Results 31 to 40 of about 1,110,495 (128)
β-Methylselenenyl α,β-unsaturated ketones were effectively synthesized by treating selenoamides with methyl triflate, followed by reaction with lithium acetylides. The reaction proceeded with high stereoselectivity to give exclusively Z-isomers. 77Se NMR
Toshiaki Murai (1402201) +2 more
core +1 more source
Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley +1 more source
Catalytic Hydrogenation of Lignin‐Derived Aromatics With Rhodium Oxide in Water
The easily available, easy‐to‐handle rhodium(III) oxide, Rh2O3, is shown to be a competent catalyst for arene hydrogenation, including chemoselective reduction of α,β‐unsaturated aryl ketones. Catalytic arene hydrogenation offers a direct pathway to saturated carbocycles. It can also be exploited to upgrade lignin‐derived aromatics.
Zhenyu Chen +8 more
wiley +1 more source
Zinc(II) Catalysed Conjugate Addition of Grignard Reagents to α,β-Unsaturated Ketones [PDF]
Zinc(II)-diamine complexes are efficient catalysts for the conjugate additions of Grignard reagents to various α,β-unsaturated ketones.
Jansen, Johan F.G.A., Feringa, Bernard
core +1 more source
Toward Sustainability: Intensification of Light‐Driven Whole Cell Biocatalysis
Whole‐cell, light‐driven biotransformations in photoautotrophic microorganisms offer the potential for higher atom economy by directly harnessing reducing equivalents and oxygen generated through natural photosynthesis. Current advances include the development of strains with improved growth rates and reactor designs that mitigate self‐shading ...
Lenny Malihan‐Yap +2 more
wiley +1 more source
An efficient chromium(III) chloride-catalyzed Michael-type reaction of water or alcohol with α,β-unsaturated ketones is developed. A variety of α,β-unsaturated ketones effectively reacted with either water or alcohols to give the corresponding β ...
Jin-Jin Yun (5687498) +11 more
core +1 more source
Background Enzymatic hydrolysis can enhance the flavor of food. The amino acids and peptides generated through enzymatic hydrolysis of poultry protein not only enhance protein absorption and utilization but also improve flavor. Methods This study utilized duck meat enzymatic hydrolysate as the primary additive for the preparation of duck meat sauce ...
Youwei Ai +9 more
wiley +1 more source
Hydrohalogenation Reaction of 1,2-Allenyl Ketones Revisited.
Shengming Ma (1312428) +2 more
core +1 more source
A Mild Isomerization Reaction for β,γ-Unsaturated Ketone to α,β-Unsaturated Ketone
A series of β,γ-unsaturated ketones were isomerized to their corresponding α,β-unsaturated ketones by the introduction of DABCO in iPrOH at room temperature. The endo-cyclic double bond (β,γ-position) on ketone was rearranged to exo-cyclic double bond (α,
李世元; Lee, Adam Shih-yuan; 林美君; Lin, Mei-chun; Wang, Shu-huei; 王淑惠; Lin, Li-shin;林立信
core +1 more source
The synthesis of α-alkenyl α,β-unsaturated ketones using germanium(II) salts is reported. Oxagermacycles derived from α,β-unsaturated ketones with germanium(II) salts and aldehydes can be transformed into α-alkenyl α,β-unsaturated ketones.
Yohei Minami +5 more
core +1 more source

