Oxidant‐Expedited Synthesis of H‐Phosphonates
An exceptionally mild method for synthesis of alkyl and aryl H‐phosphonates from phosphites is reported, requiring only water and O2 (including air) as reagents. Mechanistic experiments indicate that the role of O2 (and other oxidants) in the transformation is to promote a radical mechanism, and that H2O functions to provide both the hydrogen and the ...
Dara T. Curran +4 more
wiley +1 more source
This work presents the synthesis, characterization, and reactivity of an iridium distannylidyne as the first heavy transition metal ditetrylidyne. Characterized by its short Ir─Sn bonds and linear bonding angles at the tin atoms, this compound displays versatile reactivity toward carbon dioxide and trimethylsilyl azide.
Lennart G. Holzapfel +6 more
wiley +2 more sources
Reactions of Terminal Olefins With Iron Carbenes
Iron carbenes react with terminal olefins and show productive metathesis or metathesis‐divergent pathways depending on the nature of the olefin. Reactions proceed through 2π + 2π cycloadditions to generate transient metallacyclobutane intermediates that undergo cycloreversion to generate the metathesis product or the metathesis‐divergent β‐hydride ...
Zachary S. Lincoln +2 more
wiley +2 more sources
High-Resolution Imaging of Extracellular pH in Mouse Liver Tumor. [PDF]
Santana JG +6 more
europepmc +1 more source
Understanding charged polymer-lipid interactions in model membranes revealed by EPR and solid-state NMR: Implications for membrane protein studies. [PDF]
Okorafor EA +4 more
europepmc +1 more source
Molecular structure and composition elucidation of an industrial humin and its fractions.
Constant S +10 more
europepmc +1 more source
Synthesis of a Series of Heterocyclic N-Substituted Derivatives of Alendronic Acid and Their Preliminary Biological Evaluation. [PDF]
Nasulewicz-Goldeman A +3 more
europepmc +1 more source
Keggin-Type Polyoxometalates as a Systematic Antiviral Scaffold: Activity, Cytotoxicity, and Solution Stability across Heteroion and Addenda Metal Variations. [PDF]
Füllborn-Ott J +4 more
europepmc +1 more source
Direct NMR Evidence of Distinct Cation-CO<sub>2</sub> Adducts in Asymmetric Phosphonium-Based Aprotic N-Heterocyclic Anion (AHA) Ionic Liquids. [PDF]
Thacker PJ +3 more
europepmc +1 more source

