Results 31 to 40 of about 17,972 (231)

The 1,3-dipolar cycloaddition of 1-methylphthalazinium ylides to non-symmetrically activated alkynes on a solid support under microwave irradiation [PDF]

open access: yesJournal of the Serbian Chemical Society, 2006
In this paper, a comparative study of the reaction of 1-methylpihthalazinium ylides with nonsymmetrically activated alkynes in a solid media by classical heating and under microwaves is presented.
IONEL MANGALAGIU   +2 more
doaj   +3 more sources

Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions

open access: yesMolecules, 2002
Thieno[2,3-d]-1,2,3-thiadiazoles (1) react with carbon disulfide in a "Matryoshkatype" double compartment autoclave [1] to yield thieno[2,3-d]-1,3-dithiol-2-thiones (2).
Ving J. Lee   +3 more
doaj   +1 more source

Concerted [4 + 2] and Stepwise (2 + 2) Cycloadditions of Tetrafluoroethylene with Butadiene: DFT and DLPNO-UCCSD(T) Explorations. [PDF]

open access: yes, 2020
Tetrafluoroethylene and butadiene form the 2 + 2 cycloadduct under kinetic control, but the Diels-Alder cycloadduct is formed under thermodynamic control. Borden and Getty showed that the preference for 2 + 2 cycloaddition is due to the necessity for syn-
Houk, KN   +4 more
core  

Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". [PDF]

open access: yes, 2015
The copper-catalyzed 1,3-dipolar cycloaddition of an azide to a terminal alkyne (CuAAC) is one of the most popular chemical transformations, with applications ranging from material to life sciences.
Bertrand, Guy   +3 more
core   +2 more sources

Diethyl 4-acetyl-5-(2-nitrophenyl)pyrrolidine-2,2-dicarboxylate

open access: yesActa Crystallographica Section E, 2010
The title compound, C18H22N2O7, was synthesized by the 1,3-dipolar cycloaddition reaction of but-3-en-2-one, diethyl 2-aminomalonate and 2-nitrobenzaldehyde. In the molecule, the pyrrolidine ring possesses an envelope conformation.
Long He
doaj   +1 more source

Photo-induced 1, 3-Dipolar Cycloaddition Reaction of Aziridinedicarboximide

open access: yesChemical and Pharmaceutical Bulletin, 1969
Cycloaddition reaction of N-(p-methoxyphenyl)-1-benzyl-2, 3-aziridinedicarboximide (8) with dimethyl acetylenedicarboxylate (3) was not effected thermally, but under irradiation it resulted in a formation of 1 : 1-cycloadducts, I (9), II (17), and III (34), and a 1 : 2-cycloadduct IV (38).
SADAO OIDA, EIJI OHKI
openaire   +2 more sources

Influence of activated carbons on the kinetics and mechanisms of aromatic molecules ozonation [PDF]

open access: yes, 2010
Companies have been looking for new methods for treating toxic or refractory wastewaters; which can mainly be used prior to or after or in connexion with biological treatment processes.This paper compares conventional ozone oxidation with activatedcarbon
Debellefontaine, Hubert   +4 more
core   +2 more sources

Alkylation and 1,3-Dipolar Cycloaddition of 6-Styryl-4,5-dihydro-2H-pyridazin-3-one: Synthesis of Novel N-Substituted Pyridazinones and Triazolo[4,3-b]pyridazinones

open access: yesJournal of Chemistry, 2013
Some new N-substituted pyridazinones and triazolo[4,3-b]pyridazinones were synthesized, respectively, by simple alkylation and 1,3-dipolar cycloaddition of pyridazin-3-one with nitrile imines.
Souad Mojahidi   +6 more
doaj   +1 more source

Three-Component Synthesis of Polysubstituted Homoproline Analogs

open access: yesMolecules, 2005
Tetrasubstituted pyrrolidines representing analogs of homoproline weresynthesized by three-component condensation of aryl(heteroaryl)aldehydes, asparagineand N-methylmaleimide (NMM). Compounds with (1S*, 3R*, 3aS*, 6aR*)-configurationat the corresponding
V. Irkha, K. Kudryavtsev
doaj   +1 more source

Coordinatively unsaturated ruthenium complexes as efficient alkyne-azide cycloaddition catalysts [PDF]

open access: yes, 2012
The performance of 16-electron ruthenium complexes with the general formula Cp*Ru(L)X (in which L = phosphine or N-heterocyclic carbene ligand; X = Cl or OCH2CF3) was explored in azide−alkyne cycloaddition reactions that afford the 1,2,3- triazole ...
Broggi, Julie   +6 more
core   +2 more sources

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