Results 21 to 30 of about 8,136 (224)

5-Hydroxy-2-methyl-4H-pyran-4-one

open access: yesActa Crystallographica Section E, 2009
The title compound, C6H6O3, is a member of the pyrone family. The molecules are planar (r.m.s. deviation of the asymmetric unit is 0.0248 Å, whereas that of the dimer is 0.0360 Å) and they are dimerized due to intermolecular O—
Bernhard K. Keppler   +4 more
doaj   +1 more source

Transition-metal-free [3+3] annulation reaction of sulfoxonium ylides with cyclopropenones for the synthesis of 2-pyrones

open access: yesGreen Synthesis and Catalysis, 2020
An efficient and practical synthetic approach was developed for the tandem synthesis of trisubstituted 2-pyrone derivatives from sulfoxonium ylides and cyclopropenones. This [3+3] annulation reaction was carried out under transition-metal-free conditions.
Maoyao He   +7 more
doaj   +1 more source

Renewable synthesis of branched diols as polymer precursors from biomass-derived lactones and 2-pyrones

open access: yesMaterials Science for Energy Technologies, 2022
Hydric alcohols are important synthetic intermediates used to manufacture polymer, fine chemicals, and commodity products. Recent environmental problems due to fossil fuel-based non-degradable products have call for the advancement in research towards ...
Md. Imteyaz Alam   +3 more
doaj   +1 more source

Dioxygen Reactivity of Biomimetic Fe(II) Complexes with Noninnocent Catecholate, \u3cem\u3eo\u3c/em\u3e-Aminophenolate, and \u3cem\u3eo\u3c/em\u3e-Phenylenediamine Ligands [PDF]

open access: yes, 2014
This study describes the O2 reactivity of a series of high-spin mononuclear Fe(II) complexes each containing the facially coordinating tris(4,5-diphenyl-1-methylimidazol-2-yl)phosphine (Ph2TIP) ligand and one of the following bidentate, redox-active ...
Bittner, Michael M.   +3 more
core   +3 more sources

Synthesis of an Antileukemic Pyrone from

open access: yesNatural Product Communications, 2017
Antileukemic pyrone 1 was synthesized by way of a five-step procedure from 4 -Hydroxy-5-methoxycarbonyl-6-methyl-2-pyrone (8). This is the first synthesis of 4-methoxy-6-methyl-5-(3-oxobutyl)-2H-pyran-2-one (1).
Yang Qu, George A. Kraus
doaj   +1 more source

Nocapyrones: α- and γ-Pyrones from a Marine-Derived Nocardiopsis sp.

open access: yesMarine Drugs, 2014
One new α-pyrone (nocapyrone R (1)), and three known γ-pyrones (nocapyrones B, H and L (2–4)) were isolated from the culture extract of a Nocardiopsis strain collected from marine sediment.
Youngju Kim   +7 more
doaj   +1 more source

Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin

open access: yesAngewandte Chemie, EarlyView.
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu   +3 more
wiley   +2 more sources

4-Hydroxy-6-alkyl-2-pyrones as nucleophilic coupling partners in Mitsunobu reactions and oxa-Michael additions

open access: yesBeilstein Journal of Organic Chemistry, 2014
Two mild and efficient strategies have been developed for the O-functionalisation of 4-hydroxy-6-alkyl-2-pyrones, by using them as nucleophilic partners in oxa-Michael additions and the Mitsunobu reaction.
Michael J. Burns   +3 more
doaj   +1 more source

A Coarse Techno-Economic Model of a Combined Fermentation-Catalysis Route to Sorbic Acid [PDF]

open access: yes, 2012
The conversion of biomass into bulk chemicals provides the potential for multiple environmental and economic benefits. While current research in industrial biotechnology focuses primarily on biocatalysts, a significant opportunity exists when combining ...
Claypool, Joshua   +2 more
core   +3 more sources

Reversible Humidity-Driven Transformation of a Bimetallic {EuCo} Molecular Material: Structural, Sorption, and Photoluminescence Studies

open access: yesMolecules, 2021
Functional molecule-based solids built of metal complexes can reveal a great impact of external stimuli upon their optical, magnetic, electric, and mechanical properties. We report a novel molecular material, {[EuIII(H2O)3(pyrone)4][CoIII(CN)6]}·nH2O (1,
Jakub J. Zakrzewski   +3 more
doaj   +1 more source

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