The 1,3-dipolar cycloaddition of 1-methylphthalazinium ylides to non-symmetrically activated alkynes on a solid support under microwave irradiation [PDF]
In this paper, a comparative study of the reaction of 1-methylpihthalazinium ylides with nonsymmetrically activated alkynes in a solid media by classical heating and under microwaves is presented.
IONEL MANGALAGIU +2 more
doaj +3 more sources
Thieno[2,3-d]-1,2,3-thiadiazoles (1) react with carbon disulfide in a "Matryoshkatype" double compartment autoclave [1] to yield thieno[2,3-d]-1,3-dithiol-2-thiones (2).
Ving J. Lee +3 more
doaj +1 more source
Concerted [4 + 2] and Stepwise (2 + 2) Cycloadditions of Tetrafluoroethylene with Butadiene: DFT and DLPNO-UCCSD(T) Explorations. [PDF]
Tetrafluoroethylene and butadiene form the 2 + 2 cycloadduct under kinetic control, but the Diels-Alder cycloadduct is formed under thermodynamic control. Borden and Getty showed that the preference for 2 + 2 cycloaddition is due to the necessity for syn-
Houk, KN +4 more
core
Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". [PDF]
The copper-catalyzed 1,3-dipolar cycloaddition of an azide to a terminal alkyne (CuAAC) is one of the most popular chemical transformations, with applications ranging from material to life sciences.
Bertrand, Guy +3 more
core +2 more sources
Diethyl 4-acetyl-5-(2-nitrophenyl)pyrrolidine-2,2-dicarboxylate
The title compound, C18H22N2O7, was synthesized by the 1,3-dipolar cycloaddition reaction of but-3-en-2-one, diethyl 2-aminomalonate and 2-nitrobenzaldehyde. In the molecule, the pyrrolidine ring possesses an envelope conformation.
Long He
doaj +1 more source
Photo-induced 1, 3-Dipolar Cycloaddition Reaction of Aziridinedicarboximide
Cycloaddition reaction of N-(p-methoxyphenyl)-1-benzyl-2, 3-aziridinedicarboximide (8) with dimethyl acetylenedicarboxylate (3) was not effected thermally, but under irradiation it resulted in a formation of 1 : 1-cycloadducts, I (9), II (17), and III (34), and a 1 : 2-cycloadduct IV (38).
SADAO OIDA, EIJI OHKI
openaire +2 more sources
Influence of activated carbons on the kinetics and mechanisms of aromatic molecules ozonation [PDF]
Companies have been looking for new methods for treating toxic or refractory wastewaters; which can mainly be used prior to or after or in connexion with biological treatment processes.This paper compares conventional ozone oxidation with activatedcarbon
Debellefontaine, Hubert +4 more
core +2 more sources
Some new N-substituted pyridazinones and triazolo[4,3-b]pyridazinones were synthesized, respectively, by simple alkylation and 1,3-dipolar cycloaddition of pyridazin-3-one with nitrile imines.
Souad Mojahidi +6 more
doaj +1 more source
Three-Component Synthesis of Polysubstituted Homoproline Analogs
Tetrasubstituted pyrrolidines representing analogs of homoproline weresynthesized by three-component condensation of aryl(heteroaryl)aldehydes, asparagineand N-methylmaleimide (NMM). Compounds with (1S*, 3R*, 3aS*, 6aR*)-configurationat the corresponding
V. Irkha, K. Kudryavtsev
doaj +1 more source
Coordinatively unsaturated ruthenium complexes as efficient alkyne-azide cycloaddition catalysts [PDF]
The performance of 16-electron ruthenium complexes with the general formula Cp*Ru(L)X (in which L = phosphine or N-heterocyclic carbene ligand; X = Cl or OCH2CF3) was explored in azide−alkyne cycloaddition reactions that afford the 1,2,3- triazole ...
Broggi, Julie +6 more
core +2 more sources

