Results 201 to 210 of about 77,981 (327)

Ring Transformation of Heterocycles Transformation of 4, 5-Dihydro-5, 5-Dimethyl-H-1, 2, 4-Triazoles Into 5-Methyl-H-1, 2, 4-Triazoles

open access: yes, 2001
Reaction of 1-aryl-3-acetyl-4, 5-dihydro-5, 5-dimethyl-1H-1, 2, 4-triazoles (3) with acetyl chloride or acetic anhydride is found to give the ring transformation product 1-aryl-3-acetyl-5-methyl-1H-1, 2, 4-triazoles (4) instead of the expected N-acetyl derivative (5). This ring transformation is believed to start with N-acylation of the dihydrotriazole
openaire   +1 more source

Precise Tailoring of the Coordination Environment of Single‐Atom Cu(I) on Trifurcate AlL3 Supports for Click Chemistry

open access: yesRare Metals, EarlyView.
ABSTRACT Single‐atom catalysis hinges on fundamental challenges in precisely controlling metal‐support interactions and rationally regulating metal–adsorbate relationships. Herein, we report a universal strategy for constructing highly efficient and well‐defined Cu(I) single‐atom catalysts based on a trifurcate AlL3 molecular support.
Donghui Zhang   +9 more
wiley   +1 more source

Combining Laser‐Induced Edition to Collision‐Induced Sequencing of Digital Oligomers in a Single Gas‐Phase Experiment

open access: yesRapid Communications in Mass Spectrometry, EarlyView.
ABSTRACT Rationale To increase the confidentiality level of molecular tags, binary information can be hidden in sequence‐defined oligomers using isobaric monomers including a photo‐sensitive one, which mass can be modified upon light irradiation. Reading such secured data requires light edition prior to MS/MS sequencing, which was investigated here in ...
Clothilde Comby‐Zerbino   +3 more
wiley   +1 more source

Recent advances in fluorescent materials innovation and film‐based sensing application

open access: yesResponsive Materials, EarlyView.
This review systematically summarizes recent advances in high‐performance film‐based fluorescent sensors (FFSs), specifically covering the innovative strategies for engineering porous sensing films, and the sensitive and rapid detection for diverse target analytes. Current challenges for the further development of the sensors are discussed, guiding the
Xinyu Gou, Junxia Peng, Yu Fang
wiley   +1 more source

Modification of the existing maximum residue levels for prothioconazole in various crops. [PDF]

open access: yesEFSA J
European Food Safety Authority (EFSA)   +18 more
europepmc   +1 more source

Filomicelle‐Embedded Composite Hydrogels for Localized Gelation Within the Anterior Chamber of the Eye

open access: yesSmall, EarlyView.
A composite hydrogel (C‐gel) incorporating PEG‐b‐PPS filomicelles enables localized in situ gelation and sustained nanocarrier release within the anterior chamber. The filamentous structure promotes spatial confinement of multi‐arm polymer crosslinking, even upon injection into large aqueous volumes, and gradually transitions into spherical micelles ...
Hyeohn Kim   +6 more
wiley   +1 more source

Design, Synthesis, and Biological Evaluation of Novel Acetylcholinesterase and β-Secretase 1 Inhibitors. [PDF]

open access: yesInt J Mol Sci
Drozdowska D   +8 more
europepmc   +1 more source

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