Results 31 to 40 of about 4,277,838 (300)
Dissociation constant of anisic (p-methoxybenzoic) acid in the system ethanol-water at 25 C
The dissociation constant of anisic (p-methoxybenzoic) acid in the system ethanol-water was measured at 25 C by a combination of spectrophotometric and electrometric methods. Percentage by weight of ethanol in the solvent system varied from zero to 83.43.
Sager, Elizabeth E.; Bower, Vincent E.
core +1 more source
Thermodynamic function of valineacid in n-n dimethyl formamide mixtures from conductance measurement
Some physical properties enthalpy (?H), entropy (?s), free energy (?G),capacities(?cp?) and Pka values) for valine in dimethyl foramideover the temperature range 293.15-318.15K, were determined by direct conductance measurements. The acid dissociation at
Baghdad Science Journal
doaj +1 more source
Earlier studies of the dissociation constants of monoethanolammonium and diethanolammonium ions and the thermodynamic constants for the dissociation processes have been supplemented by a similar study of triethanolammonium ion from 0 to 50 C.
Bates, Roger G.; Allen, Guy F.
core +1 more source
Calculating the Aqueous pKa of Phenols: Predictions for Antioxidants and Cannabinoids
We aim to develop a theoretical methodology for the accurate aqueous pKa prediction of structurally complex phenolic antioxidants and cannabinoids. In this study, five functionals (M06-2X, B3LYP, BHandHLYP, PBE0, and TPSS) and two solvent models (SMD and
Max Walton-Raaby +3 more
doaj +1 more source
Calpain small subunit homodimerization is robust and calcium‐independent
Calpains dimerize via penta‐EF‐hand (PEF) domains. Using single‐molecule force spectroscopy, we measured the strength and kinetics of PEF–PEF homodimer binding. The interaction is robust, shows a transient conformational step before dissociation, and remains largely insensitive to Ca2+.
Nesha May O. Andoy +4 more
wiley +1 more source
: Tetrodotoxin (TTX) is a highly specific blocker of voltage-gated sodium channels. The dissociation constant of block varies with different channel isoforms.
C. Ruben, Shana L. Geffeney
doaj +1 more source
The dissociation constant and acid hydrolysis rate of hydroxysulfamic acid [PDF]
The acid dissociation constant and hydrolysis rate of hydroxysulfamic acid (HSA) in acid aqueous solutions have been studied. The acid dissociation constant was determined to be K = 1.5 ± 0.5 M at 298 K. The hydrolysis rate, R, was found to be R = k[H+][HSA], where k = 6.2 × 1012 exp (−26 300/RT) M−1 s−1 at (μ = 1.0 M and [HSA] is the concentration of
Littlejohn, D. +2 more
openaire +2 more sources
Structural insights into an engineered feruloyl esterase with improved MHET degrading properties
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa +5 more
wiley +1 more source
The process of internalization of the Shiga toxin A subunit via formation of a complex with the Shiga toxin B subunit, which specifically binds to the Gb3 receptor. The peptide is designed to act as a carrier of drugs into cancer cells. Here, we explored the potential of peptides derived from the catalytic A subunit of Shiga toxin (STxA) to be drug ...
Giulia Opassi +6 more
wiley +1 more source
The dissolution of copper during the leaching of chalcopyrite in ammonia solutions is an attractive alternative to acid sulfate leaching in the treatment of ores with high consumption of acid.
Lilian Velásquez-Yévenes, Rahul Ram
doaj +1 more source

