Facile N═N Bond Cleavage of Cis‐Azobenzene with Bis‐silylenes
The unexpectedly easy N═N bond scission of cis‐azobenzene using two bis‐silylenes with different spacers and distinct SiII···SiII distances is reported. While both bis‐silylenes enable C─H and N═N π‐bond activation of trans‐azobenzene, the cooperative disilicon(II)‐mediated activation of cis‐azobenzene leads to bis‐silamines (Si═N) and related novel ...
Yun Xiong, Shenglai Yao, Matthias Driess
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Atmospheric Pressure Photoionization with Halogen Anion Attachment for Mass Spectrometric Analysis of Hydrocarbons and Hydrocarbon-Based Polymers. [PDF]
Rytkönen E+3 more
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Xanthopinacol (xpin) boronates are a conceptually new class of masked boronic acids designed to alleviate many of the disadvantages of pinacol esters and other popular adducts. They can be formed directly from xanthone and UV light, undergo orthogonal transformations, and are cleavable under photoredox catalysis or oxidative conditions that recycle ...
David M. Heard+2 more
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Sulphotransferase-mediated toxification of chemicals in mouse models: effect of knockout or humanisation of SULT genes. [PDF]
Glatt H, Meinl W.
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Adduct-catalyzed tandem electro-thermal synthesis of organophosphorus (III) compounds from white phosphorus. [PDF]
Hu J+6 more
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Revisiting the Mechanistic Pathway of Gas-Phase Reactions in InN MOVPE Through DFT Calculations. [PDF]
He X, Xu N, Xue Y, Zhang H, Zuo R, Xu Q.
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Impacts of amino acid-linked platinum(II) complexes on DNA structure. [PDF]
Shrestha D, Kimutai B, Chow CS.
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Optimization of Capillary Vibrating Sharp-Edge Spray Ionization for Native Mass Spectrometry of Triplex DNA. [PDF]
Mahmud S+9 more
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Synthesis of Amorphous Cellulose Derivatives via Michael Addition to Hydroxyalkyl Acrylates for Thermoplastic Film Applications. [PDF]
Nagaishi H, Totani M, Kadokawa JI.
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