, 2018
The effect of a halocarbon (ethyl chloride) as a promoter on a Ziegler-Natta catalyst composed of‌ T‌iCl4 (catalyst), AlEt3 (activator) and Mg(OEt)2 (support) in the polymerization of ethylene have been investigated.
Yaghoob Gholami, Majid Abdouss, Sadegh Abedi, Farhad Azadi, Pezhman Baniani, Maryam Arsalanfar   +5 more
doaj   +1 more source

A Practical Guide to Heterogeneous Catalysis in Hydrocarbon Transformations

Chemistry – An Asian Journal, Volume 20, Issue 20, October 17, 2025.
A focused overview of the catalytic processing of hydrocarbons to transform them into more valuable compounds is presented. This work is intended to assist BSc, MSc, and PhD students, as well as junior researchers, in selecting and performing appropriate heterogeneous catalytic processes for specific heterogeneous catalytic reactions.
Kelvin A. Sanoja‐Lopez, Alina M. Balu, Héctor de Paz Carmona, Martin Hájek, Rafael Luque, José Miguel Hidalgo Herrador   +5 more
wiley   +1 more source

Sixtieth Anniversary of Ziegler-Natta Catalysts and Stereospecific Polymerization [PDF]

Kemija u Industriji, 2015
This review article highlights the history of the discoveries of organometallic catalysts and stereospecific polymerization of α-olefins, dienes and a number of vinyl monomers by Karl Ziegler and Giulio Natta sixty years ago, their developments and ...
Janović Z. , Veksli Z.
doaj  

MgCl2 Support Preparation Techniques and Their Effects on Ziegler-Natta Catalysts Performance in Propylene Polymerization [PDF]

علوم و تکنولوژی پلیمر, 2013
A primary adduct of MgCl2.3.3EtOH (A0) was prepared by melt quenching and then it was further dealcoholated by thermal and chemical methods. In thermal dealcoholation, two different support samples with MgCl2.2.7EtOH (A1) and MgCl2.1.8EtOH (A2) formulas ...
Najmeh Hadian, Mehdi Nekoomanesh-Haghighi, Shokoofeh Hakim, Naeimeh Bahri-Laleh   +3 more
doaj   +1 more source

Vapor Deposition of Polymer Structures: From 2D Surface Coatings and Surface Microstructures to 3D Building Blocks and Structural Monoliths

Macromolecular Rapid Communications, Volume 46, Issue 20, October 20, 2025.
This review discusses the progress of vapor‐deposited polymer structures, from simple thin films and surface microstructures to complex 3D architectures and monoliths. It covers fabrication methods, polymerization mechanisms, and processes for fabricating these structures. The applications of these polymers are discussed, focusing on device integration
Theresia Cecylia Ramli, Chung‐Ju Chen, Hui‐Hsuan Wang, Chi‐Yen Tsao, I‐Chen Hsu, Hung‐Jui Ting, Hsien‐Yeh Chen   +6 more
wiley   +1 more source

Ti+4 determination in Ziegler–Natta polymerization catalysts via UV‒vis spectroscopy method [PDF]

Polyolefins Journal
The determination of Ti+4 in Ziegler–Natta catalysts is highly relevant for industrial plants that use Ziegler–Natta (ZN) catalysts based on TiCl4 as a source of titanium.
Jonas Biagini, Joao Henrique dos Santos
doaj   +1 more source

Study of Ethylene Polymerization Kinetics by TiCl4/Mg(OC2H5)2 Catalyst and Determination of the Active Sites Concentration [PDF]

علوم و تکنولوژی پلیمر, 2008
Ethylene was polymerized in slurry phase over a TiCl4/Mg(OC2H5)2 catalyst activated by Al(C2H5)3. It was shown experimentally that mass transfer resistance has no effect on polymerization kinetics.
S. Hakim, M.M. Mortazavi
doaj   +1 more source

Synthesis of High Isotactic and High Melt Flow Polypropylene in Liquid Propylene [PDF]

علوم و تکنولوژی پلیمر, 2007
This is a report on the study of high melt flow, highly isotactic polypropylene homopolymer synthesized in liquid monomer using a fifth generation Ziegler-Natta catalytic system.
M. Emami, R. Mehtarani, M. Sadati, F. Hormozi   +3 more
doaj   +1 more source

50th Anniversary Perspective: Living Polymerization—Emphasizing the Molecule in Macromolecules [PDF]

, 2017
The ideal of living polymerization has defined research in polymer chemistry over the past 50 years. In this Perspective, we present the case that this concept has enabled the treatment of polymers as organic molecules, rather than impure mixtures of ...
Grubbs, Robert B., Grubbs, Robert H.
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