Direct C-N Coupling of Aromatic Aldehydes with Amines by H<sub>2</sub>O<sub>2</sub> for Synthesis of Amides at Room Temperature. [PDF]
Zhao MY, Li MH, Han GZ.
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2D covalent organic frameworks are promising photocatalysts. Yet, precise synthesis of sub‐stoichiometric COFs remains challenging due to poor kinetic control. We propose a general strategy: tuning polymerization degree of kinetic intermediates via time or solvent polarity directs their thermodynamic repair into highly crystallization. Using [4+3]‐type
Xiang Pei +8 more
wiley +1 more source
Selective 1,2-addition of acetonitrile/acetone to α,β-unsaturated aldehydes at room temperature: access to cinnamyl alcohol derivatives with potential protective effects against exercise-induced skeletal muscle injury. [PDF]
Ma S, Zhang Y, He Y.
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CR8L10 is self‐assembled with catalase (CAT) to form CR8L10@CAT nanocomplexes, which can anchor to mucosal surfaces via thiol‐disulfide exchange with mucin, thereby enhancing their mucosal retention. The efficient reactive oxygen species (ROS) scavenging at inflamed sites would then result in successful treatment in both the intravesical IC/BPS model ...
Xinzhu Li +13 more
wiley +1 more source
Methylglyoxal and Glyoxal in High-Puff Disposable Electronic Cigarette Liquids: Unexpected Accumulation and Enhanced Cytotoxicity. [PDF]
Omaiye EE +4 more
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Depression is increasingly recognized as a risk factor for chronic diseases, yet its biological impact on cancer remains unclear. Using data from more than 490 000 participants across three international cohorts, we show that depression significantly increases the risk of liver cancer.
Ruijiang Zeng +10 more
wiley +1 more source
Cascade transformation of 2-(diazoacetyl)-2<i>H</i>-azirines to 2-aroyl-3-hydroxy-1<i>H</i>-pyrroles via condensation with aromatic aldehydes. [PDF]
Zanakhov TO +3 more
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Calcium‐Mechanochemistry Enabled Ketone Synthesis From Organic Iodides and Carboxylic Acids
Mechanochemically generated organocalcium species display unusual chemoselectivity toward carboxylates, enabling direct ketone synthesis without overaddition. Ball milling activates commercial calcium metal under ambient, solvent‐minimized conditions, providing a broad substrate scope, high functional‐group tolerance, and a practical one‐step ...
Mengyao Pei +9 more
wiley +1 more source
Photocatalytic prins-like indole addition of tryptophol C2 with aldehydes and ketones. [PDF]
Liu L +6 more
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