In the title compound, [Nd(NO3)3(H2O)4]·3C3H4N4, neodymium is ten-coordinate with a distorted bicapped square-antiprismatic geometry formed from six O atoms from three nitrate ions and four O atoms from four coordinated water molecules.
Ramalingam Sangeetha +3 more
doaj +1 more source
An organometallic compound which exhibits a DNA topology-dependent one-stranded intercalation mode [PDF]
Understanding how small molecules interact with DNA is essential since it underlies a multitude of pathological conditions and therapeutic interventions.
Adhireksan +16 more
core +2 more sources
Electrochemically Promoted Benzylation of [60]Fullerooxazolidinone
Benzylation of the electrochemically generated dianion from N-p-tolyl-[60]fullerooxazolidinone with benzyl bromide provides three products with different addition patterns.
Xing-Xing Yan +4 more
doaj +1 more source
First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquid. An electrochemical and chemical study on the role of temperature [PDF]
Cyclic voltammetry provides the first direct evidence of N-heterocyclic carbene (NHC) presence in neat 1-‐butyl-3-methylimidazolium acetate ionic liquid (BMImAcO) at 120°C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was
Chiarotto, I., Feroci, M., Inesi, A.
core +1 more source
Crystal structure of 4-aminobenzoic acid–4-methylpyridine (1/1)
In the title 1:1 adduct, C6H7N·C7H7NO2, the carboxylic acid group is twisted at an angle of 4.32 (18)° with respect to the attached benzene ring. In the crystal, the carboxylic acid group is linked to the pyridine ring by an O—H...N hydrogen bond ...
M. Krishna Kumar +4 more
doaj +1 more source
Differentiating signals to make biological sense – a guide through databases for MS-based non-targeted metabolomics [PDF]
Metabolite identification is one of the most challenging steps in metabolomics studies and reflects one of the greatest bottlenecks in the entire workflow.
Armitage, Emily Grace +4 more
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Unusual DNA binding modes for metal anticancer complexes [PDF]
DNA is believed to be the primary target for many metal-based drugs. For example, platinum-based anticancer drugs can form specific lesions on DNA that induce apoptosis.
Pizarro, Ana M., Sadler, P. J.
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Critical depurinating DNA adducts: Estrogen adducts in the etiology and prevention of cancer and dopamine adducts in the etiology and prevention of Parkinson's disease [PDF]
Endogenous estrogens become carcinogens when dangerous metabolites, the catechol estrogen quinones, are formed. In particular, the catechol estrogen-3,4-quinones can react with DNA to produce an excess of specific depurinating estrogen-DNA adducts. Loss of these adducts leaves apurinic sites in the DNA, generating subsequent cancer-initiating mutations.
Ercole L. Cavalieri +2 more
openaire +3 more sources
Amine catalysis for the organocatalytic diboration of challenging alkenes [PDF]
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The generation of in situ sp 2 –sp 3 diboron adducts has revolutionised the synthesis of organoboranes.
Althaus +35 more
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Why is Aged Acetylcholinesterase So Difficult to Reactivate?
Organophosphorus agents are potent inhibitors of acetylcholinesterase. Inhibition involves successive chemical events. The first is phosphylation of the active site serine to produce a neutral adduct, which is a close structural analog of the acylation ...
Daniel M. Quinn +3 more
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