Results 21 to 30 of about 8,136 (224)
5-Hydroxy-2-methyl-4H-pyran-4-one
The title compound, C6H6O3, is a member of the pyrone family. The molecules are planar (r.m.s. deviation of the asymmetric unit is 0.0248 Å, whereas that of the dimer is 0.0360 Å) and they are dimerized due to intermolecular O—
Bernhard K. Keppler +4 more
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An efficient and practical synthetic approach was developed for the tandem synthesis of trisubstituted 2-pyrone derivatives from sulfoxonium ylides and cyclopropenones. This [3+3] annulation reaction was carried out under transition-metal-free conditions.
Maoyao He +7 more
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Hydric alcohols are important synthetic intermediates used to manufacture polymer, fine chemicals, and commodity products. Recent environmental problems due to fossil fuel-based non-degradable products have call for the advancement in research towards ...
Md. Imteyaz Alam +3 more
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Dioxygen Reactivity of Biomimetic Fe(II) Complexes with Noninnocent Catecholate, \u3cem\u3eo\u3c/em\u3e-Aminophenolate, and \u3cem\u3eo\u3c/em\u3e-Phenylenediamine Ligands [PDF]
This study describes the O2 reactivity of a series of high-spin mononuclear Fe(II) complexes each containing the facially coordinating tris(4,5-diphenyl-1-methylimidazol-2-yl)phosphine (Ph2TIP) ligand and one of the following bidentate, redox-active ...
Bittner, Michael M. +3 more
core +3 more sources
Synthesis of an Antileukemic Pyrone from
Antileukemic pyrone 1 was synthesized by way of a five-step procedure from 4 -Hydroxy-5-methoxycarbonyl-6-methyl-2-pyrone (8). This is the first synthesis of 4-methoxy-6-methyl-5-(3-oxobutyl)-2H-pyran-2-one (1).
Yang Qu, George A. Kraus
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Nocapyrones: α- and γ-Pyrones from a Marine-Derived Nocardiopsis sp.
One new α-pyrone (nocapyrone R (1)), and three known γ-pyrones (nocapyrones B, H and L (2–4)) were isolated from the culture extract of a Nocardiopsis strain collected from marine sediment.
Youngju Kim +7 more
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Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu +3 more
wiley +2 more sources
Two mild and efficient strategies have been developed for the O-functionalisation of 4-hydroxy-6-alkyl-2-pyrones, by using them as nucleophilic partners in oxa-Michael additions and the Mitsunobu reaction.
Michael J. Burns +3 more
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A Coarse Techno-Economic Model of a Combined Fermentation-Catalysis Route to Sorbic Acid [PDF]
The conversion of biomass into bulk chemicals provides the potential for multiple environmental and economic benefits. While current research in industrial biotechnology focuses primarily on biocatalysts, a significant opportunity exists when combining ...
Claypool, Joshua +2 more
core +3 more sources
Functional molecule-based solids built of metal complexes can reveal a great impact of external stimuli upon their optical, magnetic, electric, and mechanical properties. We report a novel molecular material, {[EuIII(H2O)3(pyrone)4][CoIII(CN)6]}·nH2O (1,
Jakub J. Zakrzewski +3 more
doaj +1 more source

