Double E─H Bond Activation of Ammonia and Water by Cyclic Gallaphosphene L(OCP)GaPGaL
Cyclic gallaphosphene 1 undergoes a twofold E─H bond activation with ammonia and water via a beneficial interplay between the polar “GaPGa” unit and the electrophilic nature of the C center in the bridging PCO unit, yielding six‐membered heterocycles 2 and 3, in which both nucleophilic phosphorus atoms are protonated.
Mahendra K. Sharma +3 more
wiley +1 more source
Mesoionic N-Heterocyclic Olefins, Imines, Thiones, Phosphinidenes and Their Application in Catalysis. [PDF]
Maji S, P S, Hansmann MM, Mandal SK.
europepmc +1 more source
A metallosupramolecular receptor binds squaraine dyes with high affinity and enables efficient dark resonance energy transfer (DRET) that generates bright near‐infrared emission with large pseudo‐Stokes shifts. ABSTRACT A metal‐organic cage was obtained by combining acridone‐based dipyridyl ligands with Pd2+ ions. The cage acts as a potent receptor for
Damien W. Chen +5 more
wiley +1 more source
Protonated decafluorobenzophenone and the decafluorobenzophenone-arsenic pentafluoride adduct. [PDF]
Uran E, Lozinšek M.
europepmc +1 more source
Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling
Reductive cross‐couplings enable efficient C–C bond formation but are limited by the heterogeneity of Zn or costly reagents like TDAE. We report arylhydrazines as inexpensive, convenient reductants for Ni‐catalyzed sp2–sp3 coupling of aryl halides and secondary alkyl iodides. Mechanistic studies support hydrazine‐mediated NiII reduction for a NiI/NiIII
Nils Kurig +5 more
wiley +1 more source
HX-Linear and Nonlinear Optical Responsiveness of Rationally Designed Heteroleptic d<sup>8</sup>-Metallo-dithiolene Complexes. [PDF]
Attar SS +9 more
europepmc +1 more source
Predicting the Stability of Base-mediated C─H Carboxylation Adducts Using Data Science Tools. [PDF]
Eckhoff M +6 more
europepmc +1 more source
Optical Force Monitoring in Polymeric Materials with a Coumarin-Based Mechanophore. [PDF]
Li Y, Clough JM.
europepmc +1 more source
Controlling cyclodextrin host-guest complexation in water with dynamic pericyclic chemistry. [PDF]
Gaedke M +3 more
europepmc +1 more source

