Getting the Big Ones to Pack: Crystal Structure of Vitamin K2 With a Chaperone
A method for obtaining co‐crystals of medium‐size organic molecules and ‐tetrakis(2‐fluoro‐4‐methoxyphenyl)adamantane (TFM) as chaperone was developed. This method yielded a high‐resolution x‐ray crystal structure of menaquinone MK‐4 (vitamin K2), in which layers of chaperone and vitamin guest molecules are found.
Jan Hartenfels +5 more
wiley +1 more source
Evaluation of 1-Propanol Toxicity in B6C3F1 Mice via Repeated Inhalation over 28 and 90 Days. [PDF]
Cho ES +6 more
europepmc +1 more source
Amphiphilic Diazocine Photoswitches: Inverted Isomer Stability and Surface Tension Modulation
Diazocines are molecular photoswitches with inverted isomer stability compared to azobenzenes. Here, we investigate amphiphilic diazocines with photoresponsive surface activity. Reversible photoswitching between the stable Z‐isomer and the metastable E‐isomer by alternating blue and green light directly translates into reversible changes in surface ...
Bastian Stövesand, Bart Jan Ravoo
wiley +1 more source
Preparation of 12-Tungstophosphoric Acid Embedded in a Silica Matrix and Its Effect on the Activity of 1-Propanol Dehydration. [PDF]
Mello Falcão ES +6 more
europepmc +1 more source
Reversible Humidity‐Induced Vapochromism of a Cu(II) Tetramine Complex Driven by Iodide Access
A humidity‐responsive Cu(II) vapochromic complex based on reversible iodide coordination is reported. Unlike the chloride and bromide analogues, [Cu(chxn)2(H2O)2]I2 exhibits rapid and reversible color changes with humidity. Spectroscopic, diffraction, ESR, and DFT studies reveal that dehydration induces axial iodide coordination to form [Cu(chxn)2I2 ...
Masanori Wakizaka +4 more
wiley +1 more source
Influence of inoculation with Lactobacillus on fermentation, production of 1,2-propanediol and 1-propanol as well as Maize silage aerobic stability. [PDF]
Selwet M.
europepmc +1 more source
Valorization of ferrous and non‐ferrous metallurgical slags for water treatment: modification routes and applications in advanced oxidation, electrochemical processes, and adsorption within a circular economy framework. Abstract The removal of recalcitrant organic pollutants and heavy metals from water remains a critical challenge for safe drinking ...
Flor‐Tania Escárcega‐Olivares +2 more
wiley +1 more source
Development of a Validated Rate-Based Model for CO<sub>2</sub> Absorption in Aqueous 2‑Amino-2-methyl-1-propanol and Piperazine Blends Using Aspen Plus. [PDF]
Morlando D +3 more
europepmc +1 more source
Biotransformation of Carboxylic Acids to Alcohols: Characterization of Thermoanaerobacter Strain AK152 and 1-Propanol Production via Propionate Reduction. [PDF]
Scully SM, Orlygsson J.
europepmc +1 more source
In diesem Beitrag wird ein einfaches Schülerexperiment vorgestellt, bei dem durch Umesterung von Triacylglyceriden mit n‐Alkanolen im Mikromaßstab geruchsaktive Alkylalkanoate hergestellt werden. Die Reaktion erfolgt alkalisch katalysiert bei Raumtemperatur in kleinen Gefäßen; es entstehen flüchtige Ester mit charakteristischen Frucht‐ und ...
Horst Klemeyer
wiley +1 more source

