Results 1 to 10 of about 3,199 (126)

Measurement of the A-Value of the Intersystem Transition in Al II at 2670 Å: Å Progress Report [PDF]

open access: yesInternational Astronomical Union Colloquium, 1984
Ratios of intensities of spectral lines produced in the radiative decay of collisionally-excited levels of atomic ions are versatile indicators of electron density in astrophysical plasmas when one of the lines involves a metastable level (see the review by Feldman 1981 and references therein). Radiative transition probabilities (A-values) and electron
B. Carol Johnson, H.S. Kwong
openaire   +1 more source

Optical spectrum of the post-AGB Star HD56126 in the wavelength interval 4010-8790 Å Å [PDF]

open access: yesAstrophysical Bulletin, 2007
The optical spectrum of the post-AGB star HD56126 identified with the infrared source IRAS07134+1005 is studied in detail using high spectral resolution observations (R = 25000 and 60000) performed with the echelle spectrographs of the 6-m telescope. A total of about one and a half thousand absorptions of neutral atoms and ions, absorption bands of C2,
V. G. Klochkova   +3 more
openaire   +1 more source

Review of the preparation and improvement of TiO2 ultrafine particle at photocatalysis(光催化剂TiO2超细粒子的制备及改进评述)

open access: yesZhejiang Daxue xuebao. Lixue ban, 2001
TiO2超细粒子作为常用的光催化剂,在环境净化中日益受到重视.本文对TiO2超细粒子的作用机理,催化剂的制备及改进等方面进行论述.
SHENHang-yan(沈杭燕)   +4 more
doaj   +1 more source

Microcaiorimetric research of interaction of adenine, deoxyadenosine, deoxyribose with alkylamines(腺嘌呤、脱氧核糖和脱氧腺苷与烷基胺的相互作用研究)

open access: yesZhejiang Daxue xuebao. Lixue ban, 2003
用LKB-2277精密微量热仪测定了288.15 K,298.15 K和308.15 K时DNA组成成分腺嘌呤、脱氧核糖和脱氧腺苷与烷基胺(乙胺、丙胺、丁胺和正庚胺)之间的相互作用焓变.实验结果表明,烷基胺与它们混合时在所测的温度范围内的相互作用焓变表现出明显的规律性.紫外光谱研究也证实腺嘌呤和脱氧腺苷与正庚胺发生相互作用.通过和正庚烷与腺嘌呤、脱氧腺苷相互作用焓变大小的比较,讨论了烷基胺与腺嘌呤、脱氧腺苷相互作用可能发生的靶点.
YANBing-hua(严兵华)   +2 more
doaj   +1 more source

Transesterification of rapeseed oil to biodiesel using La2O3 loaded with KF(KF/La2O3催化剂催化菜籽油酯交换反应制备生物柴油)

open access: yesZhejiang Daxue xuebao. Lixue ban, 2008
通过植物油酯交换法制备的生物柴油是一种清洁的可再生能源.实验从环境友好的角度出发采用KF/La2O3固体碱催化剂催化菜籽油制备生物柴油.考察了KF的负载量、醇/油摩尔比、催化剂用量和反应时间对该酯交换反应的影响.实验结果表明,通过浸渍并在873 K煅烧4 h,可以制得理想的KF添加量(KF与La2O3的质量比)为15%的KF/La2O3催化剂.采用该催化剂,当醇与油摩尔比为12 : 1、反应温度为65 ℃、反应时间为1 h、催化剂用量(催化剂与油的质量比)为3%时,酯交换反应的转化率可以达到94.3%.
HUKai(胡凯)   +5 more
doaj   +1 more source

Study on the preparation and property of Pt/Ce0.5M0.5O2 (M = Zr,Ti) catalysts with high hydrothermal stability for hydrodeoxygenation(高水热稳定性加氢脱氧催化剂Pt/Ce0.5 M0.5O2 (M = Zr,Ti)的制备及其性能研究)

open access: yesZhejiang Daxue xuebao. Lixue ban, 2018
分别采用共沉淀法和溶胶凝胶法制备了具有高水热稳定性的Ce0.5M0.5O2 (M=Zr,Ti)载体,并通过浸渍法制得高分散Pt/Ce0.5M0.5O2(M=Zr,Ti)催化剂,分析了短链脂肪醇作为氢供体用于香兰素加氢脱氧反应的催化性能.实验结果表明,复合氧化物催化剂Pt/Ce0.5M0.5O2(M=Zr,Ti)具有高的水热稳定性和优良的加氢脱氧活性,且Pt/Ce0.5Zr0.5O2较Pt/Ce0.5Ti0.5O2的催化性能更胜一筹,催化剂的加氢脱氧性能与其表面的酸性质以及贵金属Pt在载体上的高度分散有关.
CHANGAo(常傲)   +3 more
doaj   +1 more source

Effect of Al2O3 on the Ni-Al2O3/SiO2 catalysts for the production of syngas from reforming of CH4 with CO2 and O2(甲烷二氧化碳氧化重整制合成气反应中Al2O3对Ni-Al2O3/SiO2催化剂性能的影响)

open access: yesZhejiang Daxue xuebao. Lixue ban, 2008
在流化床中评价了用于甲烷二氧化碳氧化重整制合成气反应的Ni-Al2O3/SiO2催化剂体系(NixAlSi,x代表Al的质量分数,Ni的质量分数为4%)的催化性能.利用XRD,CO2(O2)-TPD,积炭量测定等手段对催化剂进行了表征.结果表明,Al2O3的添加促进了Ni金属的分散;增强了对CO2和O2的吸附能力,使催化剂的抗积炭性能得到很大的提高,延缓了催化剂的失活.
HESu-fang(何素芳)   +5 more
doaj   +1 more source

Study on the kinetics of dimethyl ether one-step synthesis from syngas(合成气一步法制二甲醚的动力学研究)

open access: yesZhejiang Daxue xuebao. Lixue ban, 2003
采用固定床积分反应器,研究了用浸渍法制备的CuO-ZnO/Y-zeolite双功能催化剂上CO加氢直接合成二甲醚的反应动力学.按一氧化碳加氢先合成甲醇,再由甲醇脱水生成二甲醚两步串联的反应机理,分别建立了动力学模型,并对该催化剂上甲醇合成及甲醇脱水的机理作了探讨.模型的计算值和实验值能较好吻合,两步反应的表观治化能分别为27.98 kJ/mol和30.62kJ ...
JIANGDa-hao(江大好)   +3 more
doaj   +1 more source

Kinetic study on nucleophilic substitution reactions of chloride with methyl benzenesulfonate as substrate in different solvents(氯化物与苯磺酸甲酯在不同溶剂中亲核取代反应的动力学研究)

open access: yesZhejiang Daxue xuebao. Lixue ban, 2005
用动力学方法研究了不同温度下氯化物与苯磺酸甲酯在丙酮、2-丁酮、环己酮、乙腈、DMF和甲醇中的亲核取代反应.反应的动力学行为可用SN2机理来解释.在一定溶剂中不同温度(5~45 ℃)的反应速率常数可用Arrhenius方程很好地关联.根据Arrhenius方程和过渡态理论分别求得了活化能、指前因子、活化焓和活化熵.对溶剂效应和焓-熵补偿作用进行了讨论.在不同溶剂中以活化能作为标度的Cl-的亲核反应性顺序为:环己酮>丙酮>2-丁酮>DMF>乙腈>甲醇.
LAIGuo-hua(赖国华)   +3 more
doaj   +1 more source

NH3-SCR performance over different types of Cu modified zeolites at low temperature(铜改性分子筛的低温NH3-SCR性能研究)

open access: yesZhejiang Daxue xuebao. Lixue ban, 2014
采用浸渍法制备了 Cu-ZSM-5、Cu-beta、Cu-USY和Cu-SAPO-34四种铜改性分子筛催化剂,并评价了各个催化剂的NH3选择性催化还原(NH3-SCR)性能,同时通过X射线衍射(XRD)、H2程序升温还原(H2-TPR)、CO 吸附红外(CO-DRIFTS)、原位红外(In-situ FTIR)等实验技术研究了不同Cu-zeolite催化剂的物理化学性质及其对NH3-SCR性能的影响.结果表明,Cu-ZSM-5和Cu-beta在150 ℃时NO转化率可达到80%左右,表现出优异的低温活性,
YANGHaipeng(杨海鹏)   +2 more
doaj   +1 more source

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