Results 281 to 290 of about 207,770 (335)

Double E─H Bond Activation of Ammonia and Water by Cyclic Gallaphosphene L(OCP)GaPGaL

open access: yesAngewandte Chemie, EarlyView.
Cyclic gallaphosphene 1 undergoes a twofold E─H bond activation with ammonia and water via a beneficial interplay between the polar “GaPGa” unit and the electrophilic nature of the C center in the bridging PCO unit, yielding six‐membered heterocycles 2 and 3, in which both nucleophilic phosphorus atoms are protonated.
Mahendra K. Sharma   +3 more
wiley   +1 more source

Arm adduction

open access: yes, 2019
Craig Hacking, Bahman Rasuli
openaire   +1 more source

A Metallosupramolecular Receptor for Squaraine Dyes Enabling Ultrafast Dark Resonance Energy Transfer

open access: yesAngewandte Chemie, EarlyView.
A metallosupramolecular receptor binds squaraine dyes with high affinity and enables efficient dark resonance energy transfer (DRET) that generates bright near‐infrared emission with large pseudo‐Stokes shifts. ABSTRACT A metal‐organic cage was obtained by combining acridone‐based dipyridyl ligands with Pd2+ ions. The cage acts as a potent receptor for
Damien W. Chen   +5 more
wiley   +1 more source

Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling

open access: yesAngewandte Chemie, EarlyView.
Reductive cross‐couplings enable efficient C–C bond formation but are limited by the heterogeneity of Zn or costly reagents like TDAE. We report arylhydrazines as inexpensive, convenient reductants for Ni‐catalyzed sp2–sp3 coupling of aryl halides and secondary alkyl iodides. Mechanistic studies support hydrazine‐mediated NiII reduction for a NiI/NiIII
Nils Kurig   +5 more
wiley   +1 more source

HX-Linear and Nonlinear Optical Responsiveness of Rationally Designed Heteroleptic d<sup>8</sup>-Metallo-dithiolene Complexes. [PDF]

open access: yesMolecules
Attar SS   +9 more
europepmc   +1 more source

Predicting the Stability of Base-mediated C─H Carboxylation Adducts Using Data Science Tools. [PDF]

open access: yesAngew Chem Int Ed Engl
Eckhoff M   +6 more
europepmc   +1 more source

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