Iterative Synthesis of Pyrene–Coronene Molecular Graphene Nanoribbons
An iterative approach delivers a new family of undoped, cove‐edged graphene nanoribbons with lengths up to 9.1 nm that exhibit both molar absorptivity and fluorescence brightness values on the order of 105 M−1 cm−1 and an intrinsic charge‐carrier mobility of 475 ± 32 cm2 V−1 s−1.
Miguel A. Medel +6 more
wiley +1 more source
Shale Asphaltene Nanostructure and Gas Preservation: A Molecular-Level Structure-Function Relationship and Predictive Modeling. [PDF]
Wang L +8 more
europepmc +1 more source
Flavin Catalysts in Organic Synthesis
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +1 more source
Development and Application of KASP Markers for Candidate Glucosinolate Biosynthesis Genes in Broccoli. [PDF]
Du S +9 more
europepmc +1 more source
Photochemical Reaction Discovery Enabled by the Dynamic Speciation of Copper Complexes
A strategy for accelerated photochemical reaction discovery is reported that harnesses the dynamic speciation of copper complexes, driven by their labile metal–ligand bonds. This platform simplifies reaction screening by combining an earth‐abundant copper(II) salt with commercially available ligands, which reversibly generate multiple catalytic species
Alessio Regni +6 more
wiley +1 more source
Systematic Expansion of an Ugi-Based Multicomponent Synthesis of Tetrasubstituted Imidazoles. [PDF]
van der Straat R +3 more
europepmc +1 more source
Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie +11 more
wiley +1 more source
Skeletal editing of tetrahydrofurans to pyrrolidines through O-to-N single atom swap. [PDF]
Geng S +6 more
europepmc +1 more source
T‐Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond
A cationic, structurally constrained stibenium platform mediates anti‐Markovnikov hydrostibination of alkenes via element–ligand cooperativity (ELC), thereby bypassing the need for weak Sb─H bonds. ABSTRACT The hydrostibination of alkenes represents a largely underdeveloped transformation, owing to the intrinsic lability of the required Sb─H reagents ...
Ekta Nag +4 more
wiley +1 more source
Interfacial Energetics of C<sub>2</sub>-C<sub>18</sub> Aliphatic Moieties on Hydrogenated Si(111) and Si(110) Surfaces: A DFT Study. [PDF]
Marchio S +3 more
europepmc +1 more source

