Results 161 to 170 of about 241,511 (301)
A catalytic network embedding a formal rearrangement enables the first catalytic enantioselective multicomponent reaction (MCR) of sulfur ylides. In the presence of a bulky chiral phosphoric acid, the reaction combines sulfoxonium ylides, aldehydes and thiols, and affords synthetically versatile β‐hydroxy‐α‐sulfanyl carbonyl compounds in ...
Nicolò Santarelli +10 more
wiley +2 more sources
Glucosinolates in <i>Brassica</i> Species: Biosynthesis, Regulation, and Molecular Breeding. [PDF]
Zhao S +6 more
europepmc +1 more source
Asymmetric Iron‐Catalyzed Vicinal C(sp3)─H Diamination of Carboxylic Acids
An iron‐catalyzed vicinal α,β‐C(sp3)─H diamination of readily available carboxylic acids furnishes chiral α,β‐diamino acids in a single pot with high regio‐, diastereo‐, and enantioselectivity (up to >20:1 dr and >99% ee). ABSTRACT The direct construction of chiral 1,2‐diamines through the stereoselective functionalization of two vicinal C(sp3)─H bonds
Bing Zhou +5 more
wiley +2 more sources
Transition Metal-Catalyzed Direct C(sp<sup>3</sup>)-H Functionalization Reactions of Aliphatic Carboxylic Acids. [PDF]
Mal S, van Gemmeren M.
europepmc +1 more source
Nanographene‐Based van der Waals Organic Framework With Permanent Porosity
Unlocking record‐breaking porosity in a supramolecular organic framework (SOF). Through the strategic design of a C3‐symmetric nanographene, a robust supramolecular framework is achieved via exclusively weak van der Waals forces. This metal‐free scaffold reaches a benchmark BET surface area of 1108 m2 g−1 –the highest to date for this class–combining ...
Arturo Oró +5 more
wiley +2 more sources
Amidation of Quinolin-2-yl Esters: Base‑, Catalyst‑, Metal‑, and Solvent-Free Conditions. [PDF]
Talati K, Rajendran S.
europepmc +1 more source
Improved process for the transformation of primary aliphatic alcohols into higher aliphatic alcohols
A process for obtaining higher aliphatic alcohols starting from aliphatic primary alcohols by condensation reactions is disclosed. Specifically, the process comprises a step in which an aliphatic primary alcohol is contacted in a 5 homogeneous phase with
Rita MAZZONI +13 more
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