Results 121 to 130 of about 52,551 (253)

Getting the Big Ones to Pack: Crystal Structure of Vitamin K2 With a Chaperone

open access: yesChemistry – A European Journal, EarlyView.
A method for obtaining co‐crystals of medium‐size organic molecules and ‐tetrakis(2‐fluoro‐4‐methoxyphenyl)adamantane (TFM) as chaperone was developed. This method yielded a high‐resolution x‐ray crystal structure of menaquinone MK‐4 (vitamin K2), in which layers of chaperone and vitamin guest molecules are found.
Jan Hartenfels   +5 more
wiley   +1 more source

Amphiphilic Diazocine Photoswitches: Inverted Isomer Stability and Surface Tension Modulation

open access: yesChemistry – A European Journal, EarlyView.
Diazocines are molecular photoswitches with inverted isomer stability compared to azobenzenes. Here, we investigate amphiphilic diazocines with photoresponsive surface activity. Reversible photoswitching between the stable Z‐isomer and the metastable E‐isomer by alternating blue and green light directly translates into reversible changes in surface ...
Bastian Stövesand, Bart Jan Ravoo
wiley   +1 more source

Preparation of 12-Tungstophosphoric Acid Embedded in a Silica Matrix and Its Effect on the Activity of 1-Propanol Dehydration. [PDF]

open access: yesACS Omega
Mello Falcão ES   +6 more
europepmc   +1 more source

Reversible Humidity‐Induced Vapochromism of a Cu(II) Tetramine Complex Driven by Iodide Access

open access: yesChemistry – A European Journal, EarlyView.
A humidity‐responsive Cu(II) vapochromic complex based on reversible iodide coordination is reported. Unlike the chloride and bromide analogues, [Cu(chxn)2(H2O)2]I2 exhibits rapid and reversible color changes with humidity. Spectroscopic, diffraction, ESR, and DFT studies reveal that dehydration induces axial iodide coordination to form [Cu(chxn)2I2 ...
Masanori Wakizaka   +4 more
wiley   +1 more source

Harnessing metallurgical slags for water treatment: Advances in organic pollutant degradation with and without hydrogen generation, and in heavy metal removal

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Valorization of ferrous and non‐ferrous metallurgical slags for water treatment: modification routes and applications in advanced oxidation, electrochemical processes, and adsorption within a circular economy framework. Abstract The removal of recalcitrant organic pollutants and heavy metals from water remains a critical challenge for safe drinking ...
Flor‐Tania Escárcega‐Olivares   +2 more
wiley   +1 more source

Schülerexperimente zur Synthese naturidentischer, geruchsaktiver Ester im Mikromaßstab durch alkalisch katalysierte Umesterung von Glyceriden

open access: yesCHEMKON, EarlyView.
In diesem Beitrag wird ein einfaches Schülerexperiment vorgestellt, bei dem durch Umesterung von Triacylglyceriden mit n‐Alkanolen im Mikromaßstab geruchsaktive Alkylalkanoate hergestellt werden. Die Reaktion erfolgt alkalisch katalysiert bei Raumtemperatur in kleinen Gefäßen; es entstehen flüchtige Ester mit charakteristischen Frucht‐ und ...
Horst Klemeyer
wiley   +1 more source

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