Results 31 to 40 of about 1,110,495 (128)

MeOTf-Mediated Alkynylation of Selenoamides Leading to β-Methylselenenyl α,β-Unsaturated Ketones and Their Characterization

open access: yes, 2016
β-Methylselenenyl α,β-unsaturated ketones were effectively synthesized by treating selenoamides with methyl triflate, followed by reaction with lithium acetylides. The reaction proceeded with high stereoselectivity to give exclusively Z-isomers. 77Se NMR
Toshiaki Murai (1402201)   +2 more
core   +1 more source

Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 32, 24 August 2026.
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley   +1 more source

Catalytic Hydrogenation of Lignin‐Derived Aromatics With Rhodium Oxide in Water

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 14, 15 April 2026.
The easily available, easy‐to‐handle rhodium(III) oxide, Rh2O3, is shown to be a competent catalyst for arene hydrogenation, including chemoselective reduction of α,β‐unsaturated aryl ketones. Catalytic arene hydrogenation offers a direct pathway to saturated carbocycles. It can also be exploited to upgrade lignin‐derived aromatics.
Zhenyu Chen   +8 more
wiley   +1 more source

Zinc(II) Catalysed Conjugate Addition of Grignard Reagents to α,β-Unsaturated Ketones [PDF]

open access: yes, 1989
Zinc(II)-diamine complexes are efficient catalysts for the conjugate additions of Grignard reagents to various α,β-unsaturated ketones.
Jansen, Johan F.G.A., Feringa, Bernard
core   +1 more source

Toward Sustainability: Intensification of Light‐Driven Whole Cell Biocatalysis

open access: yesChemBioChem, Volume 27, Issue 8, April 2026.
Whole‐cell, light‐driven biotransformations in photoautotrophic microorganisms offer the potential for higher atom economy by directly harnessing reducing equivalents and oxygen generated through natural photosynthesis. Current advances include the development of strains with improved growth rates and reactor designs that mitigate self‐shading ...
Lenny Malihan‐Yap   +2 more
wiley   +1 more source

Chromium(III)-Catalyzed Addition of Water and Alcohol to α,β-Unsaturated Ketones for the Synthesis of β‑Hydroxyl and β‑Alkoxyl Ketones in Aqueous Media

open access: yes, 2018
An efficient chromium­(III) chloride-catalyzed Michael-type reaction of water or alcohol with α,β-unsaturated ketones is developed. A variety of α,β-unsaturated ketones effectively reacted with either water or alcohols to give the corresponding β ...
Jin-Jin Yun (5687498)   +11 more
core   +1 more source

Study on the Effect of Enzymatic Hydrolyzate of Duck Meat on the Quality and Flavor of Duck Meat Sauce Using Chemometric Techniques

open access: yesJournal of Food Biochemistry, Volume 2026, Issue 1, 2026.
Background Enzymatic hydrolysis can enhance the flavor of food. The amino acids and peptides generated through enzymatic hydrolysis of poultry protein not only enhance protein absorption and utilization but also improve flavor. Methods This study utilized duck meat enzymatic hydrolysate as the primary additive for the preparation of duck meat sauce ...
Youwei Ai   +9 more
wiley   +1 more source

Hydrohalogenation Reaction of 1,2-Allenyl Ketones Revisited. Efficient and Highly Stereoselective Synthesis of β,γ-Unsaturated β-Haloketones

open access: yes, 2016
Hydrohalogenation Reaction of 1,2-Allenyl Ketones Revisited.
Shengming Ma (1312428)   +2 more
core   +1 more source

A Mild Isomerization Reaction for β,γ-Unsaturated Ketone to α,β-Unsaturated Ketone

open access: yes, 2013
A series of β,γ-unsaturated ketones were isomerized to their corresponding α,β-unsaturated ketones by the introduction of DABCO in iPrOH at room temperature. The endo-cyclic double bond (β,γ-position) on ketone was rearranged to exo-cyclic double bond (α,
李世元; Lee, Adam Shih-yuan; 林美君; Lin, Mei-chun; Wang, Shu-huei; 王淑惠; Lin, Li-shin;林立信
core   +1 more source

Synthesis of α‑Alkenyl α,β-Unsaturated Ketones via Dehydrogermylation of Oxagermacycles with Regeneration of the Germanium(II) Species

open access: yes, 2019
The synthesis of α-alkenyl α,β-unsaturated ketones using germanium­(II) salts is reported. Oxagermacycles derived from α,β-unsaturated ketones with germanium­(II) salts and aldehydes can be transformed into α-alkenyl α,β-unsaturated ketones.
Yohei Minami   +5 more
core   +1 more source

Home - About - Disclaimer - Privacy