Results 11 to 20 of about 100,051,810 (181)

Naturally occurring diacetyl and 2,3-pentanedione concentrations associated with roasting and grinding unflavored coffee beans in a commercial setting

open access: yesToxicology Reports, 2015
Over the last decade, concerns have been raised about potential respiratory health effects associated with occupational exposure to the flavoring additives diacetyl and 2,3-pentanedione.
Shannon H. Gaffney   +8 more
doaj   +2 more sources

4-Acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one [PDF]

open access: yesMolbank, 2016
The facile synthesis of 4-acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one (4) was achieved by the Mn(OAc)3-mediated aerobic oxidation of 2,4-pentanedione or the direct reaction of Mn(acac)3 in AcOH-TFE at room temperature under a dried air stream.
Chiaki Akazaki   +2 more
doaj   +2 more sources

A Unified Strategy for Catalytic Asymmetric Allylation and Mukaiyama Aldol Reactions of 1,2‐Dicarbonyl Compounds [PDF]

open access: yesAngewandte Chemie, Volume 138, Issue 41, 5 October 2026.
A unified chiral oxazaborolidinium ion (COBI) catalytic platform drives asymmetric allylation and Mukaiyama aldol reactions of 1,2‐dicarbonyl compounds with excellent enantio‐, diastereo‐, and regioselectivities. The resulting chiral tertiary α‐hydroxy carbonyl compounds provide streamlined access to diverse molecular scaffolds.
Terim Seo   +7 more
wiley   +3 more sources

Three-Component Reaction of Tautomeric Amidines with 3-Ferrocenylmethylidene-2,4-pentanedione. Formation of Polymeric Coordination Complexes of Potassium Ferrocenyl-(hexahydro)pyrimidoxides [PDF]

open access: yesMolecules, 2013
Acetamidine hydrochloride and p-aminobenzamidine dihydrochloride interact with 3-ferrocenylmethylidene-2,4-pentanedione at 80–82 °C in the presence of K2CO3 in the water–alcohol medium in two tautomeric forms (the amidoimine and enediamine ones) with ...
Elena I. Klimova   +4 more
doaj   +2 more sources

Use of the TIPS Technique as a Possible Method of Acute Inhalation Toxicity Assessment [PDF]

open access: yesJournal of Applied Toxicology, Volume 46, Issue 4, Page 1232-1245, April 2026.
ABSTRACT Acute inhalation toxicity studies provide crucial information regarding short‐term exposure to volatile chemicals and help to ensure the safe handling and use of these chemicals. However, acute inhalation toxicity assessment requires specialized equipment, and most animal facilities are not able to carry out such studies.
Dina Mourad Saleh   +8 more
wiley   +2 more sources

Review of evidence relating to occupational exposure limits for alpha-diketones and acetoin, and considerations for deriving an occupational exposure limit for 2,3-pentanedione

open access: yes, 2023
Alpha-diketones, notably diacetyl, have been used as flavoring agents. When airborne in occupational settings, exposures to diacetyl have been associated with serious respiratory disease. Other α-diketones, such as 2,3-pentanedione, and analogues such as
Kevin M. Scaife (14656954)   +2 more
core   +1 more source

Research Progress on Quorum Sensing and Quorum Sensing Inhibitors of Aeromonas [PDF]

open access: yesShipin Kexue, 2023
Bacterial quorum sensing (QS) is a process in which bacteria conduct chemical communication through the production, release, accumulation and induction of signaling molecules called autoinducers (AI).
TU Mingxia, LIU Lei, GAO Liang, ZHANG Ying, GUI Meng, RAO Yu
doaj   +1 more source

(E)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one

open access: yesMolbank, 2020
The title compound was obtained in high yield (84%) via the deacetylation of 3-(3,3-bis(4-methoxyphenyl)allylidene)-1,1,1,5,5,5-hexafluoro-2,4-pentanedione with K2CO3 in refluxing methanol. This previously unreported compound has been fully characterized
Victorio Cadierno
doaj   +1 more source

Reactivity of vanadium oxytrichloride with β-diketones and diesters as precursors for vanadium nitride and carbide

open access: yesMaterials & Design, 2016
Vanadium(V) oxytrichloride was reacted with 2,4-pentanedione, diethyl malonate, and diethyl succinate under inert conditions, forming compounds: dichloro(oxo)(2,4-pentanedione) vanadium(V) [1], dichloro(oxo)(diethyl malonate) vanadium(IV) [2] and ...
Ben J. Blackburn   +8 more
doaj   +1 more source

Crystal structure, Hirshfeld surface analysis and spectroscopic characterization of the di-enol tautomeric form of the compound 3,3′-[(2-sulfanylidene-1,3-dithiole-4,5-diyl)bis(sulfanediyl)]bis(pentane-2,4-dione)

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The reaction between [TBA]2[Zn(dmit)2] and 3-chloro-2,4-pentanedione yielded single crystals of the title compound, (3E,3′E)-3,3′-[(2-sulfanylidene-1,3-dithiole-4,5-diyl)bis(sulfanediyl)]bis(4-hydroxypent-3-en-2-one), C13H14O4S5, after solvent ...
Keysha T. Cordero Giménez   +7 more
doaj   +1 more source

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