Results 101 to 110 of about 105,486 (290)

Palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides

Beilstein Journal of Organic Chemistry, 2017
An efficient palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides has been developed. The reaction proceeds under mild reaction conditions with high efficiency and excellent functional group tolerance, even towards ...
Tao Fan, Wei-Dong Meng, Xingang Zhang
doaj   +1 more source

Natural Products Inspired Scaffold Diversification Leads to Unnatural Molecular Warhead and Covalent Strategy to Modulating Protein Function through Electrophilic Bromine Transfer

Advanced Science, EarlyView.
We report a new thiolate‐reactive α,α‐gem‐dibromo lactam warhead that activates transcription factor Nrf2 and demonstrates anti‐inflammatory activities, which have implications in cancer, neurodegeneration, and cardiovascular diseases. RNA‐seq illuminated detailed transcriptional profiles, and chemical reactions with cysteine‐containing compounds ...
Beau R. Brummel, Sofia Kokkaliari, Qiwen Gao, Jinjing Chen, Larissa Costa de Almeida, Srinivasarao Tenneti, Derek A. Leas, Eli Levit, Lewis S. Alexander, Khalil A. Abboud, Pingrong Wei, Michael D. Cameron, James R. Rocca, Ranjala Ratnayake, Donna D. Zhang, Hendrik Luesch, Robert W. Huigens III   +16 more
wiley   +1 more source

Rewriting Alkene Frameworks: A Practical Strategy for Nitrogen Incorporation

ChemistryEurope
Expanding the reach of skeletal editing to unactivated hydrocarbons presents a formidable challenge in nitrogen incorporation chemistry. In a recent advance, Morandi and coworkers have developed a direct, metal‐free strategy to insert nitrogen into ...
Ranjini Laskar, Frank Glorius
doaj   +1 more source

Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes

Inorganics, 2018
The catalytic activity of nickel complexes in hydrophosphination involving secondary phosphines is not a commonly studied transformation. Beyond a small number of stand-out examples, many reports in the literature focus on the use of simple nickel salts.
Ruth L. Webster
doaj   +1 more source

Ozone and alkyl nitrate formation from the Deepwater Horizon oil spill atmospheric emissions [PDF]

, 2012
Ozone (O3), alkyl nitrates (RONO2), and other photochemical products were formed in the atmosphere downwind from the Deepwater Horizon (DWH) oil spill by photochemical reactions of evaporating hydrocarbons with NOx (=NO+NO2) emissions from spill response
Aikin, KC, Atlas, EL, Blake, DR, Holloway, JS, Meinardi, S, Neuman, JA, Nowak, JB, Parrish, DD, Peischl, J, Perring, AE, Pollack, IB, Roberts, JM, Ryerson, TB, Trainer, M   +13 more
core   +1 more source

Cold Orthogonal Translation: A Psychrophilic Pyrrolysyl‐tRNA Synthetase Boosts Genetic Code Expansion in E. coli

Advanced Science, EarlyView.
ABSTRACT Orthogonal translation systems (OTSs) enable site‐specific incorporation of non‐canonical amino acids (ncAAs) and are central to genetic code expansion. Current engineering strategies typically rely on hyperstable aminoacyl tRNA synthetase (aaRS) scaffolds to tolerate destabilizing mutations required for substrate diversification.
Nikolaj G. Koch, Peter Goettig, Michael A. Nash, Juri Rappsilber, Nediljko Budisa   +4 more
wiley   +1 more source

The co-pyrolysis of flame retarded high impact polystyrene and polyolefins [PDF]

, 2007
The co-pyrolysis of brominated high impact polystyrene (Br-HIPS) with polyolefins using a fixed bed reactor has been investigated, in particular, the effect that different types brominated aryl compounds and antimony trioxide have on the pyrolysis ...
Bhaskar, T., Hall, W.J., Mitan, N., Muto, A., Sakata, Y., Williams, P.T.   +5 more
core   +1 more source

Stabilization of Single Metal Atoms on Graphitic Carbon Nitride: Synthetic Strategies and Emerging Applications

Advanced Science, EarlyView.
This review highlights recent advancements in stabilizing single metal atoms on graphitic carbon nitride emphasizing innovative synthesis strategies and emerging applications in electrocatalysis, photocatalysis and organic transformations, along with key challenges and future perspective. Abstract Emerging as a new frontier in catalysis science, single‐
Wenyao Zhang, Junjie Cui, Zhenjie Yao, Boyuan Zhu, Nithinraj Panangattu Dharmarajan, Ajayan Vinu, Junwu Zhu   +6 more
wiley   +1 more source

A Simple Nickel Catalyst Enabling an E‐Selective Alkyne Semihydrogenation [PDF]

, 2019
Stereoselective alkyne semihydrogenations are attractive approaches to alkenes, which are key building blocks for synthesis. With regards to the most atom economic reducing agent dihydrogen (H 2 ), only few catalysts for the challenging E ‐selective ...
Kaewmee, Benyapa, Teichert, Johannes F., Thiel, Niklas Olof, Tran Ngoc, Trung   +3 more
core   +1 more source

Liquid Bismuth Catalyst Enables High‐CO‐Selectivity in CO2 Hydrogenation

Advanced Science, EarlyView.
This work introduces a dynamic liquid bismuth catalyst for efficient CO2‐to‐syngas conversion. Stabilized molten Bi nanodroplets on a defective VOx support enable a reversible Bi3+/Bi0 redox cycle at moderate temperatures. Mechanistic insights reveal that Ni‐Bi dual sites synergistically activate H2 and cleave CO2, leading to high CO selectivity ...
Xinxin Lu, Zun Guan, Xinyi Fu, Bin Chen, Zhongliang Huang, Riguang Zhang, Guowu Zhan   +6 more
wiley   +1 more source