Spontaneously aligned, long‐range hexagonal columnar ordering is obtained in phase‐separated dynamic covalent networks by combining discrete siloxanes and dynamic acylsemicarbazide bonds. The ordered network shows improved (thermo)mechanical properties and creep resistance compared to the disordered network.
Stefan J. D. Maessen +6 more
wiley +1 more source
Transfer of structural units through imine exchanges, in solution or without solvent: successive transiminations, stimuli (pH)-modulated covalent switches, and mathematical models. [PDF]
Ramirez J, Stadler AM.
europepmc +1 more source
Imine‐linked 2D covalent organic frameworks incorporating delocalized trioxotriangulene (TOT) neutral radicals were synthesized through complementary routes. Direct incorporation of an amine‐functionalized TOT radical yields a highly crystalline, porous framework (TOT‐COF‐H) with intrinsic semiconducting behavior (σRT = 1.2 × 10−4 S cm−1) and a narrow ...
Paula Escamilla +8 more
wiley +1 more source
Decoding the Principles Governing Molecular Cage Precipitation of Aliphatic and Perfluoroalkyl Acids (PFAAs). [PDF]
Pérez-Ferreiro M, Criado A, Mosquera J.
europepmc +1 more source
Environmental Identification of Novel Enzymes for Polyurethane and Polyamide Degradation
Heteroatom‐containing plastics such as polyurethanes and nylons are produced at scale yet remain largely unrecycled. Biocatalysts offer a promising route to depolymerization under mild conditions. Here, we present a screening platform for the discovery of novel polyurethane‐ and nylon‐degrading enzymes from environmental samples and demonstrate ...
Malthe Kjær Bendtsen +17 more
wiley +1 more source
Key Roles of Aliphatic Ligands over PbS Quantum Dots for Efficient Triplet Energy Transfer in a Hybrid TES-ADT/PbS System for Triplet-Triplet Annihilation Photon Upconversion. [PDF]
Nishimura N +5 more
europepmc +1 more source
Non‐Dilute Synthesis of Macrodiolides and Macrotetrolides Enabled by Confinement Catalysis
Confinement catalysis within a hexameric resorcin[4]arene capsule enables macrolactonization under non‐dilute conditions (up to 0.1 M), overcoming the limitations of high‐dilution protocols (0.1–10 mM). This strategy provides direct access to 18–32‐membered macrodiolides and 26–32‐membered macrotetrolides in one pot and unlocks previously inaccessible ...
Feng‐Yuan Wang +3 more
wiley +1 more source
A novel flexible egtazic acid/cerium-based metal organic framework as a potent catalyst for the synthesis of benzochromenoquinolinones and triazolopyrimidines. [PDF]
Almasi G +3 more
europepmc +1 more source

