The use of carbon dioxide and alkenes as feedstocks for the production of carboxylic acids holds great significance in sustainable chemistry. Herein, we introduce a simple and unifying nickel‐catalyzed radical hydrocarboxylation for both functionalized and unactivated alkenes at proximal and remote sites.
Rong‐De He, Yixin Lu
wiley +1 more source
Accessing Different Protein Conformer Ensembles with Tunable Capillary Vibrating Sharp-Edge Spray Ionization. [PDF]
Sharif D+9 more
europepmc +1 more source
Studies on the synthesis of α−iodoaziridines and improved conditions for the synthesis of alkyl-α-iodoaziridines using ClMgCHI2 [PDF]
Affron, DA, Boultwood, T, Bull, JA
core +1 more source
Effect of Alternating Polarity in Electrochemical Olefin Hydrocarboxylation
Alternating polarity (AP) is a powerful tool for controlling selectivity in olefin hydrofunctionalization, but this use is underdeveloped. Using electrochemical olefin hydrocarboxylation as a model, we highlight how AP controls product selectivity, yield, and material decomposition.
Stella A. Fors+2 more
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Adducts of Piperidine, Piperazine, Methylpiperazine, and Morpholine with Bis(β-Ketoenolates) of Nickel(II) [PDF]
G. MARCOTRIGIANO+2 more
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We establish a simple polyamidation of carboxylic acids and ynamides to synthesize versatile piezoelectric polyamides, with the merits of 100% atom economy, no waste generation, and additive‐free as well as catalyst‐free system. Tetraphenylethene containing polyamides can generate reactive oxygen species and elicit robust immunogenic cell death ...
Xingguang Li+8 more
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Formation of Adducts in the Nitration of p-Xylene. Exchange and Rearomatization Reactions of p-Xylene Adducts [PDF]
Alfred Fischer, J. N. Ramsay
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Colorimetric 'Naked-Eye' Chemodosimeter for the Detection of CN<sup>-</sup> Ion: Experimental and Theoretical Studies. [PDF]
Yadav KK+5 more
europepmc +1 more source
The proposed D‐π‐A structured dyes enable efficient electron transfer with additives, thanks to their tailored architecture, making them ideal for high‐performance photoinitiating systems. They allow the fabrication of high‐precision 3D printed objects and exhibit outstanding performance under sunlight.
Ji Feng+9 more
wiley +1 more source
Low frequency infrared and Raman spectra of the N,N,N′,N′-tetramethyl-ethylenediamine adducts of the Group IIb dihalides [PDF]
M. H. Abraham, Frederick W. Parrett
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