Results 41 to 50 of about 158,056 (165)

Enzyme-Mediated Cross-Benzoin Reaction of Highly Enolizable Aldehydes and Aryl Aldehydes for Acess to Chiral Phosphonates [PDF]

open access: yes
Enzymatic catalysis has emerged as an attractive technology for organic synthesis but remains in its infancy for constructing biologically-relevant chiral phosphonates.
Yongtao, Xie   +10 more
core   +2 more sources

Enantioselective Michael Addition of Aldehydes to Maleimides Organocatalyzed by a Chiral Primary Amine-Salicylamide

open access: yesMolecules, 2018
A primary amine-salicylamide derived from chiral trans-cyclohexane-1,2-diamine was used as an organocatalyst for the enantioselective conjugate addition of aldehydes, mainly α,α-disubstituted to N-substituted maleimides.
Alejandro Torregrosa-Chinillach   +5 more
doaj   +1 more source

Analytical methods and experimental quality in studies targeting carbonyls in electronic cigarette aerosols

open access: yesFrontiers in Chemistry
We provide an extensive review of 14 studies (11 independent and three industry-funded) on emissions generated by Electronic Cigarettes (ECs), specifically focusing on the evaluation of carbonyls present in these emissions and emphasizing a meticulous ...
Roberto A. Sussman   +4 more
doaj   +1 more source

Deoxydichlorination of aldehydes catalyzed by Diphenyl sulfoxide

open access: yesChimica Techno Acta, 2021
The diphenyl sulfoxide-catalyzed conversion of aldehydes to 1,1-dichlorides is reported. The reaction proceeds via a sulfurous (IV)-catalysis manifold in which diphenyl sulfoxide turnover is achieved using oxalyl chloride as a consumable reagent.
I. A. Gorbunova   +2 more
doaj   +1 more source

Some Chemical Aspects of 1,2,4-triazine derivatives [PDF]

open access: yesDelta Journal of Science, 2016
Condensation of 3a,b with some aromatic aldehydes afforded the Schiff bases (4a-f). Reaction of 3a,b witharomatic aldehydes and alkyl phosphites gave the corresponding amino phosphonates (5a-d). Heating 3a,b with 6a-f in POCl3 at85 °C furnished the amino
A. A. El-Barbary⃰   +2 more
doaj   +1 more source

Amphoteric α-Boryl Aldehydes

open access: yes, 2016
A new class of stable molecules, α-boryl aldehydes, has been prepared from oxiranyl N-methyliminodiacetyl boronates by a 1,2-boryl migration with concomitant epoxide scission.
Andrei K. Yudin (1470634)   +1 more
core   +2 more sources

Molecular Response to Toxic Diatom-Derived Aldehydes in the Sea Urchin Paracentrotus lividus

open access: yesMarine Drugs, 2014
Diatoms are dominant photosynthetic organisms in the world’s oceans and represent a major food source for zooplankton and benthic filter-feeders. However, their beneficial role in sustaining marine food webs has been challenged after the discovery that ...
Stefano Varrella   +5 more
doaj   +1 more source

Oxidation of Aldehydes Used as Food Additives by Peroxynitrite

open access: yesAntioxidants, 2023
Benzaldehyde and its derivatives are used as food supplements. These substances can be used mainly as flavorings or as antioxidants. Besides, peroxynitrite, an oxidizing agent, could be formed in canned food. Both species could react between them.
Clara I. Alcolado   +5 more
doaj   +1 more source

Remarkable Diastereoselectivity in the Addition of Allylic and Unsaturated Diorganozinc Reagents to β-(N,N-Dialkylamino)-aldehydes

open access: yes, 2016
1,3-Anti amino alcohols 5a−18a are obtained with high diastereoselectivity by use of diorganozinc reagents in additions to amino aldehydes 2a and 2b. The corresponding Grignard reagents exhibit low to modest diastereoselectivity.
Denis Kozhinov (3031350)   +2 more
core   +1 more source

Exhaled Aldehydes as Biomarkers for Lung Diseases: A Narrative Review

open access: yesMolecules, 2022
Breath analysis provides great potential as a fast and non-invasive diagnostic tool for several diseases. Straight-chain aliphatic aldehydes were repeatedly detected in the breath of patients suffering from lung diseases using a variety of methods, such ...
Maximilian Alexander Floss   +5 more
doaj   +1 more source

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