Measurement of 4-(2-thiazole azo) rososinol acidy constants by means of ultraviolet spectroscopy and chemometrics in water-acetonitrile and water-dioxane binary mixtures [PDF]
In this paper, by combining ultraviolet spectroscopy and Chemometrics method, the acid dissociation constant of 4- (2-thiazole azo) rososinol was measured. The absorption spectra of the 4- (2-thiazole azo) rososinol solution have a large spectral overlap,
Mansoor Namazian +2 more
doaj +1 more source
Solvent, substituents and pH effects towards the spectral shifts of some highly colored indicators [PDF]
The solvatochromic responses of six indicators namely Sudan orange, Alizarin yellow R, Aurin tricarboxylic acid, Alizarin yellow GG, Titan yellow and Eriochrome black-T, dissolved in seven solvents of different polarities, have been measured at room ...
Masoud Mamdouh S. +2 more
doaj +1 more source
A voltammetric method has been developed for the determination of the acid dissociation constant (pKa) of (RfSO2)2CHR (Rf = perfluoroalkyl), which is a strongly acidic molecule that serves as an acid catalyst.
Akira KOTANI +3 more
doaj +1 more source
Spectrophotometric determination of dissociation constant
Vrijednost konstante disocijacije kiseline nam govori o stupnju disocijacije kiseline, odnosno o odnosu ravnotežnih koncentracija disociranog i nedisociranog oblika molekule.
Orešković, Patrik
core +3 more sources
Synthesis and Determination of Acid Dissociation Constants of Bis-Acyl Thiourea Derivatives
N,N'-((dodecane-1,12-diylbis(azanediyl))bis(carbonothioyl))bis(4-nitrobenzamide) 5 and N,N'-((dodecane-1,12-diylbis(azanediyl))bis(carbonothioyl))bis(3-nitrobenzamide) 6 as bis acyl thiourea derivatives were synthesized and their molecular structures ...
Çağla EFEOĞLU +3 more
doaj +1 more source
Direct Potentiometric Determination of Fluoride Species by Using Ion-Selective Fluoride Electrode
A novel approach and method for potentiometric determination of acid dissociation constant (Ka) of hydrofluoric acid are described. Proposed method is based on using commercial fluoride ISE (FISE) as very inexpensive, simple and reasonably fast method ...
Ante Prkić +3 more
doaj +1 more source
Accuracy Assessment for Equilibrium Dissociation Constant Using a Single Binding Isotherm [PDF]
The equilibrium dissociation constant (Kd) characterizes stability of non-covalent molecular complexes. Determining Kd for highly stable complexes may be extremely inaccurate if the ratio between the concentration of the limiting component (L0) and the a
Sergey, Krylov +3 more
core +1 more source
The solvent deuterium isotope effect on the dissociation constant of iodic acid
The solubilities of hydrated and deuterated copper(II) iodate in HClO4–H2O and DClO4–D2O solutions respectively, were measured at 1, 15, 25 and 35°C, the perchloric acid concentrations ranging from 0 to 1.0 m.
H. Gamsjäger, F. Gerber, O. Antonsen
doaj +1 more source
Novel 5,5-diphenylpyrrolidineN-aroylthioureas, containing 4-methylbenzoyl, 2-chlorobenzoyl,2,4-dichlorobenzoyl, and2-naphthoyl, were synthesized and their structural analysis was performed using 1H nuclear magnetic resonance (NMR), 13C NMR, Fourier ...
Yahya Nural
doaj +1 more source
The missing hydrogen ion, part-1: Historical precedents vs. fundamental concepts
The purpose of this review and commentary was to provide an historical and evidence-based account of organic acids and the biochemical and organic chemistry evidence for why cells do not produce metabolites that are acids.
Robert Robergs +3 more
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