Gap Analysis of Metabolic Conversions of Off-Flavors and Antinutrients in Plant-Based Substrates. [PDF]
Kuijpers RI +16 more
europepmc +1 more source
Sulfur‐Directed Construction of Vinyl Cyclopropanes from 1,3‐Dienes
Sulfur takes control. A pending thioether acts as a molecular compass, directing carbene addition to the 1,3‐diene scaffold with exceptional regio‑ and diastereocontrol to forge sulfur‐substituted vinyl cyclopropanes (S‐VCPs) — molecular architectures inaccessible via conventional cyclopropanation strategies.
Anna Keimer +6 more
wiley +2 more sources
Aroma enhancement in fig wine through sequential fermentation with <i>Candida humilis</i> and <i>Torulaspora delbrueckii</i>: A flavoromics study. [PDF]
Han B +6 more
europepmc +1 more source
Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu +3 more
wiley +2 more sources
Meat spoilage by bacteria: Influencing factors, volatile compounds, and organoleptic alterations. [PDF]
Kang J, Kim BH, Yoon Y.
europepmc +1 more source
Iron‐Photocatalyzed C(sp3)–H Phosphonylation of Alkanes
Alkyl phosphonates are valuable motifs that can be prepared by phosphonylations of various common functional groups. However, direct phosphonylations of C(sp3)–H bonds are limited to activated positions. Herein, we report an iron‐photocatalyzed phosphonylation of unactivated C(sp3)–H bonds using a novel phosphite radical trap, which is equipped with an
Ya Dong +6 more
wiley +2 more sources
Merging Double Hydrogen Atom Transfer and Stepwise Proton-Coupled Electron Transfer for γ‑C-H Hydrazination of Alcohols. [PDF]
Zuo K +7 more
europepmc +1 more source
The use of transition‐metal catalysts and design of chiral ligands have allowed chemists to access highly functionalized benzofused 5‐ and 6‐ membered rings in high yield and enantioselectivity. A common strategy used relies on an intermolecular carbometalation across alkynes and olefins, usually followed by a subsequent intramolecular carbometalation.
Clara Jans +3 more
wiley +2 more sources
Screening and oenological characterization of a high β-glucosidase-producing yeast from <i>Pyracantha fortuneana</i> (maxim.) Li. [PDF]
Wu C +6 more
europepmc +1 more source

