Results 81 to 90 of about 105,486 (290)

Multifunctional Bio‐Based Packaging for Perishable Foods: Structural Design, Scalable Fabrication, and Versatile Applications

Advanced Materials, EarlyView.
An overview of design principles and scalable fabrication strategies for multifunctional bio‐based packaging. Radiative cooling films, modified‐atmosphere films/membranes, active antimicrobial/antioxidant platforms, intelligent optical/electrochemical labels, and superhydrophobic surfaces are co‐engineered from material chemistry to mesoscale structure
Lei Zhang, Jiaqi Zhang, Mei Cui, Wei Qi, Renliang Huang, Rongxin Su, Kai Zhang   +6 more
wiley   +1 more source

Aminothiolation of alkenes with azoles and Bunte salts

Frontiers in Chemistry
We have developed an intermolecular aminothiolation of simple olefins using Bunte salt as a thiolating agent. This protocol produces thiyl free radicals under PIDA oxidation conditions, eliminating the need for transition-metal catalysts.
Bingqing Ouyang, Xing Chai, Zhe Li, Chunling Zhang, Xingmei Liu   +4 more
doaj   +1 more source

Iron-Catalyzed, Highly Regioselective Synthesis of alpha-Aryl Carboxylic Acids from Styrene Derivatives and CO2 [PDF]

, 2012
The iron-catalyzed hydrocarboxylation of aryl alkenes has been developed using a highly active bench-stable iron(II) precatalyst to give alpha-aryl carboxylic acids in excellent yields and with near-perfect regioselectivity. Using just 1 mol % FeCl2, bis(
Greenhalgh, Mark D., Thomas, Stephen P.
core   +1 more source

Advanced Separators for Liquid and Quasi‐Solid Lithium Rechargeable Batteries: Design and Development

Advanced Materials, EarlyView.
This review traces the evolution of lithium‐ion battery separators from passive barriers to multifunctional components central to cell safety and performance. Polymer‐ceramic hybrids, nanofiber architectures, and bio‐derived membranes deliver ionic conductivities above 3 mS cm−1, thermal stability beyond 200 °C, and effective suppression of lithium ...
Karthik Vishweswariah, Ningaraju Gejjiganahalli Ningappa, Anil Kumar M. R., Jeremy I. G. Dawkins, Thiago M. G. Selva, Karim Zaghib   +5 more
wiley   +1 more source

Unified metal-free intermolecular Heck-type sulfonylation, cyanation, amination, amidation of alkenes by thianthrenation

Nature Communications
Direct and site-selective C-H functionalization of alkenes under environmentally benign conditions represents a useful and attractive yet challenging transformation to access value-added molecules.
Ming-Shang Liu, Hai-Wu Du, Huan Meng, Ying Xie, Wei Shu   +4 more
doaj   +1 more source

[2+2+2] Cycloaddition Reactions of Macrocyclic Systems Catalyzed by Transition Metals. A Review

Molecules, 2010
Polyalkyne and enediyne azamacrocycles are prepared from arenesulfonamides and various alkyne and alkene derivatives either under basic or neutral conditions.
Anna Roglans, Anna Pla-Quintana
doaj   +1 more source

Allylic alcohols and amines by carbenoid eliminative cross-coupling using epoxides or aziridines

Beilstein Journal of Organic Chemistry, 2021
α-Lithiated terminal epoxides and N-(tert-butylsulfonyl)aziridines undergo eliminative cross-coupling with α-lithio ethers, to give convergent access to allylic alcohols and allylic amines, respectively.
Matthew J. Fleming, David M. Hodgson
doaj   +1 more source

Palladium-catalyzed heteroallylation of unactivated alkenes – synthesis of citalopram [PDF]

, 2013
A palladium-catalyzed difunctionalization of unactivated alkenes with tethered nucleophiles is reported. The versatile reaction occurs with simple allylic halides and can be carried out under air.
Adams, Alcaide, Alexanian, Arai, Balme, Beccalli, Byers, Carruthers, Danishefsky, Deprez, Desai, Doroski, Fries, Fries, Fukuda, Giese, Guo, Hayashi, Hayashi, Heck, Hegedus, Hickman, Hopkins, Ingalls, Jensen, Kang, Keller, Kimura, Koester, Komeyama, Kumar, Larock, Larock, Le Bras, Lei, Li, Lira, Liskin, Liu, Liwosz, Lovering, Lu, Ma, Ma, Ma, Ma, Mai, Manzoni, McDonald, Michael, Minatti, Muñiz, Muñiz, Muñiz, Nadin, Neukom, Newman, Newman, Ney, Ney, Nicolai, Nicolai, Nicolai, Nicolai, Nishimura, Pappo, Ritchie, Rosewall, Schuch, Schultz, Sehnal, Semmelhack, Sibbald, Sibbald, Streuff, Sun, Tietze, Tietze, Trost, Trost, Trost, Tsuji, VanRheenen, Vedantham, Wakabayashi, Weaver, Wolfe, Wolfe, Wolfe, Wolfe, Wu, Xu, Yip, Yip, Yorimitsu, Yorimitsu, Zeni, Zhao, Zhu   +98 more
core   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

Advanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen, Zhanxi Fan, Jingjie Ge, Qiyuan He, Zhuangchai Lai, Jiawei Liu, Chaoliang Tan, Hua Zhang   +7 more
wiley   +1 more source

Visible Light-Mediated Monofluoromethylation/Acylation of Olefins by Dual Organo-Catalysis

Molecules
Monofluoromethyl (CH2F) motifs exhibit unique bioactivities and are considered privileged units in drug discovery. The radical monofluoromethylative difunctionalization of alkenes stands out as an appealing approach to access CH2F-containing compounds ...
Jiuli Xia, Yunliang Guo, Zhiguang Lv, Jiaqiong Sun, Guangfan Zheng, Qian Zhang   +5 more
doaj   +1 more source