Results 171 to 180 of about 301,764 (392)

Cooperative Photocatalysis of 9,10‐Phenanthrenequinone and Sn(OTf)2 for Direct Mannich Reaction of Ethers via Hydrogen Atom Transfer Pathway

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A dual photocatalytic system of o‐PQ and Sn(OTf)2 enables visible light‐induced Mannich‐type addition of ethers to nitrones via Csp³–H activation. This oxidant‐free method offers broad scope and good yields. Mechanistic studies suggest that a photoexcited o‐PQ–Sn(II) complex mediates hydrogen atom transfer to form α‐oxy radicals for nitrone addition. A
Pradip Ramdas Thorve   +2 more
wiley   +1 more source

Nitric oxide circulates in mammalian plasma primarily as an S-nitroso adduct of serum albumin.

open access: yesProceedings of the National Academy of Sciences of the United States of America, 1992
J. Stamler   +8 more
semanticscholar   +1 more source

Thioether Synthesis via the Nickel‐Catalyzed Electrochemical Cross Electrophile Coupling of Aryl/Alkyl Disulfides and Aryl/Alkyl Halides

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A nickel catalyzed electrochemical cross‐electrophile coupling approach for the base‐free synthesis of (un)symmetric (hetero)aryl and alkyl sulfides from organic halides and disulfides is described. The reaction is broadly applicable and tolerates water and air atmosphere. A formal cross‐electrophile coupling approach enables the base‐free synthesis of
Jona Queder, Gerhard Hilt
wiley   +1 more source

Photoredox‐Catalyzed Synthesis of a Novel Class of Fluoroalkyl Pyrazolones

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A photoredox strategy enables regioselective synthesis of fluoroalkyl 2‐pyrazolin‐5‐ones via radical addition and cyclization. This mild, metal‐free method shows a broad substrate scope, operates in batch and flow systems, and offers a sustainable approach to fluorinated heterocycles with potential applications in medicinal chemistry.
Emanuele F. Pissinati   +3 more
wiley   +1 more source

Relative Acidity of Alcohols and Their Ethylene Oxide Adducts

open access: bronze, 1962
Hiroshi Shigematsu   +2 more
openalex   +2 more sources

Recent Advances in Ene Reactions with Carbon Enophiles

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Recent advances in the classical intra‐ and intermolecular ene nexus with carbon enophiles (alkenes, alkynes, arynes, and allenes) show a considerable increase in structural complexity and an enormous potential for functional applications in polymer science.
Thomas J. J. Müller
wiley   +1 more source

Molecular basis of aflatoxin-induced mutagenesis-role of the aflatoxin B1-formamidopyrimidine adduct.

open access: yesCarcinogenesis, 2014
Ying-Chih Lin   +5 more
semanticscholar   +1 more source

Electrocatalytic Dehydrogenative Lactonization of Benzylic Alcohols: A Sustainable Access to Phthalides via N‐hydroxyphthalimide Mediation

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A mild, scalable electrocatalytic method for direct lactonization of benzylic alcohols to phthalides using N‐hydroxyphthalimide as a redox mediator is reported. This metal‐free process proceeds via a phthalimide‐N‐oxyl‐mediated hydrogen atom transfer mechanism, shows broad scope with good to excellent yields, and enables late‐stage functionalizations ...
Pietro Ronco   +6 more
wiley   +1 more source

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