Results 151 to 160 of about 193,242 (265)

Natural Aging of Biomaterials in Ambient and Physiological Environments

Advanced NanoBiomed Research, EarlyView.
Biomaterials used in biomedical applications can change their physical properties over time, even under ambient and physiological conditions. This review highlights key studies on the natural aging of materials ranging from soft hydrogels to metals and ceramics, emphasizing how time‐dependent changes influence function and performance.
Shuyu Zhang, Anne E. Staples
wiley   +1 more source

Extracellular DNA triggers glucosinolate-dependent defence responses against Frankliniella occidentalis. [PDF]

BMC Plant Biol
Rassizadeh L, Garcia-Molina A, Flors V, Vega-Muñoz I, Gamir J.   +4 more
europepmc   +1 more source

Formation of Gallium Monofluoride in the Coordination Sphere of Nickel

Angewandte Chemie, EarlyView.
The elusive gas‐phase species gallium monofluoride forms selectively in the coordination sphere of a nickel(II) centre as a product of C(sp3)–F bond activation, with a weakly coordinating anion as the fluorine source. The herein reported gallium monofluoride ligand acts as a very strong σ‐donor ligand at nickel and serves as a fluorine donor towards ...
Johannes Stephan, Samia Kahlal, Jean‐Yves Saillard, Marvin Mühlau, Lisa Gremmel, Christian Gemel, Roland A. Fischer   +6 more
wiley   +1 more source

Glucosinolate variation, heterosis, and prediction of hybrid performance from parental values in white cabbage (<i>Brassica oleracea</i> var. <i>capitata</i>). [PDF]

Front Plant Sci
Fabjan P, Mikulič-Petkovšek M, Kastelec D, Podržaj A, Rudolf-Pilih K.   +4 more
europepmc   +1 more source

A Wagner–Meerwein‐Like Rearrangement Generates a Vinyl Group in the Biosynthesis of the Polychlorinated Lipopeptides Fischerazoles

Angewandte Chemie, EarlyView.
The fischerazoles, unusual cyanobacterial chlorinated lipopeptides are reported. During their biosynthesis, a linear fatty acyl‐acyl carrier protein (ACP) precursor is rearranged through the action of the S‐adenosyl‐methionine (SAM)‐dependent methyltransferase FshF, to generate a pendant vinyl group.
Sandra A. C. Figueiredo, Kathleen Abt, Konrad Viehrig, Peter J. Jervis, Teresa P. Martins, Iñaki Lacomba, Chuhan Li, Daniele Castagnolo, Pedro N. Leão   +8 more
wiley   +1 more source

Ion-Lock Storage With Multi-Logic Circuitry Gated by Polar-Dipolar Interactions in Poly(Ionic Liquids). [PDF]

Angew Chem Int Ed Engl
Biswas S, Liu J, Austin J, Urban MW.
europepmc   +1 more source

Exclusive Hydroformylation of Terminal Olefins: A Phosphorus‐Free Ruthenium System for the Selective Functionalization of Complex Mixtures

Angewandte Chemie, EarlyView.
Development of a phosphorus‐free Ru/DBU catalyst enabling highly chemo‐ and regioselective hydroformylation of terminal olefins, sparing internal double bonds. Optimization of reaction parameters, ligand effects, and substrate scope including industrial feedstocks was realized.
Mohamed Niyaz Vellala Syed Ali, Ida Ziccarelli, Dilver Peña Fuentes, Christoph Kubis, Robert Franke, Ralf Jackstell, Matthias Beller   +6 more
wiley   +1 more source

Interfacial mechanisms governing acid-brine-heavy oil interactions: quantitative analysis of asphaltene behavior and emulsion stability. [PDF]

Sci Rep
Parvizshahi N, Dehaghani AHS.
europepmc   +1 more source

A Novel Class of “Super‐Strained” Spiro Heterocycles: Gateway to 1‐Azaspiro[3.3]heptane Derivatives, and Biological Validation

Angewandte Chemie, EarlyView.
A new class of “super‐strained” spiro heterocycles—spirocyclic 1‐azabicyclo[1.1.0]butanes—was synthesized via insertion of cyclobutane‐, oxetane‐, and azetidine‐containing sulfonium reagents into substituted azirines. The stability of this new class of compounds was studied.
Philipp Natho, Annarita Vicenti, Marco Colella, Francesco Pasca, Giuseppe Romanazzi, Mauro Niso, Carmen Abate, Ernesto Mesto, Emanuela Schingaro, Renzo Luisi   +9 more
wiley   +1 more source

Pincer Nickel(II) Catalyzed Oxidative Carbonylation of Amines: A Phosgene-Free Synthesis for Isocyanates and Ureas. [PDF]

ACS Omega
Szwedo P, Kondrapolu RS, Munshi P, Ghosh A.   +3 more
europepmc   +1 more source