Results 21 to 30 of about 1,110,495 (128)

γ,δ-Unsaturated β-Diketones by Acylation of Ketones

open access: yes, 2016
γ,δ-Unsaturated β-diketones have been prepared by the acylation of ketones with N-acylbenzotriazoles of various aliphatic and aromatic α,β-unsaturated carboxylic ...
Sandeep K. Singh (1849165)   +2 more
core   +1 more source

Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated Ketones or Cyclopropyl Ketones with Hydrosilanes

open access: yes, 2016
α,β-Unsaturated ketones and cyclopropyl ketones undergo palladium-catalyzed hydrosilylation with hydrosilanes to yield (Z)-silyl ...
Hideki Yorimitsu (1393411)   +2 more
core   +1 more source

)‐β‐Nitroenones into β‐Nitro‐β,γ‐Unsaturated Ketones under Microwave Conditions

open access: yes, 2020
We report herein an unprecedented conversion of β-nitroenones into β-nitro-β,γ-unsaturated ketones. The reaction proceeds under microwave irradiation, furnishing products in good yields and excellent diastereoselectivity.
Palmieri A.   +17 more
core   +1 more source

Enantioselective addition of selenosulfonates to α,β-unsaturated ketones

open access: yes, 2018
An efficient organo-catalyzed enantioselective addition of selenosulfonates to α,β-unsaturated ketones was developed for the first time.
Zhen Wang   +3 more
core   +1 more source

Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)

open access: yesAngewandte Chemie International Edition, EarlyView.
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
wiley   +1 more source

Analysis of Carbohydrates and Glycoconjugates by Matrix‐Assisted Laser Desorption/Ionization Mass Spectrometry: An Update for 2023–2024

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT The use of MALDI mass spectrometry for the analysis of carbohydrates and glycoconjugates is a well‐established technique and this comprehensive review is the twelfth update of the original article published in 1999 and brings coverage of the literature to the end of 2024.
David J. Harvey
wiley   +1 more source

Liquid-Phase Combinatorial Synthesis of Alicyclic β-Lactams via Ugi Four-Component Reaction

open access: yes, 2016
Alicyclic β-lactams were successfully synthesized via a parallel liquid-phase Ugi four-center three-component reaction (U-4C-3CR), starting from alicyclic β-amino acids such as cis-2-aminocyclohexanecarboxylic acid, cis-2-aminocyclopentanecarboxylic acid,
Ferenc Fülöp (2468881)   +2 more
core   +1 more source

Advancing Biomass Valorization via Electrocatalytic Oxidation: Design Principles, Emerging Challenges, and Future Perspectives

open access: yesSusMat, EarlyView.
This review categorizes substrates for electrocatalytic biomass valorization by carbon chain length into C2–C3 alcohols, C5–C7 cyclic compounds, and Cn biopolymers. It identifies four universal catalyst design principles: optimizing intermediate adsorption, engineering synergistic multi‐type active sites, accelerating active‐site formation, and ...
Ruya Zhang, Shuaihu Jiang, Yijin Kang
wiley   +1 more source

A Novel Pyrrolidine Imide Catalyzed Direct Formation of α,β-Unsaturated Ketones from Unmodified Ketones and Aldehydes

open access: yes, 2016
A method for direct, stereoselective preparation of (E)-α,β-unsaturated ketones from ketones and aldehydes, promoted by a novel pyrrolidine imide organocatalyst, has been developed in moderate to high yields.
Yujiang Mei (2067211)   +3 more
core   +1 more source

Bio‐Based Polyurethanes for Sustainable and Multifunctional Applications

open access: yesAdvanced Science, Volume 13, Issue 50, 7 September 2026.
Bio‐based polyurethanes prepared from vegetable oils, lignin, and polysaccharides have attracted increasing interest as alternatives to fossil‐derived polyurethanes. This review summarizes recent progress in their chemistry, structural engineering, and advanced applications, highlighting the roles of feedstocks, chain‐segment design, dynamic covalent ...
Xin Li   +6 more
wiley   +1 more source

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