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Tailoring desolvation kinetics enables stable zinc metal anodes

Journal of Materials Chemistry A, 2020
The solvation structure of Zn2+ is regulated through incorporating acetonitrile (AN) into the electrolyte, elevating nucleation sites and stablizing zinc metal anode, as revealed by the complementary theoretical and experimental studies.
Zhen Hou   +5 more
openaire   +2 more sources

Surface Engineering on Zinc Anode for Aqueous Zinc Metal Batteries

ChemSusChem
AbstractRechargeable aqueous zinc metal batteries (AZMBs) are considered as a potential alternative to lithium‐ion batteries due to their low cost, high safety, and environmental friendliness. However, the Zn anodes in AZMBs face severe challenges, such as dendrite growth, metal corrosion, and hydrogen evolution, all of which are closely related to the
Huili Peng   +5 more
openaire   +2 more sources

Surface Transformation Enables a Dendrite‐Free Zinc‐Metal Anode in Nonaqueous Electrolyte

Advances in Materials, 2022
Significant challenges remain in developing rechargeable zinc batteries mainly because of reversibility problems on zinc‐metal anodes. The dendritic growth and hydrogen evolution on zinc electrodes are major obstacles to overcome in developing practical ...
Fanyang Huang   +16 more
semanticscholar   +1 more source

Bulk‐Phase Reconstruction Enables Robust Zinc Metal Anodes for Aqueous Zinc‐Ion Batteries

Angewandte Chemie, 2023
AbstractAqueous zinc‐ion batteries are inherently safe, but the severe dendrite growth and corrosion reaction on zinc anodes greatly hinder their practical applications. Most of the strategies for zinc anode modification refer to the research of lithium metal anodes on surface regulation without considering the intrinsic mechanisms of zinc anode ...
Zefang Yang   +8 more
openaire   +2 more sources

Helmholtz Plane Reconfiguration Enables Robust Zinc Metal Anode in Aqueous Zinc‐Ion Batteries

Advanced Functional Materials
Aqueous zinc‐ion batteries are promising for next‐generation energy storage systems. However, the zinc dendrite growth, corrosion, and hydrogen evolution reaction at the electrochemical interface severely impede their further development.
Tingqing Wu   +8 more
semanticscholar   +1 more source

Cotton-derived cellulose film as a dendrite-inhibiting separator to stabilize the zinc metal anode of aqueous zinc ion batteries

Energy Storage Materials, 2021
Benefiting from high safety, low cost, and competitive energy density, aqueous zinc-ion batteries (AZIBs) have become a very promising technique for grid-scale energy storage.
Weijun Zhou   +5 more
semanticscholar   +1 more source

Highly Compact Zinc Metal Anode and Wide‐Temperature Aqueous Electrolyte Enabled by Acetamide Additives for Deep Cycling Zn Batteries

Advanced Functional Materials
Rechargeable aqueous zinc (Zn) batteries are a promising candidate for large‐scale energy storage, but the noncompact and dendritic Zn deposition, water‐induced parasitic reaction, and narrow operating temperature range severely hinder their practical ...
Kaiyue Qiu   +9 more
semanticscholar   +1 more source

Successive Gradient Internal Electric Field Strategy Toward Dendrite‐Free Zinc Metal Anode

Advanced Energy Materials, 2023
With the rapidly increasing demand for grid‐scale energy storage systems, rechargeable aqueous zinc ion batteries (ZIBs) are capturing attention as a highly promising technology with low cost and high safety.
Yanxin Li   +7 more
semanticscholar   +1 more source

Oriented Metal Stripping for Highly Reversible Zinc Anode

Small
AbstractAqueous zinc metal batteries are a viable candidate for next‐generation energy storage systems, but suffer from poor cycling efficiency of the Zn anode. Emerging approaches aim to regulate zinc plating behavior to suppress uncontrolled dendrites, while the stripping process is seldom considered.
Shimeng Zhang   +5 more
openaire   +2 more sources

Achieving highly reversible zinc metal anode via surface termination chemistry

Science Bulletin, 2023
An oxidation layer on a Zn surface is considered to play a negative role in hindering the practical applications of aqueous zinc ion batteries (AZBs). Herein, we demonstrate the importance of Zn-surface termination on the overall electrochemical behavior of AZBs by revisiting the well-known bottleneck issues.
Yu, Liu   +11 more
openaire   +2 more sources

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