Results 171 to 180 of about 241,511 (301)

Ultra‐Thin and Highly Insulating Aromatic Monolayers by N‐Heterocyclic Carbenes

open access: yesAngewandte Chemie, EarlyView.
By using N‐heterocyclic carbenes extremally insulating and at the same time as thin as 0.3 nm molecular films are formed. The charge transport calculations indicate absence of destructive quantum interference effect which was so far the only way to suppress conductivity in aromatic molecules.
Mateusz Wróbel   +6 more
wiley   +2 more sources

Amidase‐Catalyzed Desorption of CO2 Captured in Aqueous Monoethanolamine (MEA) Solutions

open access: yesAngewandte Chemie, EarlyView.
CO2 is captured in aqueous monoethanolamine (MEA) sorbents as carbamate and bicarbonate/carbonate. The subsequent desorption for storage or utilization is energy‐intensive, and this is a major impediment to industrial carbon dioxide removal (CDR) processes. The desorption process can be promoted by enzymes that catalyze the dissociation of distinct CO2‐
Yang Yang   +10 more
wiley   +2 more sources

Solvent-Selective Complexity Reduction of Effluent Dissolved Organic Matter for <sup>1</sup>H NMR Spectroscopy. [PDF]

open access: yesAnal Chem
Shakeri Yekta S   +9 more
europepmc   +1 more source

Direct δ‐Lactone Synthesis From Free Alcohols via Photoinduced δ‐C(sp3)–H Carbonylation in Flow

open access: yesAngewandte Chemie, EarlyView.
Herein, we have developed a photo‐flow platform for the δ‐C(sp3)─H carbonylative lactonization of free alcohols with carbon monoxide. The transformation integrates alkoxyl radical generation, selective 1,5‐HAT, CO incorporation, and radical–polar crossover to enable direct access to δ‐lactones from simple alcohol precursors.
Prakash Chandra Tiwari   +2 more
wiley   +2 more sources

Non‐Dilute Synthesis of Macrodiolides and Macrotetrolides Enabled by Confinement Catalysis

open access: yesAngewandte Chemie, EarlyView.
Confinement catalysis within a hexameric resorcin[4]arene capsule enables macrolactonization under non‐dilute conditions (up to 0.1 M), overcoming the limitations of high‐dilution protocols (0.1–10 mM). This strategy provides direct access to 18–32‐membered macrodiolides and 26–32‐membered macrotetrolides in one pot and unlocks previously inaccessible ...
Feng‐Yuan Wang   +3 more
wiley   +2 more sources

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