Results 51 to 60 of about 428,832 (350)

Reactivity of TEMPO anion as a nucleophile and its applications for selective transformations of haloalkanes or acyl halides to aldehydes [PDF]

, 2004
Sodium 2,2,6,6-tetramethylpiperidine-N-oxide (TEMPO−Na+), generated by reduction of TEMPO· with sodium naphthalenide in THF, reacted with alkyl halides or acyl halides to produce O-alkylated or acylated TEMPOs, which were in turn oxidized with ...
Allen, Anderson, Boger, Braslau, Braslau, Gilbert, Hawker, Henry-Riyad, Hiroyuki Kawafuchi, Hudlicky, Hunter, Inokuchi, Jahn, Johnstone, Kersey, Kilenyi, Kruse, Matyjaszewski, Nahm, Ollivier, Page, Paquette, Ren, Rossi, Saunders, Schämann, Semmelhack, Sholle, Skene, Studer, Togo, Tsutomu Inokuchi, Uneyama, Wetter, Whitesides, Winterfeldt   +35 more
core   +1 more source

Role of aldehyde chemistry and NO_x concentrations in secondary organic aerosol formation [PDF]

, 2010
Aldehydes are an important class of products from atmospheric oxidation of hydrocarbons. Isoprene (2-methyl-1,3-butadiene), the most abundantly emitted atmospheric non-methane hydrocarbon, produces a significant amount of secondary organic aerosol (SOA ...
Chan, A. W. H., Chan, M. N., Chhabra, P. S., Crounse, J. D., Flagan, R. C., Loza, C. L., Seinfeld, J. H., Surratt, J. D., Wennberg, P. O., Yee, L. D.   +9 more
core   +3 more sources

Branch-Selective Addition of Unactivated Olefins into Imines and Aldehydes.

Journal of the American Chemical Society, 2018
Radical hydrofunctionalization occurs with ease using metal-hydride hydrogen atom transfer (MHAT) catalysis to couple alkenes and competent radicalophilic electrophiles. Traditional two-electron electrophiles have remained unreactive.
Jeishla L. M. Matos, Suhelen Vásquez-Céspedes, J.‐H. Gu, T. Oguma, R. Shenvi   +4 more
semanticscholar   +1 more source

Model studies on the pattern of volatiles generated in mixtures of amino acids, lipid oxidation-derived aldehydes, and glucose [PDF]

, 2011
The development of flavor and browning in thermally treated foods results mainly from the Maillard reaction and lipid degradation but also from the interactions between both reaction pathways.
Adams, An, De Kimpe, Norbert, Kitrytė, Vaida, Venskutonis, Rimantas   +3 more
core   +1 more source

Genetic attenuation of ALDH1A1 increases metastatic potential and aggressiveness in colorectal cancer

Molecular Oncology, EarlyView.
Aldehyde dehydrogenase 1A1 (ALDH1A1) is a cancer stem cell marker in several malignancies. We established a novel epithelial cell line from rectal adenocarcinoma with unique overexpression of this enzyme. Genetic attenuation of ALDH1A1 led to increased invasive capacity and metastatic potential, the inhibition of proliferation activity, and ultimately ...
Martina Poturnajova, Zuzana Kozovska, Ondrej Pos, Kristina Pavlov, Sachin Gulati, Peter Makovicky, Kristina Jakic, Monika Burikova, Eva Sedlackova, Barbora Svitkova, Silvia Tyciakova, Vojtech Bystry, Nicolas Blavet, Boris Tichy, Matej Hrnciar, Jaroslav Budis, Miroslav Tomas, Peter Dubovan, Georgina Kolnikova, Veronika Repaska, Nikoleta Mojzesova, Eva Zomborska, Daniel Pindak, Michal Mego, Tomas Szemes, Miroslava Matuskova   +25 more
wiley   +1 more source

Deoxydichlorination of aldehydes catalyzed by Diphenyl sulfoxide

Chimica Techno Acta, 2021
The diphenyl sulfoxide-catalyzed conversion of aldehydes to 1,1-dichlorides is reported. The reaction proceeds via a sulfurous (IV)-catalysis manifold in which diphenyl sulfoxide turnover is achieved using oxalyl chloride as a consumable reagent.
I. A. Gorbunova, D. A. Shipilovskikh, S. A. Shipilovskikh   +2 more
doaj   +1 more source

Volatile organic compounds and consumer preference for meat from suckling goat kids raised with natural or replacers milk [PDF]

, 2019
Most of European Union goats are slaughtered with carcase weights between 5 kg and 11 kg. Some farmers rear kids with milk replacers to produce cheese with the dams’ milk.
Alcalde Aldea, María Jesús, Argüello Hernández, Anastasio, Casquete, Rocío, Guía Córdoba, María de, Martín, Alberto, Panea, Begoña, Ripoll García, Guillermo   +6 more
core   +3 more sources

Hippo pathway at the crossroads of stemness and therapeutic resistance in breast cancer

Molecular Oncology, EarlyView.
Dysregulation of the Hippo pathway drives nuclear accumulation of YAP/TAZ, activating stemness‐related transcriptional programs that sustain breast cancer stemness and fuel therapeutic resistance across subtypes, underscoring Hippo signaling as a targetable vulnerability. Figure created and edited with BioRender.com.
Giulia Schiavoni, Antonella Palmese, Stefano Scalera, Laura Cipriani, Davide Mascolo, Patrizia Vici, Teresa Arcuri, Lorena Filomeno, Eriseld Krasniqi, Giovanni Blandino, Giulia Bon, Marcello Maugeri‐Saccà   +11 more
wiley   +1 more source

Enantioselective Michael Addition of Aldehydes to Maleimides Organocatalyzed by a Chiral Primary Amine-Salicylamide

Molecules, 2018
A primary amine-salicylamide derived from chiral trans-cyclohexane-1,2-diamine was used as an organocatalyst for the enantioselective conjugate addition of aldehydes, mainly α,α-disubstituted to N-substituted maleimides.
Alejandro Torregrosa-Chinillach, Adrien Moragues, Haritz Pérez-Furundarena, Rafael Chinchilla, Enrique Gómez-Bengoa, Gabriela Guillena   +5 more
doaj   +1 more source

Catalytic Oxidation of Lignins into the Aromatic Aldehydes: General Process Trends and Development Prospects

International Journal of Molecular Sciences, 2017
This review discusses principal patterns that govern the processes of lignins’ catalytic oxidation into vanillin (3-methoxy-4-hydroxybenzaldehyde) and syringaldehyde (3,5-dimethoxy-4-hydroxybenzaldehyde).
V. Tarabanko, N. Tarabanko
semanticscholar   +1 more source