Results 21 to 30 of about 4,216 (246)

N-alkyl-N-(phosphonoethyl) substituted (meth)acrylamides – new adhesive monomers for self-etching self-priming one part dental adhesive

open access: yesBeilstein Journal of Organic Chemistry, 2009
Novel N-alkyl-N-(phosphonoethyl) substituted mono-, bis- and tris(meth)acrylamides 3 were synthesized by two different three-step reactions and characterized by IR, 1H NMR and 13C NMR spectroscopy as well as refractive index and viscosity.
Joachim E. Klee, Uwe Lehmann
doaj   +1 more source

Copper-catalyzed Z-selective synthesis of acrylamides and polyacrylamides via alkylidene ketenimines

open access: yesNature Communications, 2022
Alkylidene ketenimines are rarely reported, but synthetically useful, reactive intermediates. Here, the authors disclose a three-component reaction of alkyne, azide and water by cycloaddition, nitrogen extrusion, and carbene-assisted rearrangement, via ...
Xuelun Duan   +6 more
doaj   +1 more source

Bifurcated synthesis of methylene-lactone- and methylene-lactam-fused spirolactams via electrophilic amide allylation of γ-phenylthio-functionalized γ-lactams

open access: yesBeilstein Journal of Organic Chemistry, 2020
New synthetic methods for spirolactams bearing an α-methylene-γ-butyrolactone or its analogous methylene-lactam have been developed. The allylation of γ-phenylthio-functionalized γ-lactams with 2-(acetoxy)methyl acrylamides was accomplished by using 2.5 ...
Tetsuya Sengoku   +4 more
doaj   +1 more source

A Recyclable Nanoparticle-Supported Rhodium Catalyst for Hydrogenation Reactions

open access: yesMolecules, 2010
Catalytic hydrogenation under mild conditions of olefins, unsaturated aldeydes and ketones, nitriles and nitroarenes was investigated, using a supported rhodium complex obtained by copolymerization of Rh(cod)(aaema) [cod: 1,5-cyclooctadiene, aaema ...
Maria Michela Dell’Anna   +3 more
doaj   +1 more source

Cross-Linked Polymeric Gels and Nanocomposites: New Materials and Phenomena Enabling Technological Applications

open access: yesMacromol, 2022
Cross-linked gels are synthesized by homo- and copolymerization of functionalized acrylamides. The gels swell in aqueous solution, and some of them (e.g., poly(N-isopropylacrylamide (PNIPAM)) also in organic solvents of low polarity (e.g ...
Cesar A. Barbero   +4 more
doaj   +1 more source

Die Umlagerung der Addukte von Säuren an Push-Pull-Acetylene : Ihre Anwendung in der Peptid-Synthese

open access: yesCHIMIA, 1979
Push-pull-acetylenes (1) react rapidly and smoothly with proton acids to yield 3-dialkylamino-3-X-acrylic derivatives, which rearrange under very mild conditions (and in the case of the adducts of carboxylic acids quantitatively) to 3-X-N,N-dialkyl ...
Markus Neuenschwander, Urs Stämpfli
doaj   +1 more source

The effect of acrylamide on mitochondrial membrane potential and glutathione extraction in human spermatozoa: A laboratory study

open access: yesInternational Journal of Reproductive BioMedicine, 2020
Background: Acrylamide (AA) is a compound used in the industrial production of polyacrylamide. AAs affects by creating oxidative stress. It produces reactive oxygen species and leads to lipid peroxide.
Zeinab Omidi   +2 more
doaj   +1 more source

In Search of Novel Degradation-Resistant Monomers for Adhesive Dentistry: A Systematic Review and Meta-Analysis

open access: yesBiomedicines, 2022
This study aimed to assess whether degradation-resistant monomers included in experimental dental adhesives can improve long-term bond strength compared to conventional monomers. This study followed the latest PRISMA guidance (2020).
Vlasta Mocharko   +3 more
doaj   +1 more source

Bile Acid Sequestrants Based on Natural and Synthetic Gels

open access: yesGels, 2023
Bile acid sequestrants (BASs) are non-systemic therapeutic agents used for the management of hypercholesterolemia. They are generally safe and not associated with serious systemic adverse effects.
Magdalena-Cristina Stanciu   +2 more
doaj   +1 more source

Pre‐analytical optimization of cell‐free DNA and extracellular vesicle‐derived DNA for mutation detection in liquid biopsies

open access: yesMolecular Oncology, EarlyView.
Pre‐analytical handling critically determines liquid biopsy performance. This study defines practical best‐practice conditions for cell‐free DNA (cfDNA) and extracellular vesicle–derived DNA (evDNA), showing how processing time, storage conditions, tube type, and plasma input volume affect DNA integrity and mutation detection.
Jonas Dohmen   +11 more
wiley   +1 more source

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