Results 311 to 320 of about 189,010 (320)

Facile N═N Bond Cleavage of Cis‐Azobenzene with Bis‐silylenes

open access: yesAngewandte Chemie, EarlyView.
The unexpectedly easy N═N bond scission of cis‐azobenzene using two bis‐silylenes with different spacers and distinct SiII···SiII distances is reported. While both bis‐silylenes enable C─H and N═N π‐bond activation of trans‐azobenzene, the cooperative disilicon(II)‐mediated activation of cis‐azobenzene leads to bis‐silamines (Si═N) and related novel ...
Yun Xiong, Shenglai Yao, Matthias Driess
wiley   +1 more source

Xanthopinacol Boronate: A Robust, Photochemically Assembled and Cleavable Boronic Ester for Orthogonal Chemistry

open access: yesAngewandte Chemie, EarlyView.
Xanthopinacol (xpin) boronates are a conceptually new class of masked boronic acids designed to alleviate many of the disadvantages of pinacol esters and other popular adducts. They can be formed directly from xanthone and UV light, undergo orthogonal transformations, and are cleavable under photoredox catalysis or oxidative conditions that recycle ...
David M. Heard   +2 more
wiley   +1 more source

Optimization of Capillary Vibrating Sharp-Edge Spray Ionization for Native Mass Spectrometry of Triplex DNA. [PDF]

open access: yesACS Omega
Mahmud S   +9 more
europepmc   +1 more source

Mechanism of DNA-protein crosslink bypass by CMG helicase

open access: yes
Kyaw MT   +3 more
europepmc   +1 more source

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