Results 181 to 190 of about 69,375 (242)

Gap Analysis of Metabolic Conversions of Off-Flavors and Antinutrients in Plant-Based Substrates. [PDF]

open access: yesCompr Rev Food Sci Food Saf
Kuijpers RI   +16 more
europepmc   +1 more source

Sulfur‐Directed Construction of Vinyl Cyclopropanes from 1,3‐Dienes

open access: yesAngewandte Chemie, EarlyView.
Sulfur takes control. A pending thioether acts as a molecular compass, directing carbene addition to the 1,3‐diene scaffold with exceptional regio‑ and diastereocontrol to forge sulfur‐substituted vinyl cyclopropanes (S‐VCPs) — molecular architectures inaccessible via conventional cyclopropanation strategies.
Anna Keimer   +6 more
wiley   +2 more sources

Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin

open access: yesAngewandte Chemie, EarlyView.
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu   +3 more
wiley   +2 more sources

Iron‐Photocatalyzed C(sp3)–H Phosphonylation of Alkanes

open access: yesAngewandte Chemie, EarlyView.
Alkyl phosphonates are valuable motifs that can be prepared by phosphonylations of various common functional groups. However, direct phosphonylations of C(sp3)–H bonds are limited to activated positions. Herein, we report an iron‐photocatalyzed phosphonylation of unactivated C(sp3)–H bonds using a novel phosphite radical trap, which is equipped with an
Ya Dong   +6 more
wiley   +2 more sources

Merging Double Hydrogen Atom Transfer and Stepwise Proton-Coupled Electron Transfer for γ‑C-H Hydrazination of Alcohols. [PDF]

open access: yesJACS Au
Zuo K   +7 more
europepmc   +1 more source

Strategies Toward Accessing Enantioenriched (Hetero)Benzo‐Fused 5‐ and 6‐ Membered Rings via Intermolecular Carbometalation

open access: yesAngewandte Chemie, EarlyView.
The use of transition‐metal catalysts and design of chiral ligands have allowed chemists to access highly functionalized benzofused 5‐ and 6‐ membered rings in high yield and enantioselectivity. A common strategy used relies on an intermolecular carbometalation across alkynes and olefins, usually followed by a subsequent intramolecular carbometalation.
Clara Jans   +3 more
wiley   +2 more sources

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